Efficient inhibitor composition for copper-sulfur separation and copper-sulfur separation flotation method by applying same

A copper-sulfur separation and inhibitor technology, applied in flotation, solid separation, etc., can solve the problems of mine wastewater not up to standard, high production cost, corrosion equipment, etc., and achieve the separation of copper and sulfur, reduce the concentration, and reduce the adsorption effect Effect

Active Publication Date: 2018-04-13
WESTERN MINING CO LTD +3
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  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In copper-sulfur separation flotation, a large amount of lime and other conventional sulfur-iron mineral inhibitors are often added, resulting in high production costs, and lime is easy to cause pipeline blockage, scaling, unity, corrosion of equipment, and mine wastewater not up to standard.

Method used

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  • Efficient inhibitor composition for copper-sulfur separation and copper-sulfur separation flotation method by applying same
  • Efficient inhibitor composition for copper-sulfur separation and copper-sulfur separation flotation method by applying same
  • Efficient inhibitor composition for copper-sulfur separation and copper-sulfur separation flotation method by applying same

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] Embodiment 1, ore properties: the main metal minerals in the ore include chalcocite, chalcopyrite, blue chalcocite, copper blue, pyrite, magnetite, limonite, lead vanadium, etc., and the gangue minerals include quartz , halloysite, sericite, potash feldspar, etc. The results of multi-element analysis of raw ore are shown in Table 1, the phase analysis of copper is shown in Table 2, and the results of mineral composition measurement of ore are shown in Table 3.

[0031] Table 1 Chemical multi-element analysis results of raw ore

[0032]

[0033] Table 2 The results of phase analysis of raw ore copper

[0034]

[0035] Table 3 Mineral content analysis results

[0036]

[0037]Lime inhibitor was added to the copper-sulfur separation roughing operation of this ore, the amount of lime was 10Kg / t relative to the raw ore, and under the conditions of pulp pH=12-13, the test results are shown in Table 4.

[0038] Table 4 lime as inhibitor test results

[0039]

...

Embodiment 2

[0054] Embodiment 2, preparation inhibitor XKY-03, raw material composition is as follows: sodium humate is 65.50%, potassium permanganate is 27.00%, C 2 h 3 NaO 2 S is 7.50%, and it is prepared under normal temperature and pressure with a beaker as a container and a magnetic stirrer for 40 to 50 minutes.

[0055] The technological process steps of copper sulfur separation are:

[0056] 1) Add ore, lime and water into the ball mill, and grind the ore until the particle size is -0.074mm and the content is 60%;

[0057] 2) Pour the ground pulp into the flotation machine, stir, and carry out the rapid flotation operation of mixed flotation of copper and sulfur to obtain mixed coarse concentrate I and rapid flotation tailings; the process conditions of rapid flotation of copper and sulfur For: add collector Z-200: 60g / t, collector butyl xanthate: 20g / t, action time 3min, add foaming agent BK201: 28g / t, action time 1min;

[0058] 3) The rapid flotation tailings obtained in step...

Embodiment 3

[0066] Embodiment 3, preparation inhibitor XKY-03, raw material composition is as follows: sodium humate is 66%, potassium permanganate is 29, C 2 h 3 NaO 2 S is 6%, and it is prepared under normal temperature and pressure with a beaker as a container and a magnetic stirrer for 40 to 50 minutes.

[0067] The technological process steps of copper sulfur separation are:

[0068] 1) Add ore, lime and water into the ball mill, and grind the ore until the particle size is -0.074mm and the content is 60%;

[0069] 2) Pour the ground pulp into the flotation machine, stir, and carry out the rapid flotation operation of mixed flotation of copper and sulfur to obtain mixed coarse concentrate I and rapid flotation tailings; the process conditions of rapid flotation of copper and sulfur For: add collector Z-200: 70g / t, collector butyl xanthate: 25g / t, action time 3min, add foaming agent BK201: 30g / t, action time 2min;

[0070] 3) The rapid flotation tailings obtained in step 2) are th...

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Abstract

The invention discloses an efficient inhibitor composition for copper-sulfur separation and a copper-sulfur separation flotation method by applying the same. The inhibitor composition (XKY-03) comprises, by mass percentage, 55-70% of sodium humate, 20-35% of potassium permanganate and 5-10% of sodium thioglycollate; and a preparation method of the inhibitor composition (XKY-03) comprises the stepsof taking a beaker as a container at normal temperature and normal pressure, and stirring for 40-50 minutes by a magnetic stirrer. According to the inhibitor composition (XKY-03) prepared by the preparation method, the copper-sulfur separation can be effectively realized, the sulfur-iron ore which is activated by Cu2+ can be inhibited, the grade and the recovery rate of copper in the copper concentrate can be improved, meanwhile, the complexation reaction can occur between the inhibitor composition (XKY-03) and unavoidable ions in the ore pulp such as Cu2+, Pb3+, Fe3+ and the like, so that the concentration of the unavoidable ions in the ore pulp is reduced, and the activation effect of the unavoidable ions on the pyrite ore is reduced; and additionally, the inhibitor composition (XKY-03)further has the characteristics of less use amount, low toxicity and the like, and is suitable for popularization and application.

Description

technical field [0001] The invention relates to the technical field of mineral metallurgical processing, in particular to a copper-sulfur separation high-efficiency inhibitor composition and a copper-sulfur separation flotation method thereof. Background technique [0002] As an important strategic resource in the process of industrialization, copper ore resources occupy an important position in my country's mineral resources. The basic reserves of copper resources in my country account for 6.70% of the world's total basic reserves of copper resources, ranking third in the world, second only to Chile and the United States. From the type of ore, my country's copper ore is dominated by sulfide ore. Among the proven reserves of copper resources, sulfide ore accounts for 87%, oxide ore accounts for 10%, and mixed ore accounts for only 3%. my country's copper resources mainly have the following characteristics in terms of deposit scale, ore properties, ore optionality, and deve...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B03D1/018B03D1/02B03D1/08B03D101/06B03D103/02
Inventor 罗仙平翁存建孙康赖春华张忠平王鹏程
Owner WESTERN MINING CO LTD
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