Wet-process solid-liquid separation method for desulfurized slurry and triple box process improvement method

A technology of solid-liquid separation and wet desulfurization, which is applied in chemical instruments and methods, water/sewage multi-stage treatment, gaseous effluent wastewater treatment, etc., to reduce the cost of chemicals, reduce the amount of sludge and sludge moisture content, reduce Effect of sludge treatment costs

Inactive Publication Date: 2018-04-20
RES CENT FOR ECO ENVIRONMENTAL SCI THE CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At the same time, in recent years, the demand for zero discharge of power plant wastewater has become higher and higher. How to achieve rapid pretreatment to remove suspended solids has become a limiting process for the zero discharge treatment of power plant desulfurization wastewater.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0056] The desulfurization wastewater is taken from a power plant, with a pH of 6.40, a suspended particulate matter (SS) of 74.64g / L, a chemical oxygen demand (COD) of 660mg / L, and a conductivity of 72.2μS / cm, using lime + anionic polyacrylamide (PAM) The method for solid-liquid separation, this embodiment is carried out according to the following steps:

[0057] (1) Ingress of water;

[0058] (2) Add 10% quicklime 10ml;

[0059] (3) rapid stirring, the stirring rate is 400r / min, and the stirring time is 5min;

[0060] (4) Add 1g / L flocculant PAM 60ml;

[0061] (5) rapid stirring, the stirring rate is 400r / min, and the stirring time is 30s;

[0062] (6) rapid stirring, the stirring rate is 80r / min, and the stirring time is 5min;

[0063] (7) Set aside to settle for 30 minutes and take samples.

[0064] In this example, after pretreatment, the COD drops to 600mg / L, the turbidity is 293NTU, and the removal rate is 99.7%. After the coagulation treatment in this example, mo...

Embodiment 2

[0066] The desulfurization wastewater is taken from a power plant, the pH is 6.52, the SS is 68.64g / L, the COD is 600mg / L, and the conductance is 70.2μS / cm. The method of lime + magnetic seed + anion PAM is used for solid-liquid separation. This embodiment is based on Follow these steps:

[0067] (1) Ingress of water;

[0068] (2) Add 10% quicklime 5ml;

[0069] (3) rapid stirring, the stirring rate is 400r / min, and the stirring time is 5min;

[0070] (4) Add 1 g / L of ferroferrogen tetroxide magnetic seed;

[0071] (5) rapid stirring, the stirring speed is 400r / min, and the stirring time is 1min;

[0072] (6) Add 1g / L flocculant PAM60ml;

[0073] (7) Quick stirring , The stirring rate is 400r / min, and the stirring time is 30s;

[0074] (8) rapid stirring, the stirring rate is 80r / min, and the stirring time is 5min;

[0075] (2) Set aside to settle for 10 minutes and take samples.

[0076] In this example, after pretreatment, the COD is reduced to 580mg / L, the turbidity...

Embodiment 3

[0078] The desulfurization wastewater is taken from a power plant, the pH is 5.96, the SS is 138.56g / L, the COD is 620mg / L, and the conductance is 58.6μS / cm. The method of lime + magnetic seed + anion AM is used for solid-liquid separation. This example is as follows Steps to proceed:

[0079] (1) Ingress of water;

[0080] (2) Add 10% quicklime 5ml;

[0081] (3) rapid stirring, the stirring rate is 350r / min, and the stirring time is 5min;

[0082] (4) Add 2 g / L of ferroferric oxide magnetic seed;

[0083] (5) rapid stirring, the stirring speed is 400r / min, and the stirring time is 1min;

[0084] (6) Add 1g / L flocculant PAM50ml;

[0085] (7) rapid stirring, the stirring rate is 400r / min, and the stirring time is 30s;

[0086] (8) rapid stirring, the stirring rate is 80r / min, and the stirring time is 5min;

[0087] (9) Set aside to settle for 10 minutes and take samples.

[0088] In this example, after pretreatment, the COD drops to 600mg / L, the turbidity is 127NTU, and ...

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Abstract

The invention provides a wet-process solid-liquid separation method for desulfurized slurry and a triple box process improvement method. The wet-process solid-liquid separation method for the desulfurized slurry comprises the following steps: placing the desulfurized slurry in a reaction device, and adding lime milk till pH is 8-12; adding magnetic seeds; adding a flocculant; and performing solid-liquid separation. Owing to adding of the magnetic seeds and the function of the flocculant, solid-liquid separation can be quickly realized through magnetic flocculation, the sedimentation time is shortened, the size of a clarification tank is reduced, the floc sedimentation efficiency is improved by 50% or above, the sludge content and the moisture content of sludge can be reduced, the follow-upsludge dehydration pressure is relieved, and the sludge treatment cost is lowered; heavy metals and suspended solids can be effectively removed; part of calcium and magnesium can be removed, and softening of desulfurized wastewater is realized; adding of an inorganic coagulant can be omitted, the chemical addition is reduced, and the treatment process is simplified; the magnetic seeds can be recovered, and the recovery rate is up to 90% or above; and the wet-process solid-liquid separation method can be used for improving the triple box process and improving the pre-treatment efficiency of the desulfurized slurry.

Description

technical field [0001] The invention belongs to the technical field of desulfurization wastewater treatment, and relates to a slurry solid-liquid separation method for wet desulfurization and a triple box process improvement method. Background technique [0002] Limestone-gypsum wet flue gas desulfurization technology is currently the most commonly used desulfurization technology in thermal power plants. During the flue gas desulfurization process, limestone slurry absorbs sulfur dioxide in the flue gas to achieve desulfurization, and at the same time forms gypsum, which can be recycled. However, during the desulfurization process, other solid particles or gases in the flue gas from coal mine combustion are also absorbed. At the same time, due to the circulation of the desulfurization absorption liquid, the ionic substances in the original process water also gradually accumulate. In order to ensure the balance of the slurry circulation system of the desulfurization unit, en...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F9/12C02F101/20C02F103/18
CPCC02F1/488C02F1/56C02F1/66C02F9/00C02F2101/20C02F2103/18
Inventor 魏源送郑利兵郁达伟岳增刚王钢
Owner RES CENT FOR ECO ENVIRONMENTAL SCI THE CHINESE ACAD OF SCI
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