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Heat insulating material and equipment using the heat insulating material

A thermal insulation, carbon material technology, applied in heat exchange equipment, lighting and heating equipment, mechanical equipment and other directions, can solve the problem of low thermal conductivity, reduce heat transfer, prevent the effect of burning

Inactive Publication Date: 2021-10-15
PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Therefore, it has a lower thermal conductivity than still air

Method used

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  • Heat insulating material and equipment using the heat insulating material
  • Heat insulating material and equipment using the heat insulating material
  • Heat insulating material and equipment using the heat insulating material

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0153] In water glass (Tosoh Sangyo Co., Ltd.), add self-dispersing graphene oxide (Sigma-Aldrich, 4mg / ml in H 2 O) and water to prepare raw materials (SiO 2 Concentration 6%, graphene oxide GO concentration 0.1%). To 20.5 g of this dispersion liquid, 3.6 parts by weight (0.74 g) of concentrated hydrochloric acid was added as an acid catalyst, followed by stirring to prepare a sol solution.

[0154] Then, pass to non-woven fabric fiber 116 (material; Cellophane, thickness specification 600um, weight per unit area 100g / m 2 , size 12 cm square) into the sol solution so that the sol solution impregnates the non-woven fabric fibers 116 . The non-woven fiber 116 impregnated with the sol solution was sandwiched by a PP film (thickness 50um×2 pieces), and placed at room temperature 23° C. for 3 minutes to make the sol gel. After confirming the gelation, pass the film together with the impregnated non-woven fiber 116 through a biaxial roller with a gap set to 1.00 mm (including fil...

Embodiment 2

[0158] In water glass aqueous solution (Tosoh Industry Co., Ltd.), add self-dispersing graphene oxide (Sigma-Aldrich, 4mg / ml in H 2 O) and water to prepare raw materials (SiO 2 Concentration 6%, graphene oxide GO concentration 0.5%). Except that the concentration of graphene oxide was increased to 0.5%, a sheet was produced under the same process conditions as in Example 1.

[0159] As a result, heat insulating material 108 having an average thickness of 0.88 mm and a thermal conductivity of 0.020 W / mK was obtained. The filling rate of the silica xerogel 115 at this time was 44.6% by weight. V0 in the UL94 vertical burning test. In addition, as a result of DSC measurement, the thermal decomposition temperature (exothermic peak) of the organic modification group was 550° C. or higher, which was shifted to the high temperature side by 190° C. or higher than when the carbon material 114 was not added. In the cone calorimetry test, in the 20-minute non-combustible material tes...

Embodiment 3

[0161] In aqueous solution of water glass (Tosoh Sangyo Co., Ltd.), add self-dispersing carbon black (Tokai carbon, Aqua black 162 19.2wt% in H as carbon material 114) 2 O) and water to prepare raw materials (SiO 2 Concentration 6%, carbon black CB concentration 0.1%). To 20.5 g of this dispersion, 3.6 parts by weight (0.74 g) of concentrated hydrochloric acid was added as an acid catalyst, followed by stirring to prepare a sol solution. Sheets were produced under the same process conditions as in Example 1 except that the carbon material was changed to carbon black.

[0162] As a result, heat insulating material 108 having an average thickness of 0.88 mm and a thermal conductivity of 0.019 W / mK was obtained. The filling rate of the silica xerogel 115 at this time was 45.9% by weight. V0 in the UL94 vertical burning test. In addition, as a result of DSC measurement, the thermal decomposition temperature (exothermic peak) of the organic modification group was 550° C. or hig...

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Abstract

The present invention provides a heat insulating material having both high heat insulating properties capable of effectively blocking heat flow even in a narrow space and flame retardancy capable of preventing flame propagation, and equipment using the heat insulating material. A heat insulating material comprising silica xerogel, a carbon material, and a nonwoven fiber holding the silica xerogel and the carbon material is used. A 3-component composite layer comprising the silica xerogel, the carbon material, and the non-woven fabric fiber is used, and a non-woven composite layer that is disposed on one side of the 3-component composite layer does not contain the non-woven fabric. The 2-component composite layer comprising the silica xerogel and the carbon material, and the single layer comprising the silica xerogel arranged on the other side of the 3-component composite layer The thermal insulation material. A device in which the above-mentioned heat insulating material is disposed as a part of a heat-retaining or cold-retaining structure, or between a component accompanied by heat generation and a casing is used.

Description

technical field [0001] The present invention relates to a heat insulating material and a device using the same. In particular, it relates to a flame-retardant heat insulating material and equipment using the same. Background technique [0002] In recent years, in the fields of automobiles and industrial equipment, it is necessary to ensure heat flow control, safety, and flame spread prevention in limited and narrow spaces. Therefore, there is a demand for a high-performance heat insulating material that has not been conventionally achieved, such as excellent heat insulating properties that can effectively block heat even if it is thin, flame retardancy, and heat resistance. [0003] Therefore, flame-retardant polyurethanes to which flame retardants are added are being developed. In the flame-retardant polyurethane, a general brominated flame retardant or the like is used as the flame retardant for the resin. These are mechanisms for preventing progress of combustion based...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B32B9/00B32B9/04D06M11/79C04B30/02
CPCB32B5/028B32B9/00B32B9/007B32B9/047C04B30/02D06M11/79B32B2250/02B32B2250/03B32B2307/304B32B2307/3065B32B2605/08C04B14/064C04B14/022C04B16/06F16L59/029F16L59/06F16L59/145C09K21/02F28F13/003F28F21/02F28F21/04F28F2270/00
Inventor 及川一摩丰田庆酒谷茂昭光明寺大道大城达弘和田享
Owner PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO LTD