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Graphite modified water-coated anticorrosive resin and preparation method

A graphene-modified, anti-corrosion resin technology, applied in anti-corrosion coatings, coatings, etc., can solve the problems of poor outdoor weather resistance, poor hydrolysis resistance, slow drying of paint films, etc., achieve good water resistance and improve storage performance , the effect of stable performance

Active Publication Date: 2018-07-06
JIANGSU CHAMPION TECHNOLOGY GROUP CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] However, water-based alkyd resin coatings have many performance defects, such as slow drying of the paint film, low hardness, corrosion resistance, poor outdoor weather resistance, and poor hydrolysis resistance due to a large amount of ester bonds.
However, the modification of water-based alkyd resin by existing technologies such as acrylic acid, styrene, polyurethane, epoxy resin, silicone, and inorganic nanometers can only solve part of the problem.

Method used

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  • Graphite modified water-coated anticorrosive resin and preparation method
  • Graphite modified water-coated anticorrosive resin and preparation method

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0031] A graphene-modified water-coated anticorrosion resin, in weight percentage, comprises 5% graphene dispersion liquid, 38% deionized water, 30% vegetable oil fatty acid, 15% pentaerythritol, 9.5% in this anticorrosion resin % phthalic anhydride, 0.1% antioxidant, 2% emulsifier, 0.4% pH regulator; the sum of the weight percentages of each component in the graphene modified water-coated anticorrosion resin is 100%.

[0032] The graphene dispersion is XF020 monolayer graphene oxide dispersion (Xianfeng Nano). The vegetable oil fatty acid is soybean oil. Described antioxidant is JYANOX-1010 antioxidant. Described emulsifier is EFS-1312 nonionic emulsifier (Shanghai Zhongcheng Fine Chemical Co., Ltd.). Described pH adjusting agent is potassium hydroxide.

[0033] The preparation method of above-mentioned graphene modified water-coated type anticorrosion resin comprises the following preparation steps:

[0034] (1) Put vegetable oil fatty acid, pentaerythritol, phthalic anh...

Embodiment 2

[0038] A graphene-modified water-coated anticorrosion resin, in weight percentage, comprises 10% graphene dispersion liquid, 35% deionized water, 26% vegetable oil fatty acid, 9% pentaerythritol, 16% in this anticorrosion resin % phthalic anhydride, 0.03% antioxidant, 3.5% emulsifier, 0.47% pH regulator; the sum of the weight percentages of each component in the graphene modified water-coated anticorrosion resin is 100%.

[0039] The graphene dispersion is XF020 single-layer graphene oxide dispersion. Described vegetable oil fatty acid is castor oil. Described antioxidant is JYANOX-1076 antioxidant. Described emulsifier is ES-1230 anionic emulsifier (Shanghai Zhongcheng Fine Chemical Co., Ltd.). The pH regulator is ammonia water.

[0040] The preparation method is the same as in Example 1.

Embodiment 3

[0042] A graphene-modified water-coated anticorrosion resin, in weight percentage, comprises 6% graphene dispersion liquid, 30% deionized water, 33% vegetable oil fatty acid, 14% pentaerythritol, 13% in this anticorrosion resin % phthalic anhydride, 0.08% antioxidant, 3.62% emulsifier, 0.3% pH regulator; the sum of the weight percentages of each component in the graphene modified water-coated anticorrosion resin is 100%.

[0043] The graphene dispersion is XF020 single-layer graphene oxide dispersion. The vegetable oil fatty acid is a mixture of refined linseed oil and coconut oil (weight ratio 1:1). Described antioxidant is JYANOX-1076 antioxidant. Described emulsifier is EFS-1312 nonionic emulsifier. The pH regulator is dimethylethanolamine.

[0044] The preparation method is the same as in Example 1.

[0045] The graphene-modified water-coated anticorrosion resin described in any one of Examples 1 to 3 was used to prepare steel structure anticorrosion coatings, and the pe...

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Abstract

The invention discloses graphite modified water-coated anticorrosive resin and a preparation method. The graphite modified water-coated anticorrosive resin is prepared from the following components inpercentage by weight: 5 to 10 percent of graphene dispersion liquid, 30 to 38 percent of deionized water, 26 to 33 percent of vegetable oil fatty acid, 9 to 15 percent of pentaerythritol, 9.5 to 16 percent of phthalic anhydride, 0.03 to 0.1 percent of an antioxidant, 2 to 3.62 percent of an emulsifier and 0.3 to 0.47 percent of a pH modifier. The sum of the weight percent of all the components inthe modified water-coated anticorrosive resin is 100 percent. The anticorrosive coating for a steel structure synthesized by the anticorrosive resin disclosed by the invention has the advantages of better water resistance, weather resistance, stable performance and higher paint film hardness; the graphite modified water-coated anticorrosive resin is anticorrosive resin with excellent comprehensive performance.

Description

technical field [0001] The invention belongs to the field of water-based anticorrosion coatings, and in particular relates to a graphene-modified water-coated anticorrosion resin and a preparation method thereof. Background technique [0002] Traditional solvent-based coatings emit a large amount of VOCs into the air during the synthesis and construction process, which is one of the main sources of air pollution, ranking second only to automobile exhaust. With the impact of the oil energy crisis and the enhancement of people's awareness of environmental protection, the paint industry has gradually turned to the direction of saving resources and energy, reducing pollution, benefiting ecological balance and improving economic benefits. At present, the technological development of the coatings industry is mainly reflected in "water-based, powderized, and high-solidification", and solvent-based coatings with a solid content of less than 50% are technologies in decline. Compared...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D191/00C09D7/61C09D5/08
CPCC08K3/04C09D5/08C09D191/00C08L91/00
Inventor 谢海孟庆泉
Owner JIANGSU CHAMPION TECHNOLOGY GROUP CO LTD
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