Heat-resistant graphene conductive thin film and preparation method thereof

A conductive film and graphene technology, applied in the field of heat-resistant graphene conductive film and its preparation, can solve the problems of poor compatibility, reduced mechanical stability of the film, poor heat resistance stability, etc., to achieve enhanced viscosity and improved mechanical stability , Improve the effect of heat resistance stability

Inactive Publication Date: 2018-07-13
查公祥
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Polyaniline has been widely studied and applied because of its easy-to-obtain raw materials, simple synthesis process, and good chemical and environmental stability; polyaniline film is a conductive film, which is widely used in solar cells, electrode materials, displays, etc. Among various optoelectronic materials, however, at present, commercially available polyaniline films have poor heat resistance stability, and in order to improve their heat resistance performance, high heat resistant inorganic fillers are often added therein, because the compatibility between inorganic fillers and polyaniline is poor , which will easily reduce the mechanical stability of the film

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] A heat-resistant graphene conductive film, which is composed of the following parts by weight:

[0025] Graphene 14, diethylene glycol dibenzoate 2, alkanolamide 1, silane coupling agent kh5502, barium stearate 3, stannous sulfide 0.2, heat-resistant polyethylene wax 7, alkylphenol polyoxyethylene ether 0.2, polyaniline 70, ammonium polyphosphate 2, aluminum dihydrogen phosphate 4, triethanolamine 3.

[0026] In the heat-resistant graphene conductive film, the heat-resistant polyethylene wax is composed of the following raw materials in parts by weight:

[0027] Oxidized polyethylene wax 14, calcium acetylacetonate 2, hexamethylphosphoric triamide 1, stannous sulfide 1, glyceryl monostearate 2;

[0028] The preparation method of the heat-resistant polyethylene wax includes the following steps:

[0029] (1) Take stannous sulfide, add it to 10 times its weight in absolute ethanol, stir evenly to obtain an alcohol solution;

[0030] (2) Take the oxidized polyethylene wax, add it to ...

Embodiment 2

[0041] A heat-resistant graphene conductive film, which is composed of the following parts by weight:

[0042] Graphene 10, diethylene glycol dibenzoate 1, alkanolamide 0.8, silane coupling agent kh5501, barium stearate 2, stannous sulfide 0.1, heat-resistant polyethylene wax 5, alkylphenol polyoxyethylene ether 0.1, polyaniline 60, ammonium polyphosphate 1, aluminum dihydrogen phosphate 3, triethanolamine 2.

[0043] In the heat-resistant graphene conductive film, the heat-resistant polyethylene wax is composed of the following raw materials in parts by weight:

[0044] Oxidized polyethylene wax 10, calcium acetylacetonate 1, hexamethylphosphoric triamide 0.7, stannous sulfide 0.7, glyceryl monostearate 1;

[0045] The preparation method of the heat-resistant polyethylene wax includes the following steps:

[0046] (1) Take stannous sulfide, add it to 7 times its weight in absolute ethanol, stir evenly to obtain an alcohol solution;

[0047] (2) Take the oxidized polyethylene wax, add i...

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Abstract

The invention discloses a heat-resistant graphene conductive thin film. The heat-resistant graphene conductive thin film is prepared from the following raw materials in parts by weight: 10 to 14 partsof graphene, 1 to 2 parts of diethylene glycol dibenzoate, 0.8 to 1 part of alkanolamide, 1 to 2 parts of silane coupling agent kh550, 2 to 3 parts of barium stearate, 0.1 to 0.2 part of stannous sulfide, 5 to 7 parts of heat-resistant polyethylene wax, 0.1 to 0.2 part of alkylphenol polyoxyethylene, 60 to 70 parts of polyaniline, 1 to 2 parts of ammonium polyphosphate, 3 to 4 parts of aluminiumdihydrogen phosphate, and 2 to 3 parts of triethanolamine. The heat-resistant graphene conductive thin film has the advantages that by adding the aluminium dihydrogen phosphate, calcium acetylacetonate and the like, the heat-resistant stability of the finished thin film is improved; by adding the aluminium dihydrogen phosphate, the viscosity between the raw materials can be enhanced in the calendering and filming process, thereby further improving the uniform stability of filming.

Description

Technical field [0001] The invention belongs to the field of films, and specifically relates to a heat-resistant graphene conductive film and a preparation method thereof. Background technique [0002] Polyaniline, a kind of polymer compound, has special electrical and optical properties, and can have conductivity and electrochemical properties after being doped. After certain treatments, various devices and materials with special functions can be prepared, such as urease sensors that can be used as biological or chemical sensors, electron field emission sources, and more excellent reversibility in the charge and discharge process than traditional lithium electrode materials. Electrode materials, selective membrane materials, anti-static and electromagnetic shielding materials, conductive fibers, anti-corrosion materials, etc. Polyaniline has been widely studied and applied because of its easy-to-obtain raw materials, simple synthesis process, and good chemical and environmental...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L79/02C08L23/06C08K13/06C08K9/06C08K3/04C08K3/32C08K5/07C08J5/18
CPCC08J5/18C08J2379/02C08J2423/06C08K3/04C08K5/07C08K9/06C08K13/06C08K2003/321
Inventor 查公祥
Owner 查公祥
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