UV viscosity reducing composition, UV viscosity reducing film and preparation method thereof

A composition and film technology, applied in non-polymer organic compound adhesives, conductive adhesives, film/sheet adhesives, etc., can solve the problem that the performance is not completely stable, the residual glue is not easy to remove, and it is easy to adsorb. Dust and other problems, to achieve excellent anti-static effect, high production efficiency, easy to peel effect

Inactive Publication Date: 2018-07-20
SUZHOU CHENGBANG DALI MATERIAL TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In the domestic market, most of the UV viscosifying adhesives used for wafer cutting and picking process protection are mainly in Japan and Taiwan, China. There are also several domestic UV viscosifying adhesives that are developing and promoting, but their performance is not yet fully stable.
Moreover, the base material of the UV anti-adhesive protective film is prone to static electricity due to friction during use, and its use in the field of electronic parts with high static requirements is limited, such as easy to absorb dust, and then transferred to the attached product The surface, or the electrostatic voltage is too high, resulting in defective parts, etc.
In addition, after the current anti-viscosity protective film is used at high temperature, it is easy to cause residual glue that is difficult to remove

Method used

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  • UV viscosity reducing composition, UV viscosity reducing film and preparation method thereof
  • UV viscosity reducing composition, UV viscosity reducing film and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0070] The UV viscosity-reducing composition described in the present embodiment, the raw material composition is as follows:

[0071] 40g high temperature resistant acrylic pressure-sensitive adhesive resin (manufacturer: Changxing Chemical Industry (China) Co., Ltd., model: ETERAC7710), 20g multifunctional oligomer (manufacturer: Huayao Chemical (Wuxi) Co., Ltd., model: UX- 5805W), 1g crosslinking agent (manufacturer: Bayer, Germany, model: N3390), 3g antistatic agent (manufacturer: Shenzhen Huigao Gold Standard Technology Co., Ltd., model: GW-2008), 0.8g dispersant (manufacturer : German BYK company, model: BYK-170), 0.2g leveling agent (manufacturer: German BYK company, model: BYK-333), 5g of 2,4,6-(trimethylbenzoyl) - Diphenylphosphine oxide (TPO), 30 g of butanone.

[0072] Wherein, the UX-5805W is an aliphatic urethane acrylate oligomer.

Embodiment 2

[0074] The UV viscosity-reducing composition described in the present embodiment, the raw material composition is as follows:

[0075] 40g high temperature resistant acrylic pressure-sensitive adhesive resin (manufacturer: Changxing Chemical Industry (China) Co., Ltd., model: ETERAC7710), 20g multifunctional oligomer (manufacturer: Huayao Chemical (Wuxi) Co., Ltd., model: UX- 5805W), 1g crosslinking agent (manufacturer: Bayer, Germany, model: N3390), 2g nano-graphite powder (manufacturer: Shanghai Youmo Composite Materials Co., Ltd.), 0.8g dispersant (manufacturer: BYK, Germany, Model: BYK-164), 0.2g leveling agent (manufacturer: BYK, Germany, model: BYK-306), 5g of 2,4,6-(trimethylbenzoyl)-diphenylphosphine oxide (TPO), 31 g of butanone.

[0076] Wherein, the particle size range of the nano-graphite powder is 50-100nm.

Embodiment 3

[0078] The UV viscosity-reducing composition described in the present embodiment, the raw material composition is as follows:

[0079] 40g high temperature resistant acrylic pressure-sensitive adhesive resin (manufacturer: Changxing Chemical Industry (China) Co., Ltd., model: ETERAC7710), 20g multifunctional oligomer (manufacturer: Huayao Chemical (Wuxi) Co., Ltd., model: UX- 5805W), 1g crosslinking agent (manufacturer: Bayer, Germany, model: N3390), 0.2g nano-graphene (manufacturer: Hefei Microcrystalline Material Technology Co., Ltd.), 0.8g dispersant (manufacturer: BYK, Germany , model: BYK-180), 0.2g leveling agent (manufacturer: BYK, Germany, model: BYK-390), 5g of 2,4,6-(trimethylbenzoyl)-diphenyl oxide Phosphine (TPO), 32.8 g of butanone.

[0080] Wherein, the particle size range of the nano-graphene is 5-20nm.

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Abstract

The invention relates to the technical field of protective films, in particular to an UV viscosity reducing composition, an UV viscosity reducing film and a preparation method thereof. The UV viscosity reducing composition is prepared from the following main raw materials in percent by weight: 20-50% of high temperature-resistant acrylate pressure-sensitive adhesive resin, 1-30% of a polyfunctional oligomer and/or polyfunctional monomer, 0.3-2% of a crosslinking agent, 0.1-5% of an antistatic agent, 0-2% of a dispersant, 0.2-2% of a leveling agent, 0.5-5% of a photoinitiator and 25-60% of a solvent. The UV viscosity reducing film comprises a substrate layer, an UV viscosity reducing layer coated thereon and a release film layer. The UV viscosity reducing composition has an excellent adhesive force, has a high adhesive force and a high release force before UV irradiation, has a low adhesive force, a low release force and a good antistatic effect after UV irradiation, and can resist 120DEG C high temperature for 30 minutes without an adhesive residue.

Description

technical field [0001] The invention relates to the technical field of protective films, in particular to a UV viscous reducing composition, a UV viscous reducing film and a preparation method thereof. Background technique [0002] In the semiconductor manufacturing process, when cutting and polishing semiconductor wafers, in order to reduce the defect density of silicon thin layers, wafer cutting and adhesion-reducing protective films are often used. Anti-adhesive protective film means that the adhesive force is strong when it is used, and the adhesive force is weakened for peeling in the later peeling process. [0003] At present, most of the anti-adhesive protective films on the market are UV anti-adhesive protective films, which means that they have high adhesive force and good adhesion before UV irradiation, and the adhesive force decreases significantly after UV irradiation and is easy to peel off. In the domestic market, most of the UV viscosifying adhesives used for...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09J4/02C09J4/06C09J9/02C09J7/30
CPCC09J4/06C09J9/02C09J2203/326C09J2423/006C09J2427/006C09J2467/005C09J2467/006C09J2301/122C09J2301/312
Inventor 闫勇陈伟
Owner SUZHOU CHENGBANG DALI MATERIAL TECH
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