Heavy oil emulsifier and preparation method thereof

An emulsifier, heavy oil technology, used in the petroleum industry, liquid carbon-containing fuels, fuels, etc., can solve the problems of poor compatibility and thermal stability of non-ionic surfactants, loss, and high prices, to improve fluidity and dilution. Viscosity, the effect of reducing interfacial tension

Inactive Publication Date: 2018-07-20
张可池
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The surfactants used in traditional emulsifiers are mostly petroleum sulfonates, amphoteric surfactants, nonionic surfactants, anion-nonionic surfactants and anion / cation composite surfactants, but each of them has corresponding Defects, such as petroleum sulfonate is easy to adsorb with clay, resulting in a large loss; nonionic surfactants have poor compatibility and thermal stability in the formation; amphoteric surfactants, anion-nonionic surfactants and anion / cation The price of complex surfactants is not only high, some are only in the research and development stage

Method used

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  • Heavy oil emulsifier and preparation method thereof
  • Heavy oil emulsifier and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0038] A kind of heavy oil emulsifier, by weight, its raw material composition is:

[0039] Span-80: 10 servings;

[0040] Tween-60: 12 parts;

[0041] Alkylphenol polyoxyethylene ether: 6 parts;

[0042] Alkylbenzenesulfonic acid: 6 parts;

[0043] Dicarboxybetaine sulfate type zwitterionic gemini surfactant (DBA s-n , s=2, n=8): 4 copies;

[0044] Urea: 0.5 parts;

[0045] Glycerol: 4 parts;

[0046] Stearic acid: 5 parts;

[0047] Deionized water: 20 parts.

[0048] The preparation method of a kind of heavy oil emulsifier as mentioned above, the specific steps are as follows: Span-80, Tween-60, alkylphenol polyoxyethylene ether, alkylbenzenesulfonic acid, dicarboxybetaine sulfate type zwitterionic gemini Surfactant (DBA s-n , s=2, n=8), urea, glycerin, stearic acid and deionized water were added in proportion to the stirred reactor, heated to 45°C, and stirred evenly to prepare the heavy oil emulsifier.

Embodiment 2

[0050] A kind of heavy oil emulsifier, by weight, its raw material composition is:

[0051] Span-80: 12 servings;

[0052] Tween-60: 12 parts;

[0053] Alkylphenol polyoxyethylene ether: 9 parts;

[0054] Alkylbenzenesulfonic acid: 9 parts;

[0055] Dicarboxybetaine sulfate type zwitterionic gemini surfactant (DBA s-n , s=4, n=12): 6 copies;

[0056] Urea: 1.5 parts;

[0057] Glycerol: 8 parts;

[0058] Stearic acid: 8 parts;

[0059] Deionized water: 30 parts.

[0060] The preparation method of a kind of heavy oil emulsifier as mentioned above, the specific steps are as follows: Span-80, Tween-60, alkylphenol polyoxyethylene ether, alkylbenzenesulfonic acid, dicarboxybetaine sulfate type zwitterionic gemini Surfactant (DBA s-n , s=4, n=12), urea, glycerol, stearic acid and deionized water were added in proportion to the stirred reactor, heated to 60°C, and stirred evenly to prepare the heavy oil emulsifier.

Embodiment 3

[0062] A kind of heavy oil emulsifier, by weight, its raw material composition is:

[0063] Span-80: 11 parts;

[0064] Tween-60: 11 parts;

[0065] Alkylphenol polyoxyethylene ether: 8 parts;

[0066] Alkylbenzenesulfonic acid: 8 parts;

[0067] Dicarboxybetaine sulfate type zwitterionic gemini surfactant (DBA s-n , s=6, n=14): 5 copies;

[0068] Urea: 1 part;

[0069] Glycerol: 6 parts;

[0070] Stearic acid: 6 parts;

[0071] Deionized water: 25 parts.

[0072] The preparation method of a kind of heavy oil emulsifier as mentioned above, the specific steps are as follows: Span-80, Tween-60, alkylphenol polyoxyethylene ether, alkylbenzenesulfonic acid, dicarboxybetaine sulfate type zwitterionic gemini Surfactant (DBA s-n , s=6, n=14), urea, glycerin, stearic acid and deionized water were added in proportion to the stirred reactor, heated to 40°C, and stirred evenly to prepare the heavy oil emulsifier.

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Abstract

The invention discloses a heavy oil emulsifier and a preparation method thereof. The heavy oil emulsifier is prepared from the raw materials in parts by weight: 10 to 12 parts of span-80, 10 to 12 parts of tween-60, 6 to 9 parts of alkylphenol ethoxylates, 6 to 9 parts of alkyl benzene sulfonic acid, 4 to 6 parts of dicarboxyl sulfuric acid betaine type zwitter-ion dimeric surfactant, 0.5 to 1.5 parts of urea, 4 to 8 parts of glycerol, 5 to 8 parts of stearic acid, and 20 to 30 parts of deionized water. According to the heavy oil emulsifier provided by the invention, the oil / water interface tension can be remarkably reduced, so that water drops are stably dispersed into heavy oil for a long term so as to form a stable microemulsion system; the heavy oil viscosity is greatly diluted, so that the fluidity is improved, and the heavy oil emulsifier can be widely applied to the fields such as thickened oil recovery and transportation, industrial burnup, heavy oil fluid catalytic cracking and casting techniques, and has a broad market prospect.

Description

technical field [0001] The invention belongs to the field of heavy oil emulsifiers, in particular to a heavy oil emulsifier and a preparation method thereof. Background technique [0002] Heavy oil, also called residual oil, is the remaining heavy oil after gasoline and diesel oil are extracted from crude oil. It is characterized by large molecular weight, high viscosity and complex composition. Due to the complex composition of heavy oil, which contains a variety of harmful substances (such as sulfur, sodium, vanadium, etc.), heavy oil will cause serious corrosion to metal equipment when it is burned. [0003] In the past, physical and chemical methods were used to make viscous heavy oil into a fluid with good fluidity at room temperature, so as to achieve the purpose of heavy oil production, transportation and industrial combustion without steam heating and heat tracing. However, traditional physical or chemical methods are costly. At present, heavy oil emulsification tec...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C10L1/19C10L1/198C10L1/24C10L1/224C10L1/182C10L1/188C10L1/32
Inventor 张可池张昂
Owner 张可池
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