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Laser cladding forming method for single-crystal MCrAlY coating on single-crystal high-temperature alloy matrix

A high-temperature alloy and laser cladding technology, which is applied in the direction of metal material coating process, coating, crystal growth, etc., can solve the problems of discontinuity, performance discontinuity, and reducing the service life of blades, etc., and achieve fine dendrite structure, combined excellent effect

Active Publication Date: 2018-07-27
INST OF METAL RESEARCH - CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The microstructure of the traditional MCrAlY coating is polycrystalline, which is quite different from the single crystal superalloy, which is the first material of the current advanced aero-engine blades, in phase structure, which is easy to cause the physical properties of the coating / substrate interface (such as: thermal expansion) and Discontinuities in mechanical properties (e.g. elastic modulus, creep strength)
During blade service, this performance discontinuity can reduce the service life of the blade

Method used

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  • Laser cladding forming method for single-crystal MCrAlY coating on single-crystal high-temperature alloy matrix
  • Laser cladding forming method for single-crystal MCrAlY coating on single-crystal high-temperature alloy matrix
  • Laser cladding forming method for single-crystal MCrAlY coating on single-crystal high-temperature alloy matrix

Examples

Experimental program
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Effect test

Embodiment 1

[0038] In this example, a single crystal MCrAlY coating is prepared on the first generation single crystal superalloy SRR99 substrate according to the method described in the technical solution of the present invention. SRR99 single crystal superalloy rods were prepared by the traditional spiral selection method, and the rod diameter was Φ16mm. The alloy bars were solution heat treated at 1295°C / 4h. Then, a base material is cut out from the single crystal alloy rod. The MCrAlY coating powder required in this example is TMBC-1 powder prepared by argon atomization, and the powder particle size is -100 to +300 mesh. Before laser cladding, the surface of the single crystal alloy substrate to be clad is polished with 240# sandpaper, and then sandblasted with corundum sand. The airflow pressure during sandblasting is 2.2MPa, and the surface roughness after sandblasting is 0.9Ra. The MCrAlY powder was dried at 150°C / 1h. When cladding, the laser power used is 600w, the laser spot d...

Embodiment 2

[0040]In this embodiment, a single crystal MCrAlY coating is prepared on the second-generation single crystal superalloy RenéN5 substrate according to the method described in the technical solution of the present invention. The oriented RenéN5 single crystal superalloy rods were prepared by the traditional seed crystal method, and the rod diameter was Φ16mm. The alloy bar was subjected to solution treatment at 1300°C / 4h, and the base material was cut from the bar. The angle between the normal direction of the substrate surface and the direction of the substrate is not greater than 10°. The MCrAlY coating powder used in this example is TMBC-1 powder prepared by argon atomization, and the powder particle size is -100 to +450 mesh. Before laser cladding, the surface of the alloy substrate was polished with 150# sandpaper, and then sandblasted with corundum sand. The air pressure during sandblasting was 2.0MPa, and the surface roughness after sandblasting was 0.8Ra. The MCrAlY...

Embodiment 3

[0042] In this example, a single crystal MCrAlY coating is prepared on the second generation single crystal superalloy CMSX-4 substrate according to the method described in the technical solution of the present invention. CMSX-4 single crystal superalloy rods were prepared by the traditional spiral selection method. After the rod is subjected to solution heat treatment at 1300°C / 4h, the base material is cut by wire cutting, and the angle between the normal line direction of the base material surface and the direction of the base material is not greater than 10°. In this example, the TMBC-1 powder prepared by argon atomization was used as the coating powder, and the powder particle size was -100 to +450 mesh. Before cladding, the surface of the alloy substrate was polished with 240# sandpaper and sandblasted with 2.2MPa corundum sand, and the surface roughness after sandblasting was 0.9Ra. When cladding, the laser power used is 1000w, the laser spot diameter is 0.9mm, the pro...

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Abstract

The invention relates to the field of high-temperature protection coating preparation, in particular to a laser cladding forming method for a single-crystal MCrAlY coating on a single-crystal high-temperature alloy matrix. The method comprises the steps that a single-crystal high-temperature alloy sample surface to be cladded with the coating is subjected to sand papering and sand blasting processing to ensure that no oxidation film or other impurities exist on the sample surface; according to the shape of the single-crystal high-temperature alloy sample surface, computer software is used forplanning a laser scanning path; cladding forming is carried out through a laser beam according to the planned path in a coaxial powder conveying way; and finally, annealing treatment is carried out atthe specific temperature to obtain a stress-free coating structure with the good element ingredients and microscopic structure. According to the MCrAlY coating prepared through the method, the crystal orientation is the same as the alloy matrix, the contact face between the coating and the matrix can form compact metallurgical bonding, and stripping is not likely to occur in the service process.

Description

Technical field: [0001] The invention relates to the field of preparation of high temperature protective coatings, in particular to a laser cladding forming method for a single crystal MCrAlY coating on a single crystal high temperature alloy substrate. Background technique: [0002] In order to develop high-thrust, high-efficiency and low-fuel-consumption aero-engines, it is necessary to improve the temperature-bearing capacity of turbine blades. The increase in the thermal capacity of turbine blades can exacerbate the corrosion and oxidation of the blades, leading to their premature failure, for which a high temperature protective coating must be applied to the blade surface. MCrAlY coating has excellent high temperature oxidation corrosion resistance and flexibility of composition selection, and has been widely used in aero-engines as the metal bonding layer of surface cladding coating and thermal barrier coating. The microstructure of the traditional MCrAlY coating is p...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C23C24/10C30B29/52C30B33/02
CPCC23C24/106C30B29/52C30B33/02
Inventor 梁静静杨彦红周亦胄金涛孙晓峰
Owner INST OF METAL RESEARCH - CHINESE ACAD OF SCI