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Thin-walled large specification honeycomb ceramic carrier and preparation method thereof

A honeycomb ceramic carrier, large-scale technology, applied in the direction of ceramic products, catalyst carriers, chemical instruments and methods, etc., can solve the problems of lack of lattice walls, increased mold pressure, increased extrusion force, etc., to achieve high mechanical strength and resistance Effects of thermal decomposition, wear reduction, and fluidity improvement

Inactive Publication Date: 2018-11-02
安徽中都环宇新材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] With the increasingly stringent regulations on automobile exhaust emissions, the honeycomb ceramic carrier for automobile exhaust purification is also developing in the direction of high pore density and thinner lattice wall. When using the same mud material as the existing honeycomb ceramic carrier When the thin-walled ceramic carrier is used, since the mud channel becomes much narrower, the extrusion force required for the mud in the mold channel will greatly increase, and at the same time, the mud will not be able to keep up, which will lead to two problems Problem: On the one hand, it will greatly increase the pressure on the mold, aggravate the damage of the mold, and even exceed the pressure range that the mold can withstand; on the other hand, the state that the mud cannot keep up will cause defects in the molded products Lattice walls or simply can not form a continuous qualified product

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] The invention provides a thin-walled and large-sized honeycomb ceramic carrier. The raw materials in parts by weight include: 20.4 parts of kaolin, 21.7 parts of alumina, 5.2 parts of silicon dioxide, 29.6 parts of talc, 1.6 parts of aluminum titanate micropowder, and zirconium phosphate. 0.7 parts, 1.2 parts of cerium phosphate, 1.1 parts of hydroxypropyl methylcellulose, 4.7 parts of glycerin, and 26.9 parts of water.

[0029] Among them, the particle size of kaolin is 2 μm, the particle size of alumina is 7 μm, the particle size of silica is 5 μm, the particle size of talc is 10 μm, the particle size of aluminum titanate powder is 0.4 μm, and the particle size of zirconium phosphate is 0.4 μm. is 3 μm, and the particle size of cerium phosphate is 2 μm.

Embodiment 2

[0031] The invention provides a thin-walled and large-sized honeycomb ceramic carrier. The raw materials in parts by weight include: 22.1 parts of kaolin, 20.5 parts of alumina, 7.8 parts of silicon dioxide, 25.4 parts of talc, 1.9 parts of aluminum titanate micropowder, zirconium phosphate 1.1 parts, 0.9 parts of cerium phosphate, 1.3 parts of hydroxypropyl methylcellulose, 4.4 parts of glycerin, and 28.2 parts of water.

[0032] Among them, the particle size of kaolin is 3 μm, the particle size of alumina is 6 μm, the particle size of silica is 6 μm, the particle size of talc is 9 μm, the particle size of aluminum titanate powder is 0.5 μm, and the particle size of zirconium phosphate is 0.5 μm. is 2 μm, and the particle size of cerium phosphate is 4 μm.

Embodiment 3

[0034] The invention provides a thin-walled and large-sized honeycomb ceramic carrier. The raw materials in parts by weight include: 23.7 parts of kaolin, 18.9 parts of alumina, 6.1 parts of silicon dioxide, 26.7 parts of talc, 1.2 parts of aluminum titanate micropowder, zirconium phosphate 1.3 parts, 0.6 parts of cerium phosphate, 0.6 parts of hydroxypropyl methylcellulose, 4.8 parts of glycerin, and 25.5 parts of water.

[0035] Among them, the particle size of kaolin is 4 μm, the particle size of alumina is 8 μm, the particle size of silica is 4 μm, the particle size of talc is 8 μm, the particle size of aluminum titanate fine powder is 0.3 μm, and the particle size of zirconium phosphate is 0.3 μm. is 4 μm, and the particle size of cerium phosphate is 5 μm.

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Abstract

The invention discloses a thin-walled large specification honeycomb ceramic carrier and a preparation method thereof. Raw materials of the carrier comprise kaolin, aluminum oxide, silicon dioxide, talc powder, aluminum titanate micropowder and the like. The preparation method comprises the following steps: mixing kaolin, aluminum oxide, silicon dioxide, talc powder, aluminum titanate micropowder,zirconium phosphate and cerous phosphate, and uniformly stirring the mixture to obtain a mixed material; adding glycerin and hydroxypropyl methyl cellulose into water to obtain an additive solution; mixing the mixed material with the additive solution, uniformly stirring the mixture, and carrying out kneading, ageing and vacuum pugging to obtain a pug; and extruding the pug under pressure by meansof a mold to obtain a cylindrical honeycomb ceramic wet blank, and drying and roasting the cylindrical honeycomb ceramic wet blank to obtain the thin-walled large specification honeycomb ceramic carrier. The disc diameter of the thin-walled large specification honeycomb ceramic carrier provided by the invention can reach 300-350 mm, the pore density can reach 300-400 pore / sq. inch, and the thin-walled large specification honeycomb ceramic carrier meets the demand of treating tail gas of a large discharge diesel vehicle.

Description

technical field [0001] The invention relates to the field of preparation of a honeycomb ceramic carrier, in particular to a thin-walled and large-sized honeycomb ceramic carrier and a preparation method thereof. Background technique [0002] With the continuous improvement of the level of industrialization, the share of vehicle exhaust pollution in urban air pollution is getting higher and higher, and vehicle exhaust control technology has great social significance for energy conservation and emission reduction. The monolithic honeycomb is a thin-walled, parallel porous cylinder with large specific surface area, good thermal stability, high temperature resistance and not easy to break. With the expansion of the application of honeycomb ceramic carriers in the catalytic purification industry, and the incomparable advantages of honeycomb ceramics as catalyst carriers, honeycomb ceramics have penetrated into various fields of air pollution prevention and control, especially in ...

Claims

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Application Information

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IPC IPC(8): C04B38/00C04B35/20C04B35/478C04B35/622C04B35/626B01J35/04B01J32/00
CPCC04B35/20C04B35/478C04B35/622C04B35/62605C04B38/0006C04B2235/3217C04B2235/3418C04B2235/349C04B2235/447B01J35/56
Inventor 李高升于永启张靖
Owner 安徽中都环宇新材料科技有限公司
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