The invention relates to a preparation method of a high-temperature oxidation-resistant
silicide coating containing a composite
diffusion-resistant layer, the high-temperature oxidation-resistant
silicide coating comprises a MoSi2 outer layer, a WSi2-YSZ
diffusion-resistant layer and a thin NbSi2 and Nb5Si3 mutual
diffusion layer between the WSi2-YSZ diffusion-resistant layer and a substrate, the outer layer provides good high-temperature
oxidation resistance for the
coating, the diffusion-resistant layer can effectively slow down element mutual diffusion between the coating and the substrate, and the high-temperature oxidation-resistant
silicide coating has good
oxidation resistance. The loss of the beneficial element Si is reduced, metallurgical bonding is formed between the mutual
diffusion layer and the matrix, and the
interface bonding between the external coating and the matrix can be improved. According to the method, a YSZ resistance
diffusion layer sample containing WSi 2-20% is subjected to constant-temperature oxidation at the temperature of 1400 DEG C for 100 h, and then the oxidation weight of the sample is increased by 1.5 mg / cm < 2 >; meanwhile, compared with an unimpeded
diffusion layer sintering sample, the thickness of an oxidation film and the thickness of a diffusion layer are reduced by 28.5% and 29.2% respectively after oxidation is conducted for 100 h, the oxidation film does not peel off, and the coating is well combined with a matrix
alloy interface.