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Method for preparing self-compacting concrete by using herbal pulp waste liquid

A technology for self-compacting concrete and pulp waste liquid, applied in the field of self-compacting concrete and preparing self-compacting concrete, can solve the problems of low consumption of papermaking black liquor, high cost, not more than 0.3wt%, etc. Water-cement ratio, the effect of improving overall performance

Active Publication Date: 2021-01-01
JIANGSU UNIV OF SCI & TECH IND TECH RES INST OF ZHANGJIAGANG
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although such an application scheme is green and environmentally friendly, it needs to separate lignin from the papermaking black liquor, and its usage in concrete should generally not exceed 0.3wt%. The cost is high and the consumption of papermaking black liquor is small. Other large solids separated from the black liquor need to be post-treated

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] Embodiment 1 A kind of method that utilizes herbal pulp waste liquid to prepare self-compacting concrete, it comprises the following concrete steps:

[0023] (1) filter out suspended matter and silt in the herbaceous pulp waste liquid with a sieve, and retain the filtrate;

[0024] (2) After mixing 10 parts by weight of the suspended matter and silt with 80 parts by weight of titanium gypsum, 5 parts by weight of blast furnace slag, 10 parts by weight of quicklime powder and 5 parts by weight of kaolin powder, the Sintering under conditions, and then ball milling at a speed of 400 rpm for more than 1 hour to form powder;

[0025] (3) filtering the filtrate obtained in step (1) with a hollow fiber ultrafiltration membrane, and collecting the filtrate;

[0026] (4) adding the filtrate obtained in step (3) into a sulfuric acid solution with a concentration of 1 wt% and immersing it for 1 hour, then filtering it out with a hollow fiber ultrafiltration membrane, and then dr...

Embodiment 2

[0031] Embodiment 2 A kind of method that utilizes herbal pulp waste liquid to prepare self-compacting concrete, it comprises the following concrete steps:

[0032] (1) filter out suspended matter and silt in the herbaceous pulp waste liquid with a sieve, and retain the filtrate;

[0033] (2) After mixing 10 parts by weight of the suspended solids and silt with 90 parts by weight of titanium gypsum, 10 parts by weight of blast furnace steel slag, 5 parts by weight of quicklime powder and 15 parts by weight of kaolin powder, the Sintering under the same conditions, and then ball milling at a speed of 250 rpm for more than 1 hour to form a powder;

[0034] (3) filtering the filtrate obtained in step (1) with a hollow fiber ultrafiltration membrane, and collecting the filtrate;

[0035] (4) adding the filtrate obtained in step (3) into a sulfuric acid solution with a concentration of 3 wt% and immersing it for 1 hour, then filtering it out with a hollow fiber ultrafiltration mem...

Embodiment 3

[0040] Embodiment 3 A kind of method that utilizes herbal pulp waste liquid to prepare self-compacting concrete, it comprises the following specific steps:

[0041] (1) filter out suspended matter and silt in the herbaceous pulp waste liquid with a sieve, and retain the filtrate;

[0042] (2) After mixing 10 parts by weight of the suspended matter and silt with 83 parts by weight of titanium gypsum, 6 parts by weight of blast furnace slag, 8 parts by weight of quicklime powder, and 12 parts by weight of kaolin powder, the Sintering under the same conditions, and then ball milling at a speed of 300 rpm for more than 1 hour to form a powder;

[0043] (3) filtering the filtrate obtained in step (1) with a hollow fiber ultrafiltration membrane, and collecting the filtrate;

[0044] (4) adding the filtrate obtained in step (3) into a sulfuric acid solution with a concentration of 1 wt% and immersing it for 1 hour, then filtering it out with a hollow fiber ultrafiltration membrane,...

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Abstract

The invention discloses a method for preparing self-compacting concrete by utilizing a herbal paper pulp waste liquid. The method comprises the following steps: filtering suspended substances and sediments out of the herbal paper pulp waste liquid, subjecting the suspended substances and the sediments to co-sintering with titanium gypsum and the like so as to obtain a powder material, blending substances filtered out of a filtrate through a hollow fiber ultrafiltration film with a plurality of substances like sodium sulfite and polyaniline so as to obtain an additive, and mixing the additive with the powder material, fine aggregate, coarse aggregate, water and the like so as to prepare the self-compacting concrete. According to the invention, main pollution components are separated from the herbal paper pulp waste liquid and used as auxiliary components of the self-compacting concrete after simple treatment, so environmental protection treatment of a large amount of the herbal paper pulp waste liquid can be realized; and comprehensive performances of the self-compacting concrete can be greatly improved, e.g., a water-cement ratio can be greatly reduced; the strength, compactness, compressive strength, tensile strength, heat and frost resistance, salting resistance and permeability resistance of the self-compacting concrete are improved; the service life of the self-compacting concrete is long; and corrosion of reinforcing steel bars to the self-compacting concrete can be greatly retarded.

Description

technical field [0001] The invention relates to a self-compacting concrete, in particular to a method for preparing self-compacting concrete by using herbal pulp waste liquid, and belongs to the field of building materials. Background technique [0002] Lignin is the second largest renewable resource in nature, regenerated at a quality of 50 billion tons per year, but lignin is difficult to be metabolized and degraded by microorganisms, and is often discharged as waste in the biomass industry. my country's paper industry mainly uses various wood and herbaceous plants as raw materials, such as poplar, eucalyptus, reed, wheat straw and bagasse. The paper industry discharges a large amount of foul smelling and toxic black liquor, the main component of which is alkali lignin that cannot be used by microorganisms. It is estimated that the annual discharge of lignin by my country's paper industry is as high as 40 million tons. At present, the main way to deal with the lignin in t...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C04B28/14C04B111/20C04B111/26C04B111/27
CPCC04B28/142C04B2111/20C04B2111/26C04B2111/27C04B2111/29C04B2201/50C04B22/064C04B18/141C04B14/106C04B22/14C04B24/02C04B24/28C04B14/386C04B14/064C04B22/04C04B14/00C04B18/241
Inventor 马剑吴春杨江飞飞王静芳谢海舰
Owner JIANGSU UNIV OF SCI & TECH IND TECH RES INST OF ZHANGJIAGANG
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