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Graphene-based high-temperature coating and preparation method thereof

A graphene-based, graphene-based technology, used in anti-corrosion coatings, alkali metal silicate coatings, coatings, etc., can solve the problems of high strength, high wear resistance, high toughness, corrosion resistance, oxidation resistance, high temperature resistance, loss of Protection effect, surface cracking of alloy coating, etc., to achieve the effect of construction difficulty and cost reduction

Inactive Publication Date: 2018-12-18
深圳陶金材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The high temperature anti-ceramic coating materials widely used at present have the advantages of high hardness, high wear resistance, corrosion resistance and high temperature oxidation resistance. However, in some more extreme application fields, such as thermal power plant boilers, high temperature heat exchangers, etc. In equipment such as waste heat boilers, cement kilns, and chemical reaction vessels, in addition to high temperature and oxidizing conditions, they are also accompanied by hydrothermal and corrosive gas environments, and are subjected to dust and thermal shock shocks, resulting in surface cracking and corrosion burning of alloy coatings. Corrosion, local shedding and other problems, loss of protective effect, and even cause production accidents
The current alloy materials cannot meet the application requirements of high strength, high wear resistance, high toughness, corrosion resistance, oxidation resistance and high temperature resistance.

Method used

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  • Graphene-based high-temperature coating and preparation method thereof
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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0039] Preparation of graphene dispersion: First, 2.4 kg of boron nitride nanosheets and 25.2 kg of water were stirred and dispersed at a high speed of 1500 rad / min for 10 minutes, and then 2.4 kg of graphene nanosheets were added to it, continued high-speed stirring for 20 minutes and ultrasonication for 10 minutes to obtain Uniform and stable graphene dispersion;

[0040] Preparation of graphene high-temperature coating: add 35 kg of water glass solution and 7 kg of water into a stirring container, then add the graphene dispersion obtained above under the condition of high-speed stirring at 1500 rad / min, and continue to add 14 kg of zirconia powder after stirring evenly and 14 kilograms of metal nickel powder, after mixing and stirring, use a sand mill to grind it to a fineness below 15 μm, and filter to obtain the required graphene-based high-temperature coating.

Embodiment 2

[0042] Preparation of graphene dispersion: First, 1 kg of boron nitride nanosheets and 18 kg of water were stirred and dispersed at a high speed of 1500 rad / min for 10 minutes, then 1 kg of graphene nanobelts were added to it, continued high-speed stirring for 20 minutes and ultrasonication for 10 minutes to obtain Uniform and stable graphene dispersion;

[0043] Preparation of graphene high-temperature coating: Add 32 kg of aluminum dihydrogen phosphate aqueous solution and 23.2 kg of water into the stirring container, then add the graphene dispersion obtained above under the condition of high-speed stirring at 1500 rad / min, and continue to add 12 kg of alumina after stirring evenly The powder and 12.8 kg of aluminum-silicon alloy powder are mixed and evenly ground with a sand mill until the fineness is below 15 μm, and filtered to obtain the required graphene-based high-temperature coating.

Embodiment 3

[0045] Preparation of graphene dispersion: First, 2.8 kg of boron nitride nanosheets and 31.15 kg of water were stirred and dispersed at a high speed of 1500 rad / min for 10 minutes, then 1.05 kg of multilayer graphene was added to it, continued high-speed stirring for 20 minutes and ultrasonication for 10 minutes to obtain Uniform and stable graphene dispersion;

[0046] Preparation of graphene high-temperature coating: Add 16.25 kg of silica sol aqueous solution and 16.25 kg of water into the stirring container, then add the graphene dispersion obtained above under the condition of high-speed stirring at 1500 rad / min, and continue to add 19.5 kg of silicon nitride powder after stirring evenly Body and 13 kg of chromium powder, after mixing and stirring, use a sand mill to grind it to a fineness below 15 μm, and filter to obtain the required graphene-based high-temperature coating.

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Abstract

The invention provides a graphene-based high-temperature coating. The graphene-based high-temperature coating is composed of a high-temperature coating main body and graphene dispersion liquid. In thegraphene-based high-temperature coating, the mass percentage of the coating main body is 40% to 80%, and the mass percentage of the graphene dispersion liquid is 20%-60%, the graphene dispersion liquid includes graphene, boron nitride nanosheet and water, and the graphene is uniformly dispersed in the coating main body by forming a Pi-Pi bond with the boron nitride nanosheet. The invention also provides a preparation method of the graphene-based high-temperature coating. The dispersion effect of graphene in the coating is good, so that the high-temperature coating can meet the application requirements of high strength, high wear resistance, high toughness, corrosion resistance, oxidation resistance, high temperature resistance and the like, and the construction cost is low.

Description

technical field [0001] The invention relates to a graphene-based high-temperature coating and a preparation method thereof, and is especially suitable for long-term heat-resistant and corrosion-resistant protection of metal materials in a high-temperature environment. Background technique [0002] As the industry has higher and higher requirements for materials and structures operating in high-temperature environments, people have developed a variety of high-temperature protective coatings for metal corrosion, from traditional single-layer coatings to multi-layer coatings. Composite gradient coating, coating materials from pure metal materials to current alloy coatings, ceramic coatings and composite coatings of metal materials and ceramic materials, and endow the coating materials with anti-corrosion, anti-oxidation protection and some special coatings. function etc. The coating material has developed from simple aluminide coating to the current ceramic thermal barrier coa...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D1/02C09D1/00C09D5/08C09D7/61
CPCC09D1/00C09D1/02C09D5/08C09D7/61
Inventor 戴雷唐知桥王亚文刘春艳
Owner 深圳陶金材料科技有限公司