A kind of preparation method of ion exchange membrane with ordered ion conduction structure
An ion-exchange membrane and ion-conducting technology, applied in the field of ion-conducting polymer material preparation, can solve the problems of performance stability and service durability reduction, and achieve the effects of enhanced stability, broad application prospects, and reduced water absorption.
- Summary
- Abstract
- Description
- Claims
- Application Information
AI Technical Summary
Problems solved by technology
Method used
Image
Examples
Embodiment 1
[0039] (1) Preparation of polymers containing metal coordination structures The proportion x of the chain segment containing the metal coordination structure is 50%, and the specific steps are: dissolve 1.6g of pentacyanamide iron sodium salt and 3.8g of 15-crown-5 in 10ml of water, and dissolve 0.4g of polyvinylpyridine in 10ml of methanol , mix the two solutions, react at 40°C for 36h, pour the reaction solution into water, wash the precipitate with 1mol / L dilute sulfuric acid for 3 times, then wash with ultrapure water until pH = 7, and then dry at 80°C for 12h. product;
[0040] (2) Dissolve this polymer containing metal coordination structure in dimethylacetamide together with polysulfone and phosphotungstic acid in a mass ratio of 5:45:50, so that the total concentration of the solute is 500g / The film-making solution of L, after fully dissolving, let it stand for defoaming;
[0041] (3) Pour the film-making solution into a petri dish, and evaporate the solvent at 80°...
Embodiment 2
[0050] (1) Preparation of polymers containing metal coordination structures The chain segment ratio x of the metal-containing coordination structure is 80%. The specific steps are: dissolve 1g styrene, 5g dimethylsilyl bridged nickelocene, 0.1g tetramethylpiperidine oxide and 0.3g azobisisobutyronitrile React in 100ml of toluene at 130°C for 12h under the protection of nitrogen, pour the reaction solution into water, wash the precipitate with ultrapure water until pH = 7, then dry at 80°C for 12h to obtain the product;
[0051] (2) The polymer containing the metal coordination structure is dissolved in dimethylformamide together with the magnesium-aluminum layered double hydroxide in a ratio of 75:25 by mass, and the total concentration of the solute is 100g / The film-making solution of L, after fully dissolving, let it stand for defoaming;
[0052] (3) Pour the film-making solution into a petri dish, and evaporate the solvent at 20° C. for 48 hours to form a film under the ...
Embodiment 3
[0057] (1) Preparation of polymers containing metal coordination structures The chain segment ratio x of the metal-containing coordination structure is 100%. The specific steps are: dissolve 3g of vinylcobaltocene, 0.1g of tetramethylpiperidine oxide and 0.3g of azobisisobutyronitrile in 100ml of toluene, and protect React at 130°C for 12 hours, then lower the temperature to room temperature, add 1g tetracyanoethylene solution in 20ml toluene with a syringe, continue to react for 12 hours, pour the reaction solution into water, soak the precipitate in 1mol / L sodium hydroxide for 12 hours, and then use super Wash with pure water to pH = 7, then dry at 80°C for 12 hours to obtain the product;
[0058] (2) This polymer containing the metal coordination structure is dissolved in nitrogen methyl pyrrolidone alone, and made into a film-making solution with a total concentration of solute of 10g / L, which is fully dissolved and allowed to stand for defoaming;
[0059] (3) Pour the f...
PUM
| Property | Measurement | Unit |
|---|---|---|
| electrical conductivity | aaaaa | aaaaa |
| electrical conductivity | aaaaa | aaaaa |
| electrical conductivity | aaaaa | aaaaa |
Abstract
Description
Claims
Application Information
Login to View More 
PatSnap Eureka turns technology decisions into work you can execute. Powered by our Innovation Knowledge Graph, it runs expert workflows across engineering, life sciences, materials and intellectual property. Get your review-ready output in minutes.
