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Starch-based biodegradable bionic bait added with modified nano calcium carbonate

A technology of nano-calcium carbonate and bionic bait, applied in the field of bionic bait, can solve problems such as poor mechanical properties, achieve excellent modification effect, reduce agglomeration, and improve dispersion and stability

Inactive Publication Date: 2018-12-25
界首市汇珠渔具有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0012] Strong, and the mechanical properties are poor, so improving the mechanical properties and improving its water resistance have become the main problems to be solved urgently.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0035] A starch-based biodegradable bionic bait added with modified nano-calcium carbonate is characterized in that it comprises the following steps:

[0036] (1) Composite hydrophobic modification of dialdehyde starch:

[0037] Dry the dialdehyde starch in an oven at 128-132°C for 1 hour, ultrasonically treat it at 74-76°C for 15 minutes, add 1.3 parts of coupling agent tetrabutyl titanate, stir and react at 74-76°C for 15 minutes, then add 0.9 parts Hydrophobic agent stearic acid, stirred and reacted at 74-76°C for 15 minutes, and dried in an oven at 128-132°C to obtain highly hydrophobic starch;

[0038] (2) High-speed stirring modification of nano calcium carbonate:

[0039] Add 0.5 parts of modifier hyperbranched polyester and 10 parts of nano-calcium carbonate to 50 parts of modified solvent DMF, put them into a high-speed mixer, stir and react at a high speed in a constant temperature water bath at 73-77°C for 1 hour, then vacuum filter and dry , grinding, and passing...

Embodiment 2

[0050] A starch-based biodegradable bionic bait added with modified nano-calcium carbonate is characterized in that it comprises the following steps:

[0051] (1) Composite hydrophobic modification of dialdehyde starch:

[0052] Dry dialdehyde starch in an oven at 128-132°C for 2 hours, ultrasonically treat at 74-76°C for 20 minutes, add 1.5 parts of coupling agent tetrabutyl titanate, stir and react at 74-76°C for 20 minutes, then add 1 part Hydrophobic agent stearic acid, stirred and reacted at 74-76°C for 20 minutes, dried in an oven at 128-132°C to obtain highly hydrophobic starch;

[0053] (2) High-speed stirring modification of nano calcium carbonate:

[0054] Add 1 part of modifier hyperbranched polyester and 12 parts of nano-calcium carbonate to 55 parts of modified solvent DMF, put them into a high-speed mixer, stir and react at a high speed in a constant temperature water bath at 73-77°C for 2 hours, then vacuum filter and dry , grinding, and passing through a 200-me...

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PUM

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Abstract

The invention discloses starch-based biodegradable bionic bait added with modified nano calcium carbonate. A preparation method of the starch-based biodegradable bionic bait includes: evenly dispersing high hydrophobic modified dialdehyde starch in distilled water, heating for gelatinization, adding polylactic acid, polyvinyl alcohol and plasticizer glycerin, sufficiently mechanically evenly stirring and mixing, adding preprocessed jute fibers, high-speed stirring modified nano calcium carbonate, stirring, and adding into a single-screw extruder to prepare master batch; evenly pacing the master batch into a mould of the bionic bait, prepressing the mould in a plate vulcanizing machine, and performing hot-press molding. The high hydrophobic modified dialdehyde starch, the polylactic acid and the polyvinyl alcohol are used as the raw materials, the modified nano calcium carbonate and the preprocessed jute fibers are added, and the starch-based biodegradable bionic bait is prepared through the compounding of the materials above; by adding the jute fibers which has a lot of hydroxyl on the surface, the blending compatibility of the dialdehyde starch and polyvinyl alcohol can be increased, and mechanical performance is increased while the water resistance of the bait is increased.

Description

technical field [0001] The invention belongs to the field of bionic fishing bait, in particular to a starch-based biodegradable bionic fishing bait added with modified nano-calcium carbonate. Background technique [0002] Starch is a polysaccharide compound, which is a natural polymer material with a wide range of sources. Starch has a wide range of applications in textiles, papermaking, and petroleum industries. Since the 1960s, with the dwindling of the earth's oil resources and the gradual aggravation of environmental degradation caused by plastic white pollution, biodegradable plastics have been favored by research at home and abroad. Due to the good biodegradability of starch, the research on biomass as a biodegradable plastic has achieved certain results. However, the inherent polyhydroxyl structure of native starch makes it highly polar, resulting in poor compatibility between starch and non-polar or weakly polar synthetic resins, which limits its application in biod...

Claims

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Application Information

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IPC IPC(8): C08L3/04C08L67/04C08L29/04C08L1/02C08K9/04C08K3/26C08K5/053C08B31/18
CPCC08B31/185C08K2003/265C08K2201/011C08L3/04C08L2201/06C08L2205/035C08L2205/16C08L67/04C08L29/04C08L1/02C08K9/08C08K3/26C08K5/053
Inventor 朱银忠
Owner 界首市汇珠渔具有限公司
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