Starch-based biodegradable bionic bait added with modified nano calcium carbonate
A technology of nano-calcium carbonate and bionic bait, applied in the field of bionic bait, can solve problems such as poor mechanical properties, achieve excellent modification effect, reduce agglomeration, and improve dispersion and stability
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Embodiment 1
[0035] A starch-based biodegradable bionic bait added with modified nano-calcium carbonate is characterized in that it comprises the following steps:
[0036] (1) Composite hydrophobic modification of dialdehyde starch:
[0037] Dry the dialdehyde starch in an oven at 128-132°C for 1 hour, ultrasonically treat it at 74-76°C for 15 minutes, add 1.3 parts of coupling agent tetrabutyl titanate, stir and react at 74-76°C for 15 minutes, then add 0.9 parts Hydrophobic agent stearic acid, stirred and reacted at 74-76°C for 15 minutes, and dried in an oven at 128-132°C to obtain highly hydrophobic starch;
[0038] (2) High-speed stirring modification of nano calcium carbonate:
[0039] Add 0.5 parts of modifier hyperbranched polyester and 10 parts of nano-calcium carbonate to 50 parts of modified solvent DMF, put them into a high-speed mixer, stir and react at a high speed in a constant temperature water bath at 73-77°C for 1 hour, then vacuum filter and dry , grinding, and passing...
Embodiment 2
[0050] A starch-based biodegradable bionic bait added with modified nano-calcium carbonate is characterized in that it comprises the following steps:
[0051] (1) Composite hydrophobic modification of dialdehyde starch:
[0052] Dry dialdehyde starch in an oven at 128-132°C for 2 hours, ultrasonically treat at 74-76°C for 20 minutes, add 1.5 parts of coupling agent tetrabutyl titanate, stir and react at 74-76°C for 20 minutes, then add 1 part Hydrophobic agent stearic acid, stirred and reacted at 74-76°C for 20 minutes, dried in an oven at 128-132°C to obtain highly hydrophobic starch;
[0053] (2) High-speed stirring modification of nano calcium carbonate:
[0054] Add 1 part of modifier hyperbranched polyester and 12 parts of nano-calcium carbonate to 55 parts of modified solvent DMF, put them into a high-speed mixer, stir and react at a high speed in a constant temperature water bath at 73-77°C for 2 hours, then vacuum filter and dry , grinding, and passing through a 200-me...
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