Quantum dot-doped functional boron nitride polymeric heat conducting compound film and preparation method thereof
A thermally conductive composite, boron nitride technology, applied in chemical instruments and methods, heat exchange materials, etc., can solve the problems of limited production application, complex preparation process, insufficient mechanical properties, etc., to reduce agglomeration phenomenon, reasonable process, excellent The effect of mechanical properties
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Embodiment 1
[0026] The doped quantum dot functionalized boron nitride polymer heat-conducting composite film provided in this embodiment, the heat-conducting composite film includes the following components in weight percentage:
[0027] Boron nitride quantum dots 1~5wt%,
[0028] Functionalized boron nitride 5~50wt%,
[0029] Polymer matrix 50-95wt%;
[0030] The sum of the weight percentages of the above components is 100wt%
[0031] The doped quantum dot functionalized boron nitride polymer heat conduction composite film, the particle size of the functionalized boron nitride is 50-200nm, and the particle size of the boron nitride quantum dot is 2-50nm.
[0032] Doped with quantum dots functionalized boron nitride polymer heat conduction composite film, the polymer matrix is one or more of polyimide, polyvinyl alcohol, polypropylene, polyamide, polyethylene, polycarbonate mixed.
[0033] The preparation method of the doped quantum dot functionalized boron nitride polymer heat-condu...
Embodiment 2
[0042] The doped quantum dot functionalized boron nitride polymer heat-conducting composite film provided in this embodiment is basically the same as in Example 1, except that the mass fraction of boron nitride quantum dots in the composite film is 1%. The mass fraction of functionalized boron nitride nanosheets is 5%, and the mass fraction of polyimide is 94%.
[0043] The preparation method of the doped quantum dot functionalized boron nitride polymer heat-conducting composite film in this embodiment includes the following steps:
[0044] (1) Preparation of functionalized boron nitride: h-BN and urea are sand-milled according to a mass ratio of 1:20, and ground for 2 hours; after filtration, the resulting boron nitride powder is dispersed into 100ml of dimethylformamide ( DMF), ultrasonically dispersed for 10 hours to obtain a boron nitride nanosheet dispersion; finally, the boron nitride nanosheet dispersion was subjected to solvothermal reaction at 100°C for 24 hours, and ...
Embodiment 3
[0051] The doped quantum dot functionalized boron nitride polymer heat-conducting composite film provided in this embodiment is basically the same as that of Examples 1 and 2, except that the quality of the boron nitride quantum dots of the composite film in this embodiment The fraction is 3%, the mass fraction of functionalized boron nitride nanosheets is 5%, and the mass fraction of polyimide is 92%.
[0052] Its preparation method comprises the following steps:
[0053] (1) Preparation of functionalized boron nitride: h-BN and urea are sand-milled according to a mass ratio of 1:20, and ground for 10 h; after filtration, the boron nitride powder obtained is dispersed into 100 ml of dimethylformamide ( DMF), ultrasonically dispersed for 24 hours to obtain a boron nitride nanosheet dispersion; finally, the boron nitride nanosheet dispersion was subjected to solvothermal reaction at 200°C for 12 hours, and the lower layer dispersion was the functionalized boron nitride dispersi...
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