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Non-gumming wear-resistant sole and preparation method thereof

A shoe sole and degumming technology, which is applied in the field of shoe sole preparation, can solve problems such as pollution of the treatment agent and glue environment, poor compatibility of rubber materials, and poor high temperature stability, so as to improve construction performance and storage stability. Degumming performance, color stabilization effect

Pending Publication Date: 2019-02-22
浙江薪然鞋业集团有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

EVA is a copolymer made of ethylene-vinyl acetate, referred to as EVA. The EVA midsole refers to the shoe midsole that is molded after injecting EVA into the mold and then heated at a high temperature. However, the EVA sole has poor wear resistance and often needs to be combined with rubber. Bottom fit prepared into sole material
This method often needs to polish the rubber outsole first, then treat the rubber outsole and the EVA midsole with a treatment agent, and then use glue to bond the rubber outsole and the EVA midsole. Glue pollutes the environment, and the obtained soles are prone to degumming
[0003] Chinese patent (201310407289.4) provides an environmentally friendly material for shoe materials and its preparation method and application. The environmentally friendly material for shoe materials includes EVA, EVA compatibilizer, peroxide vulcanizing agent, antioxidant, but it uses DCP vulcanizing agent , harmful to the human body, and the material has poor adhesion, poor compatibility with rubber compounds, poor high temperature stability, and needs to be improved

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] Embodiment 1: a kind of non-degumming wear-resistant sole comprises following components according to parts by weight, EVA 30 parts, calcium stearate 10 parts, nanometer calcium carbonate 5 parts, zinc stearate 5 parts, styrene-butadiene rubber 20 parts, three parts 10 parts of ethylene propylene rubber, 5 parts of nano-titanium oxide, 1 part of vulcanizing agent, 2 parts of bridging agent, 5 parts of compatibilizer, 2 parts of anti-aging agent, 5 parts of epoxy resin, 5 parts of polyacrylate, polyethylene 20 parts of alcohol, 2 parts of blowing agent, 5 parts of carbon tetrachloride.

[0027] Carry out modification to polyvinyl alcohol, comprise the steps,

[0028] Step1: Weigh 20 parts of polyvinyl alcohol according to parts by weight, add water until the polyvinyl alcohol is completely dissolved, and stir at 85-95°C at a stirring rate of 300r / min;

[0029] Step2: Weigh 5 parts of carboxymethyl cellulose according to the parts by weight, add water until the carboxyme...

Embodiment 2

[0040] Embodiment 2: a kind of non-degumming wear-resisting sole, comprises following components according to parts by weight, EVA40 parts, calcium stearate 15 parts, nanometer calcium carbonate 8 parts, zinc stearate 8 parts, styrene-butadiene rubber 25 parts, three 12.5 parts of ethylene propylene rubber, 6.5 parts of nano-titanium oxide, 2 parts of vulcanizing agent, 3.5 parts of bridging agent, 7.5 parts of compatibilizer, 5 parts of anti-aging agent, 10 parts of epoxy resin, 10 parts of polyacrylate, polyethylene 25 parts of alcohol, 3.5 parts of blowing agent, 7.5 parts of carbon tetrachloride.

[0041] Carry out modification to polyvinyl alcohol, comprise the steps,

[0042] Step1: Weigh 25 parts of polyvinyl alcohol according to parts by weight, add water until the polyvinyl alcohol is completely dissolved, and stir at 85-95°C at a stirring rate of 300r / min;

[0043] Step2: Weigh 7.5 parts of carboxymethyl cellulose according to parts by weight, add water until the carb...

Embodiment 3

[0054] Embodiment 3: a kind of non-degumming wear-resisting sole comprises following components according to parts by weight, 50 parts of EVA, 20 parts of calcium stearate, 10 parts of nano calcium carbonate, 10 parts of zinc stearate, 30 parts of styrene-butadiene rubber, three parts 15 parts of ethylene propylene rubber, 8 parts of nano-titanium oxide, 3 parts of vulcanizing agent, 5 parts of bridging agent, 10 parts of compatibilizer, 8 parts of anti-aging agent, 15 parts of epoxy resin, 15 parts of polyacrylate, polyethylene 30 parts of alcohol, 5 parts of blowing agent, 10 parts of carbon tetrachloride.

[0055] Carry out modification to polyvinyl alcohol, comprise the steps,

[0056] Step1: Weigh 30 parts of polyvinyl alcohol according to parts by weight, add water until the polyvinyl alcohol is completely dissolved, and stir at 85-95°C at a stirring rate of 300r / min;

[0057] Step2: Weigh 10 parts of carboxymethyl cellulose according to the parts by weight, add water u...

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PUM

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Abstract

The invention relates to a non-gumming wear-resistant sole by regulating the formula and process of various components of the sole. The non-gumming wear-resistant sole contains the following components in parts by weight: 30-50 parts of EVA (Ethylene-Vinyl Acetate), 10-20 parts of calcium stearate, 5-10 parts of nano calcium carbonate, 5-10 parts of zinc stearate, 20-30 parts of butadiene styrenerubber, 10-15 parts of ethylene-propylene-diene monomer, 5-8 parts of nano-titanium oxide, 1-3 parts of a vulcanizing agent, 2-5 parts of a bridging agent, 5-10 parts of a compatilizer, 2-8 parts of an anti-aging agent, 5-15 parts of epoxy resins, 5-15 parts of polyacrylate, 20-30 parts of polyvinyl alcohol and 2-5 parts of a foaming agent. Therefore, the prepared sole is excellent in mechanical property and excellent in high temperature resistance. The polyvinyl alcohol can achieve an excellent bonding effect, has high heat resistance, and achieves an excellent bonding effect when matched with polyacrylate.

Description

technical field [0001] The invention relates to the technical field of shoe sole preparation, in particular to a non-degumming wear-resistant shoe sole and a preparation method thereof. Background technique [0002] Shoes are items that we often use in our daily life, and the sole is an essential part of making shoes. Among them, since EVA foam sports soles entered the Chinese market, due to their lightness, good elasticity, strong toughness, and comfortable feet The advantages have been praised and recognized by the majority of consumers. EVA is a copolymer made of ethylene-vinyl acetate, referred to as EVA. The EVA midsole refers to the shoe midsole that is molded after injecting EVA into the mold and then heated at a high temperature. However, the EVA sole has poor wear resistance and often needs to be combined with rubber. The bottom fit is prepared as a sole material. This method often needs to polish the rubber outsole first, then treat the rubber outsole and the EVA...

Claims

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Application Information

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IPC IPC(8): C08L23/08C08L9/06C08L23/16C08L63/00C08L33/08C08L29/04C08L1/28C08K13/02C08K5/098C08K3/26C08K3/22C08K3/38C08K5/3492C08J9/04A43B13/04
CPCA43B13/04C08J9/0023C08J9/0028C08J9/0066C08J9/0071C08J9/0095C08J9/04C08J2323/08C08J2463/00C08J2429/04C08J2433/08C08J2423/16C08J2409/06C08J2401/28
Inventor 王友义
Owner 浙江薪然鞋业集团有限公司
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