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PTFE (polytetrafluoroethylene) spiral-wound membrane and preparation method thereof

A technology of polytetrafluoroethylene and roll-type membrane, which is applied in the field of membrane distillation, can solve the problems of difficult balance between separation accuracy and processing efficiency, high difficulty in realization, high cost of use, etc., and achieves good selection efficiency and selection effect, easy to use and operate, The effect of long service

Inactive Publication Date: 2019-03-01
CHONGQING RUNZE PHARM CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the relationship between the structure and performance of PTFE membranes has not been thoroughly studied at present, such as the separation accuracy and processing efficiency are difficult to balance; it has a precise microstructure, is easy to be damaged, has a short service life, and high cost of use; Stable performance, difficult structure control and performance improvement, difficult processing, etc.; when PTFE materials are used in separation applications, how to synergistically match between microstructure and macroscopic morphology to obtain better performance, etc.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] A polytetrafluoroethylene roll-type membrane with a three-dimensional penetrating pore structure, with stem holes surrounding the stems, the pore diameter is 800±200nm, the stem diameter is 500±100nm, and the stem pore diameter is 175±25nm; the pores of the pores The porosity is 60±10%, the porosity of the stem hole is 55±10%; the total surface area of ​​the stem, stem area:stem hole area=1-15:1. The film thickness is 100-200µm. The diameter is 80-250mm.

[0028] Stem surface area image analysis: photographs of the material were taken with a scanning electron microscope (SEM photographs, magnified 10000-50000 times). Scan this photo with image processing equipment (the television image processor TVIP-4100II that Japan Avionics company produces, the television image processor that Latock system engineering company provides) stem and stem hole are separated to obtain stem and stem hole image, The image is processed by software to obtain the respective areas, and the rat...

Embodiment 2

[0038] A polytetrafluoroethylene roll-type membrane has a three-dimensional through-hole pore structure. There are stem holes on the stems surrounding the pores. The porosity is 55-70%, the porosity of the stem hole is 50-60%; the total surface area of ​​the stem, stem area:stem hole area=3-6:1. The film thickness is 100-200µm. The diameter is 80-250mm.

[0039] The hydrophobic angle of the obtained material is 155-175°. The obtained PTFE material is subjected to membrane distillation: it is used for the treatment of lemon juice, and has excellent properties and effects suitable for industrial production. Highly concentrated fruit juice can be obtained without damaging nutrients (such as vitamin C, total acid, TSS, etc.). Membrane distillation flux>20L / m 2 h, the rejection rate is stable above 99.5%, and the membrane distillation is carried out continuously for 3-5 months, the flux drops to 68-75% of the original flux, the color of the material after cleaning is pure white...

Embodiment 3

[0041] A polytetrafluoroethylene roll-type membrane with a three-dimensional through-hole pore structure. There are stem holes on the stems surrounding the pores. The pore diameter is 880nm, the stem diameter is 550nm, and the stem pore diameter is 160nm; the porosity of the pores is 58%. The porosity of the stem hole is 58%; the total surface area of ​​the stem, stem area:stem hole area=5:1. The film thickness is 150µm. The membrane diameter is 120mm.

[0042] The resulting material had a hydrophobic angle of 160°. The obtained PTFE material is subjected to membrane distillation: it is used for the treatment of lemon juice, and has excellent properties and effects suitable for industrial production. Highly concentrated fruit juice can be obtained without damaging nutrients (such as vitamin C, total acid, TSS, etc.). Membrane distillation flux>20L / m 2 h, the rejection rate is stable above 99.5%, and the membrane distillation is carried out continuously for 3-5 months, the fl...

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Abstract

The invention provides a PTFE (polytetrafluoroethylene) spiral-wound membrane. The PTFE spiral-wound membrane adopts a 3D communicated pore structure, stem holes are formed in stems surrounding pores,the diameter of pores is 800 plus / minus 200 nm, the diameter of stems is 500 plus / minus 100 nm, and the diameter of stem holes is 175 plus / minus 25 nm; the porosity of pores is 60% plus / minus 10% andthe porosity of stem holes is 55% plus / minus 10%; the ratio of the total surface area of stems to the total surface area of stem holes is (1-15):1. The PTFE spiral-wound membrane has long service life and excellent separation effects.

Description

technical field [0001] The invention relates to a polytetrafluoroethylene rolled membrane and a preparation method thereof, which are used for separation, and are especially suitable for membrane distillation. technical background [0002] Due to its wide temperature range, PTFE has excellent chemical stability, low friction and thermal insulation properties. The separation membrane prepared from PTFE not only has excellent chemical stability, thermal stability It also has excellent waterproof, windproof, moisture permeable, breathable and stable charge storage properties. It has shown excellent performance in the manufacture of protective clothing, bag filter, architectural lighting, etc. A large number of PTFE microporous membranes are used in the National Stadium "Bird's Nest" and the Millennium Dome in the United Kingdom. However, the current PTFE microporous membrane still has disadvantages such as low flux, low filtration precision, easy pollution of membrane pores, ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01D71/36B01D69/02B01D67/00B01D63/00B01D61/36
CPCB01D61/364B01D63/00B01D67/0002B01D69/02B01D71/36B01D2325/02B01D2325/38
Inventor 周涛孙琦叶雷
Owner CHONGQING RUNZE PHARM CO LTD