Hot melt butyl adhesive with high cohesion strength and preparation method of hot melt butyl adhesive

A hot-melt butyl adhesive, cohesive strength technology, applied in adhesives, polymer adhesive additives, non-polymer adhesive additives, etc., can solve the problem of low peel strength between the self-adhesive surface and the adhered surface, and limited Problems such as the popularization and use of base pressure-sensitive adhesives and high requirements for material technical indicators can achieve the effects of high cohesive strength, changing hot-melt fluidity, and good hot-melt fluidity

Pending Publication Date: 2019-03-01
KESHUN WATERPROOF TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the cohesive strength of butyl pressure-sensitive adhesive is low, which leads to the low peel strength between the self-adhesive surface and the adhered surface of the waterproof membranes currently on the market that use butyl pressure-sensitive adhesive as self-adhesive adhesive, which makes the overlapping parts exist. The risk of being destroyed; in addition, non-asphalt-based hot-melt pressure-sensitive adhesives account for the main market, which can be produced by melt tank-pressurized pump-die casting, with low production equipment costs and mature technology, but butyl Pressure-sensitive adhesives can only be produced by twin-screw feeding extrusion-booster pump-die extrusion. Not only the secondary investment cost of equipment is high, but also the requirements for material technical indicators are high. These factors greatly limit the production of butyl pressure. Promoting the use of sensitive glue

Method used

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  • Hot melt butyl adhesive with high cohesion strength and preparation method of hot melt butyl adhesive

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0037] This embodiment provides a high cohesive strength hot-melt butyl rubber, including the following raw material components in parts by weight: 20 parts of butyl rubber, 10 parts of hot-melt reinforcing agent, 1 part of flux, and 25 parts of tackifier , 10 parts of plasticizer, 10 parts of filler, 10 parts of reinforcing agent, 0.5 part of coupling agent, 0.1 part of crosslinking agent, 0.1 part of auxiliary crosslinking agent, 1 part of antioxidant and 1 part of light stabilizer.

[0038] Further, the hot-melt reinforcing agent is an amorphous α-olefin copolymer.

[0039] Further, the flux is maleic anhydride grafted polyamide.

[0040] Further, the grafting rate of the fluxing agent is 0.5%.

[0041] Further, the crosslinking agent is dicumyl peroxide.

[0042] Further, the auxiliary crosslinking agent is tripropenyl isocyanurate.

[0043] Further, the butyl rubber is common butyl rubber.

[0044] Further, the tackifier is petroleum resin.

[0045] Further, the plasti...

Embodiment 2

[0058] This embodiment provides a high cohesive strength hot-melt butyl rubber, including the following raw material components in parts by weight: 30 parts of butyl rubber, 15 parts of hot-melt reinforcing agent, 3 parts of flux, and 10 parts of tackifier , 30 parts of plasticizer, 30 parts of filler, 30 parts of reinforcing agent, 1 part of coupling agent, 1 part of crosslinking agent, 1 part of auxiliary crosslinking agent, 3 parts of antioxidant and 3 parts of light stabilizer.

[0059] Further, the hot-melt enhancer is α-methylstyrene.

[0060] Further, the flux is glycidyl methacrylate grafted polyamide.

[0061] Further, the grafting rate of the fluxing agent is 1%.

[0062] Further, the crosslinking agent is phenolic resin.

[0063] Further, the auxiliary crosslinking agent is tripropenyl isocyanurate.

[0064] Further, the butyl rubber is chlorinated butyl rubber.

[0065] Further, the tackifier is rosin resin.

[0066] Further, the plasticizer is 0# naphthenic o...

Embodiment 3

[0079] This embodiment provides a high cohesive strength hot-melt butyl rubber, including the following raw material components in parts by weight: 60 parts of butyl rubber, 30 parts of hot-melt reinforcing agent, 10 parts of flux, and 45 parts of tackifier , 60 parts of plasticizer, 60 parts of filler, 40 parts of reinforcing agent, 5 parts of coupling agent, 3 parts of crosslinking agent, 3 parts of co-crosslinking agent, 5 parts of antioxidant and 5 parts of light stabilizer.

[0080] Further, the hot-melt reinforcing agent is a combination of ethylene-vinyl acetate and vinyl acetate of polyethylene at a ratio of 1:1, wherein the vinyl acetate content of ethylene-vinyl acetate is 30%, and the molecular weight of polyethylene is 3000 .

[0081] Further, the fluxing agent is polyamide grafted with hydroxyethyl methacrylate.

[0082] Further, the grafting rate of the fluxing agent is 1.5%.

[0083] Further, the crosslinking agent is diisobutylbenzene peroxide.

[0084] Furt...

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Abstract

The invention discloses a hot melt butyl adhesive with high cohesion strength and a preparation method of the hot melt butyl adhesive. The hot melt butyl adhesive comprises raw materials in parts by weight as follows: 20-60 parts of butyl rubber, 10-30 parts of a hot melting enhancer, 1-10 parts of flux, 10-45 parts of a tackifier, 10-60 parts of a plasticizer, 10-60 parts of filler, 10-40 parts of a reinforcing agent, 0.5-5 parts of a coupling agent, 0.1-3 parts of a crosslinking agent, 0.1-3 parts of an assistant crosslinker, 1-5 parts of an antioxidant and 1-5 parts of a light stabilizer. The hot melt butyl adhesive has quite high cohesion strength and good hot melting processability, can be prepared in a manner of melting box-pressure pump-die head casting and has low material requirement, low equipment investment and high production efficiency, and stripping strength between a self-adhesion surface and an adhered surface is high.

Description

technical field [0001] The invention relates to the field of waterproof materials, in particular to a hot-melt butyl rubber with high cohesive strength and a preparation method thereof. Background technique [0002] Building waterproofing is a measure taken from building materials or structures to prevent rainwater from penetrating certain parts of a building. It is mostly used in roofs, underground buildings, underground parts of buildings, and inner rooms that need waterproofing and water storage. buildings etc. According to the measures and means adopted, it is divided into two categories: material waterproofing and structural waterproofing. Material waterproofing relies on building materials to block the passage of water to achieve waterproofing or increase the ability to resist leakage, such as coiled material waterproofing, coating film Waterproof, rigid waterproofing of concrete and cement mortar, etc.; structural waterproofing is to adopt a suitable structural form ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09J123/22C09J123/28C09J11/04C09J11/06C09J11/08C09J4/06
CPCC08L2205/035C09J4/06C09J11/04C09J11/06C09J11/08C09J123/22C09J123/283C08L23/02C08L51/08C08L57/02C08K13/02C08K3/346C08K5/14C08L45/00C08L23/0853C08K3/04
Inventor 胡全超龚兴宇曹昌义
Owner KESHUN WATERPROOF TECH CO LTD
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