A kind of water-based epoxy modified water-based polyurethane ink link material and preparation method thereof
A water-based polyurethane and water-based epoxy technology, used in inks, household appliances, applications, etc., can solve the problems of water resistance to be improved, slow drying speed, paper shrinkage, etc., and achieve low cost, fast drying speed and good adhesion. Effect
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Embodiment 1
[0043] The epoxy polyurethane linking material is prepared from the following raw material components and proportioning (by weight): 63 parts of water-based epoxy resin, 27 parts of polyurethane prepolymer, and 10 parts of end-capping agent; wherein the polyurethane prepolymer consists of Prepared from the following raw material components and proportions (by weight): 30 parts of toluene diisocyanate, 60 parts of pentaerythritol diacrylate, 5 parts of 1,4-butanediol, and 5 parts of dimethylol propionic acid .
[0044] Its preparation method is:
[0045] (1) Add pentaerythritol diacrylate 1000 into a four-necked flask with a condenser, heat it, and slowly add toluene diisocyanate dropwise after the raw materials are completely melted. After the dropwise addition, react at 90°C for 2 hours to obtain an intermediate product.
[0046] (2) Mix the intermediate product with dimethylolpropionic acid, dissolve it in acetone, react at 60°C for 2h, then add 1,4-butanediol for mixing, a...
Embodiment 2
[0052] The epoxy polyurethane linking material is prepared from the following raw material components and proportioning (by weight): 75 parts of water-based epoxy resin, 15 parts of polyurethane prepolymer, and 10 parts of end-capping agent; wherein the polyurethane prepolymer is made of Prepared from the following raw material components and proportions (by weight): 35 parts by weight of toluene diisocyanate, 55 parts by weight of polycaprolactone diol 2000, 8 parts by weight of 1,4-butanediol, dihydroxy 2 parts by weight of methylpropionic acid.
[0053] Its preparation method is:
[0054] (1) Add polycaprolactone diol 2000 into a four-necked flask with a condenser, heat it, and slowly add toluene diisocyanate dropwise after the raw materials are completely melted. After the dropwise addition, react at 90°C for 2 hours to obtain mid product.
[0055] (2) Mix the intermediate product with dimethylolpropionic acid, dissolve it in isopropanol, react at 80°C for 2h, then add 1...
Embodiment 3
[0061] The epoxy polyurethane linking material is prepared from the following raw material components and proportioning (by weight): 63 parts of water-based epoxy resin, 27 parts of polyurethane prepolymer, and 10 parts of end-capping agent; wherein the polyurethane prepolymer consists of Prepared from the following raw material components and proportions (by weight): 45 parts by weight of toluene diisocyanate, 40 parts by weight of polycarbonate diol, 13 parts by weight of 1,4-butanediol, dimethylol 2 parts by weight of propionic acid.
[0062] Its preparation method is:
[0063] (1) Add polycarbonate diol into a four-necked flask with a condenser, heat it, and slowly add toluene diisocyanate dropwise after the raw materials are completely melted, and react at 90°C for 2 hours to obtain an intermediate product.
[0064] (2) Mix the intermediate product with dimethylolpropionic acid, dissolve it in butanone, react at 80°C for 2h, then add 1,4-butanediol and mix, react at 80°C...
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