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High-efficiency utilization method of waste plastic particles

A technology for waste plastics and granules, which is used in the improvement of process efficiency, waste gas treatment, manufacturing converters, etc. It can solve the problem of high temperature spontaneous combustion, save energy, and improve the calorific value per unit.

Active Publication Date: 2019-04-16
WUHAN UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] However, the recycling of waste plastics requires that the composition of waste plastics is relatively single and pure, so that the quality and reuse value of recycled plastics can be fundamentally guaranteed; waste plastics recycling technology is an important aspect of resource utilization and harmless treatment of waste plastics. The means and methods have good social, environmental and economic benefits, but because the technology has high requirements on raw materials, it is often difficult to achieve large-scale production
[0007] In order to solve the problem that it is difficult to achieve large-scale production of waste plastics recycling, scientists have invented waste plastics thermal decomposition and oilization technology, which refers to the process of decomposing plastics to produce fuel oil and fuel gas by heating or adding a certain catalyst at the same time. Plastic resource utilization method; this method can deal with waste plastics that are not easy to recycle, but most of the processes are mainly used to deal with the same kind or a single type of waste plastics. For the treatment of mixed waste plastics, there are currently sorting, feeding and slag discharge, Heat transfer and coking, catalyst regeneration and other technical problems, but also problems such as collection difficulties and the need to provide external heat sources lead to high investment and operation costs
[0008] Aiming at the low recovery rate of converter gas, low CO content in recovered gas and CO 2 , O 2 Due to the problems of high content and difficulty in recycling waste plastics, this invention proposes a new method of adding waste plastic particles to converters or electric furnaces as raw materials to prepare high-quality gas, and applies waste plastic powder pyrolysis and gasification technology to metallurgical high-temperature waste gas utilization , make full use of waste plastics as a resource, and open up a new technical approach for the utilization of metallurgical high-temperature waste gas

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] This embodiment provides a method for efficient utilization of waste plastic granules. The converter used for smelting is a 120t converter, and the waste plastic granules used are ethylene phthalate waste plastic granules. The ethylene phthalate waste plastic granules are The particle size is 10mm.

[0026] During converter gas recovery in converter smelting, the ethylene phthalate waste plastic granules are added into the converter as raw materials, and the ratio of the ethylene phthalate waste plastic granules to steel scrap is 0.5 ton: 1 ton.

[0027] Carry out 10 tests according to the above method, and the average gas volume recovered is 135m 3 / ton of steel, the main component of recovered gas is CO 68-85% by volume, CO 2 4~10%, H 2 3~5%, O 2 0.1-0.5%, and the balance is organic matter such as methane.

[0028] A comparative test without adding waste plastic particles, the average gas volume of gas recovery is 110m 3 / ton of steel, the main component of ...

Embodiment 2

[0031] This embodiment provides a method for efficient utilization of waste plastic granules. Compared with Example 1, the difference is that the converter used for smelting is a 100t converter, and when the converter gas is recovered, waste plastic granules are added to the converter as raw materials. The ratio of the amount of waste plastic particles to steel scrap is 0.1 ton: 1 ton. .

[0032] According to the above method, 10 tests were carried out, and the average gas volume recovered was 118m 3 / ton of steel, the main component of recovered gas is CO 65-81% by volume, CO 2 6~12%,H 2 2 to 5%, O 2 0.3-0.5%, and the balance is organic matter such as methane.

[0033] A comparative test without adding waste plastic particles, the average gas volume of gas recovery is 100m 3 / ton of steel, the main component of recovered gas is CO 45-65% by volume, CO 2 10-20%, H 2 0.5~1%, O 2 0.4 to 1.0%, and the balance is nitrogen and the like.

[0034] Compared with the ori...

Embodiment 3

[0036] This embodiment provides a method for efficient utilization of waste plastic granules. Compared with Embodiment 1, the difference lies in that a 60t converter is used for smelting.

[0037] During converter gas recovery, waste plastic particles are added into the converter as raw materials, and the ratio of waste plastic particles to scrap steel is 1 ton: 1 ton.

[0038] According to the above method, 10 tests were carried out, and the average gas volume recovered was 113m 3 / ton of steel, the main component of recovered gas is CO 75-88% by volume, CO 2 5~10%,H 2 2 to 4%, O 2 0.2-0.5%, and the balance is organic matter such as methane.

[0039] A comparative test without adding waste plastic particles, the average gas volume of gas recovery is 98m 3 / ton of steel, the main component of recovered gas is CO 65-75% by volume, CO 2 12~17%,H 2 0.5~1%, O 2 0.8-1.0%, and the balance is nitrogen and the like.

[0040] Compared with the original technology, the r...

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Abstract

The invention discloses a high-efficiency utilization method of waste plastic particles. The high-efficiency utilization method of the waste plastic particles comprises the steps that when the waste plastic particles are smelted in a converter or an electric furnace, the waste plastic particles are added as raw materials to the converter or the electric furnace, and the use level ratio of the waste plastic particles to scrap steel is (0.1-1) ton / to 1 ton; and the pyrolysis of the waste plastic particles produces H2 gas, CO gas and carbon black, the pyrolitic carbon black can react with oxygenin smelting molten steel to form carbon monoxide and release heat energy, and meanwhile, the H2 gas and the CO gas can be used as energy resources for recovery and utilization, and environmental pollution is reduced. According to the high-efficiency utilization method of the waste plastic particles, the potential resources of plastic waste is fully used, the problems of huge waste of plastic resources and the harm to the environment are solved, meanwhile, the output and quality of recovered converter gas are obviously improved, the recovery amount of per ton steel gas is increased by 15-22%,the unit calorific value is increased by 15-25%, the energy is saved by 10-30%, and the market prospect is broad.

Description

technical field [0001] The invention relates to a method for utilizing waste plastics, in particular to a method for efficiently utilizing waste plastic particles. Background technique [0002] Converter steelmaking occupies a dominant position in my country's steelmaking process, and its by-product, converter gas, is an important secondary energy source for iron and steel enterprises, and its recovery accounts for 80%-90% of the total energy recovery in the entire steelmaking process; therefore, improving The quantity and quality of converter steelmaking gas recovery is conducive to increasing the efficiency of steelmaking and effectively reducing the greenhouse gas CO 2 emission, which is of great significance to the sustainable development of iron and steel enterprises. [0003] At present, my country's converter gas recovery is still at a relatively low level, and there are generally low gas recovery rates, low CO content in recovered gas and CO 2 , O 2 high content is...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C21C5/38C21C5/52
CPCC21C5/38C21C5/527C21C2005/5282C21C2100/02Y02P10/20
Inventor 周建安宋伟明张翔吴江江
Owner WUHAN UNIV OF SCI & TECH