Novel inorganic intumescent steel structure fireproof coating and preparation method thereof

A technology for fire-resistant coatings and steel structures, applied in the direction of fire-resistant coatings, alkali metal silicate coatings, coatings, etc., can solve the problems of reduced fire-proof performance, coating cracking, and poor expansion of coatings, and achieve excellent high-temperature foam insulation Effects of thermal fire resistance, same-life weather resistance and aging resistance, and excellent high-temperature expansion

Active Publication Date: 2019-04-19
SHIHEZI UNIVERSITY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, at present, ultra-thin steel structure fire retardant coatings are mostly organic models, which pollute the environment during production and construction, release a large amount of toxic smoke during flame retardancy, and endanger human health; in addition, there are high prices, weather resistance and aging resistance. Poor and other deficiencies, do not meet the future development trend of green environmental protection materials
[0005] In the Chinese patent CN 105885488A, a preparation method of a new type of inorganic ultra-thin expanded steel structure fireproof coating is disclosed. Liquid sodium silicate, expanded graphite, low melting point glass powder, magnesium hydroxide, latex powder and water are weighed according to the formula, and mixed After uniformity, add it to the mixer and stir to make the coating evenly dispersed, and put it in a tank for later use. In this patent, liquid sodium silicate is used alone as a binder. Experiments have proved that when liquid sodium silicate is used alone, the liquid silicic acid has a lower modulus. The curing time of sodium is too long, and the water resistance is too poor. With the increase of the modulus, the curing time of liquid sodium silicate becomes shorter, and the water resistance is enhanced, but the expansion is poor, and there are wrinkles after the coating is formed, and it burns. Over time, cracks are prone to occur, and the fire resistance performance cannot meet the requirements; in addition, the large amount of magnesium hydroxide used in this patent will cause cracks in the coating, and the coating has poor expansion, which reduces the fire protection performance

Method used

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  • Novel inorganic intumescent steel structure fireproof coating and preparation method thereof
  • Novel inorganic intumescent steel structure fireproof coating and preparation method thereof
  • Novel inorganic intumescent steel structure fireproof coating and preparation method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0046] Example 1: This example is the effect of using liquid sodium silicate alone on the film-forming and fire-proof performance of fireproof coatings, and the film-forming properties of liquid sodium silicate with a modulus of 1.5, 2.0, 2.5, 3.0, and 3.3 are studied , and the film-forming properties of the samples are shown in Table 1.

[0047] Table 1 The influence of liquid sodium silicate modulus on the film-forming properties of coatings

[0048]

[0049] It can be seen from Table 1 that when the low-modulus liquid sodium silicate is used as a film-forming agent, the curing time is longer, and when the modulus is 1.5, the curing time is greater than 96h, and the curing time decreases with the increase of the liquid sodium silicate modulus , when the modulus reaches above 3.0, the curing time is only 2 hours, but because the high modulus sample dries too fast, it will wrinkle, which is not conducive to film formation, and it is easy to crack during the burning process,...

Embodiment 2

[0054] Embodiment 2: This embodiment is the influence of using the modulus of solid sodium silicate alone on the film-forming property of the coating: in order to devote oneself to the coating of preparing a kind of pure solid phase, it is 1.0, 2.0, 2.5, 3.3 to the solid silicon of modulus The film-forming properties of sodium bicarbonate were studied, and its film-forming performance and sample appearance are shown in Table 2 and image 3 shown.

[0055] Table 2 The influence of solid sodium silicate modulus on the film-forming properties of coatings

[0056] modulus

[0057] From Table 2, image 3 It can be seen that image 3 Among them, a, b, c, and d correspond to the modulus 1.0, 2.0, 2.5, and 3.3 respectively. Except for the solid sodium silicate with a modulus of 1.0, when the solid sodium silicate with other moduli is used as a film-forming agent, severe cracking occurs. phenomenon, and the larger the modulus, the more obvious the cracking phenomenon of th...

Embodiment 3

[0058] Embodiment 3: This embodiment is the influence of the mixing ratio of solid-liquid sodium silicate on the film-forming performance and fire resistance of fireproof coatings. Sodium silicate is the most ideal inorganic film-forming agent, but it can be seen from Examples 1 and 2 that, Whether liquid sodium silicate or solid sodium silicate is used as a film-forming agent alone, there are some shortcomings. In order to make the film-forming property and fireproof performance of the coating the best, but also to reduce the water content as much as possible (due to the In the process of water, the volume shrinkage of the sample will cause cracking), so this embodiment analyzes according to the above-mentioned experimental results, selects the liquid sodium silicate with a modulus of 3.0 as the main, and a small amount of solid sodium silicate with a modulus of 1.0 as an auxiliary. Solid-liquid mixed sodium silicate is used as a film-forming agent for fire-resistant coatings ...

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Abstract

The invention discloses a novel inorganic intumescent steel structure fireproof coating and a preparation method thereof, and belongs to the field of fireproof coatings, and the novel inorganic intumescent steel structure fireproof coating is characterized in that the fireproof coating mainly comprises the following raw materials in parts by dry weight: 5 to 6 parts of solid sodium silicate, 25 to44 parts of liquid sodium silicate, 20-40 parts of aluminum hydroxide, 3-10 parts of low-melting-point glass powder, 5-20 parts of magnesium oxide, 0-10 parts of redispersible latex powder, 0.1-5 parts of a waterproof agent, 0.1-1 part of a defoaming agent and 0-20 parts of water. Compared with the prior art, the method has the advantages of high expansion layer strength, small smoke amount, good film forming and fireproof performance, low cost, simple preparation process, convenient operation and the like.

Description

technical field [0001] The invention relates to a fireproof coating, in particular to a novel inorganic expansion steel structure fireproof coating and a preparation method thereof, belonging to the field of fireproof coatings. Background technique [0002] Steel structures are widely used in the field of construction due to their high strength, good toughness, good earthquake resistance, and good extensibility. The steel structure is a good conductor of heat, and the relationship between its bearing capacity and temperature shows that the bearing capacity will decrease rapidly with the increase of temperature, resulting in poor fire resistance. Experiments have proved that when the temperature of the steel structure reaches about 550°C, the steel structure will lose most of its bearing capacity. When a fire breaks out, the temperature of the fire site can reach about 1000°C. At this temperature, the building collapses due to the loss of bearing capacity of the steel struct...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D1/04C09D5/18
CPCC09D1/04C09D5/185
Inventor 刘承友李洪玲但建明乔浩洪成林乔秀文齐誉
Owner SHIHEZI UNIVERSITY
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