Composite nano-filtration membrane and preparation method thereof

A composite nanofiltration membrane and composite support technology, applied in the field of composite nanofiltration membrane and its preparation, can solve the problems of high required cost, low salt rejection rate, complex preparation process and the like

Active Publication Date: 2019-04-23
OCHEMATE MATERIAL TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the above aromatic polyamide hollow fiber membranes do not mention the removal effect of salt solution, and the existing composite nanofiltration membranes still h

Method used

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  • Composite nano-filtration membrane and preparation method thereof
  • Composite nano-filtration membrane and preparation method thereof
  • Composite nano-filtration membrane and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0076] (1) Preparation of modified meta-aramid polymer

[0077] Under nitrogen protection, add 80.383mL of DMAc solvent, 0.077mol of m-phenylenediamine, 0.0616mol of APBIA and 0.0154mol of 4-fluoro-1,3-phenylenediamine into a 1L four-necked flask equipped with mechanical stirring and a thermometer. Stir under nitrogen protection until the solute is completely dissolved. Use a freezing bath to adjust the reaction temperature to -15°C, add 0.1155mol of isophthaloyl chloride under stirring, control the reaction temperature of the reaction system below 0°C, and continue to add 0.0262mol of isophthaloyl dimethanol after reacting until the viscosity of the system is stable Acyl chloride, after the reaction until the viscosity of the system is stable, add 0.0123mol of isophthaloyl chloride at the end, the solution starts to thicken, the temperature rises, adjust the stirring speed to control the reaction temperature below 60°C until the reaction is complete, after adding 0.154mol of ...

Embodiment 1

[0104] (1) Prepare an aqueous solution: mix piperazine monomer (PIP), 2,5-diaminotrifluorobenzene monomer, SDS and triethylamine into deionized water to prepare an aqueous solution. In this aqueous solution, the content of piperazine monomer is 0.5% (w / v), the content of 2,5-diaminotrifluorobenzene monomer is 0.025% (w / v), and the content of SDS is 0.06% (w / v). v), the content of triethylamine is 0.2% (w / v).

[0105] (2) Preparation of organic solution: adding trimesoyl chloride into n-hexane to prepare an organic solution. The content of trimesoyl chloride in the organic solution was 0.3% (w / v).

[0106] (3) Immerse the modified meta-aramid hollow fiber base membrane in the aqueous solution, take it out after 1 minute, and dry it for 15 minutes after taking it out.

[0107] (4) Immerse the dried basement film in step (3) into an organic solution for interfacial polymerization, take it out after 1 minute, and dry it for 5 minutes after taking it out.

[0108] (5) heat-treat...

Embodiment 2

[0110] Except that the content of piperazine monomer in the aqueous solution was changed to 1% (w / v), other experimental conditions were the same as in Example 1.

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Abstract

The invention discloses a composite nano-filtration membrane, wherein a modified meta-aramid hollow fiber membrane is used as a base membrane, and polyamine, a diaminobenzene fluoride and polyacyl chloride are subjected to an interface polymerization reaction on the base membrane to form an ultra-thin polyamide layer. The invention further provides a preparation method of the composite nano-filtration membrane. With the technical scheme of the present invention, the pure water flux of the prepared composite nano-filtration membrane is more than or equal to 50 L/(m<2>.h) at 0.5 MPa, the desalination rate of the prepared composite nano-filtration membrane to the 2 g/L divalent cation salt solution is more than or equal to 80%, the required cost is low, and the method is suitable for industrial production; and the preparation method has characteristics of simpleness, mild reaction condition, stable product performance and wide market application prospect.

Description

technical field [0001] The invention relates to the technical field of polymer nanofiltration membranes, in particular to a composite nanofiltration membrane and a preparation method thereof. Background technique [0002] Nanofiltration (NF) is a membrane separation technology between ultrafiltration (UF) and reverse osmosis (RO). Nanofiltration membrane preparation methods mainly include phase inversion method, dip coating method, surface graft polymerization method and interfacial polymerization method. Among them, the interfacial polymerization method is a preparation technology for preparing a nanofiltration functional separation layer on the ultrafiltration base membrane by interfacial polymerization. . Due to the simple operation and obvious advantages of this method, this preparation technology has been widely used in the preparation of commercial nanofiltration membranes. [0003] For example, Chinese patent CN105617875A discloses a high-throughput hollow fiber com...

Claims

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Application Information

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IPC IPC(8): B01D71/56B01D69/12B01D69/08B01D69/02B01D67/00
CPCB01D67/0011B01D67/0013B01D69/02B01D69/08B01D69/12B01D71/56
Inventor 方佩晖王冰菲曹俊
Owner OCHEMATE MATERIAL TECH CO LTD
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