Oil field scale inhibitor, and preparation method and use method thereof

A scale inhibitor, oilfield technology, applied in chemical instruments and methods, earthwork drilling, cleaning appliances, etc., can solve the problems of unstable properties of scale inhibitor, increase labor costs, damage to oil production equipment, etc., and prolong the pump inspection period. , Extend the validity period, and the effect of scale inhibition is remarkable.

Active Publication Date: 2019-05-03
YANGTZE UNIVERSITY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] However, the current scale inhibitors have problems of unstable properties and short action time. In actual use, scale inhibitors need to be injected into oil wells every day, which greatly increases labor costs.
Therefore, it is necessary to develop a scale inhibitor with stable properties and long acting time to solve the problem of damage to oil production equipment caused by wellbore scaling, so as to ensure the stable and normal production of oilfields

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0035] Embodiment 1 of the present invention provides a kind of oil field scale inhibitor, and it comprises the first scale inhibitor, the second scale inhibitor and the 3rd scale inhibitor, wherein:

[0036] The first scale inhibitor includes the following components by weight: 10 parts of sodium ethylenediamine tetramethylene phosphonate, 8 parts of amino trimethylene phosphonic acid, 5 parts of hydroxyethylidene diphosphonic acid, 2-phosphonobutane - 8 parts of 1,2,4-tricarboxylic acid and 100 parts of water; mix the above-mentioned components with water, stir and mix evenly to prepare the first scale inhibitor.

[0037] The second scale inhibitor includes the following components by weight: 15 parts of maleic anhydride, 10 parts of acrylic acid, 5 parts of hydroxypropyl acrylate, 1 part of ammonium persulfate, and water is added to 100 parts; Mix hydroxypropyl ester and water, then add ammonium persulfate to the mixture, and polymerize for 4 hours at a temperature of 80°C ...

Embodiment 2

[0040] Embodiment 2 of the present invention provides a kind of oil field scale inhibitor, and it comprises the first scale inhibitor, the second scale inhibitor and the 3rd scale inhibitor, wherein:

[0041] The first scale inhibitor includes the following components by weight: 8 parts of sodium ethylenediamine tetramethylene phosphonate, 6 parts of amino trimethylene phosphonic acid, 3 parts of hydroxyethylidene diphosphonic acid, 2-phosphonobutane - 8 parts of 1,2,4-tricarboxylic acid and 100 parts of water; mix the above-mentioned components with water, stir and mix evenly to prepare the first scale inhibitor.

[0042] The second scale inhibitor includes the following components by weight: 20 parts of maleic anhydride, 10 parts of acrylic acid, 8 parts of hydroxypropyl acrylate, 1 part of ammonium persulfate, and water is added to 100 parts; Mix hydroxypropyl ester and water, then add ammonium persulfate to the mixture, and polymerize for 4 hours at a temperature of 80°C t...

Embodiment 3

[0045] Embodiment 3 of the present invention provides a kind of oil field scale inhibitor, and it comprises the first scale inhibitor, the second scale inhibitor and the 3rd scale inhibitor, wherein:

[0046] The first scale inhibitor includes the following components by weight: 9 parts of sodium ethylenediamine tetramethylene phosphonate, 5 parts of amino trimethylene phosphonic acid, 3 parts of hydroxyethylidene diphosphonic acid, 2-phosphonobutane - 5 parts of 1,2,4-tricarboxylic acid and 100 parts of water; mix the above-mentioned components with water, stir and mix evenly to prepare the first scale inhibitor.

[0047] The second scale inhibitor includes the following components by weight: 18 parts of maleic anhydride, 7 parts of acrylic acid, 5 parts of hydroxypropyl acrylate, 0.5 parts of ammonium persulfate, and water is added to 100 parts; maleic anhydride, acrylic acid, acrylic acid Mix hydroxypropyl ester and water, then add ammonium persulfate to the mixture, and po...

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Abstract

The invention discloses an oil field scale inhibitor including a first scale inhibitor, a second scale inhibitor and a third scale inhibitor, wherein the first scale inhibitor includes: 8-10 parts ofsodium ethylenediamine tetramethylene phosphonate, 5-8 parts of aminotrimethylenephosphonic acid, 3-5 parts of hydroxyethylidene diphosphonic acid, and 5-8 parts of 2-phosphonobutane-1,2,4-tricarboxylic acid; the second scale inhibitor includes: 15-20 parts of maleic anhydride, 5-10 parts of acrylic acid, 5-8 parts of hydroxypropyl acrylate, and 0.5-1 part of ammonium persulfate; the third scale inhibitor includes: 10-12 parts of polyepoxysuccinic acid, 8-10 parts of polyaspartic acid, 5-8 parts of modified imidazolines, 0.5-1 part of modified quaternary ammonium salts, and 0.05-0.1 parts of sodium polyacrylate. The oil field scale inhibitor has stable properties; when being injected into an oil well, the scale inhibitor is slowly released, thus effectively relieving scaling on the wall cylinder and prolonging pump inspection period. The invention also provides a preparation method and a use method of the oil field scale inhibitor.

Description

technical field [0001] The invention relates to the technical field of oil recovery and development in oilfields, in particular to an oilfield scale inhibitor, a preparation method and a use method thereof. Background technique [0002] In the process of oilfield development, produced water and injected water contain Ca in varying degrees. 2+ , Mg 2+ , Ba2+, Sr2+, CO32-, SO42- and other scaling ions, with the change of external environment (temperature, pressure, etc.), lead to formation, wellbore and surface pipeline scaling. Commonly seen in oil fields are CaCO3 scale, CaSO4 scale, SrSO4 scale, BaSO4 scale, etc. Corrosion products, such as FeCO3, FeS, Fe(OH)2, Fe2O3, which have high solubility and high content, are easy to precipitate under certain conditions. Substances such as sodium chloride are included. Scaling mostly occurs within 400m above the oil well pump, and the parts prone to scaling are mainly concentrated on the inner wall of the tubing, the outer wall of...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K8/52E21B37/06
Inventor 杨欢黄茗帅群石秀慧尹先清苏高申于小荣米远祝顾晓敏
Owner YANGTZE UNIVERSITY
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