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A kind of intercalation material for enhancing the interlayer performance of continuous fiber resin-based composite board and its preparation method

A technology of intercalation materials and composite materials, applied in fiber processing, fiber types, textiles and papermaking, etc., can solve the problems of adverse effects on strength and modulus, limiting toughening effects, etc., and achieves easy structure control and great operability , The effect of simple preparation process

Active Publication Date: 2021-06-22
GUILIN UNIV OF ELECTRONIC TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Li Yuting et al. (Li Yuting, Ma Chuanguo, Oqiju, et al. Interlaminar properties of rod-shaped nano-iron oxide reinforced carbon fiber / epoxy resin composites[J]. Journal of Guilin University of Electronic Science and Technology, 2017,37(6): 508- 512.) Divide the needle-like nanoparticles in the epoxy resin. When the addition of nanoparticles is 1%, the type I interlayer toughness of the composite material is increased by 99%. However, when the nanoparticles continue to increase, the Agglomeration phenomenon, which limits the toughening effect
Ni Nannan et al. proposed (Ni Nannan, Wen Yuefang, He Delong, et al. Research on structural damping performance of carbon fiber / epoxy resin composites loaded with nylon non-woven fabric loaded with PVDF[J]. Acta Polymerica Sinica, 2015, (9): 1060 -1069.) The nylon non-woven fabric loaded with quantitative polyvinylidene fluoride (PVDF) is used as the intercalation material, so that the G of the composite material IC It reached 1700.0 J / m2, which is 4.6 times higher than that of the unused intercalation material, but at this time the strength and modulus of the composite material were adversely affected by the introduction of flexible PVDF components

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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  • A kind of intercalation material for enhancing the interlayer performance of continuous fiber resin-based composite board and its preparation method
  • A kind of intercalation material for enhancing the interlayer performance of continuous fiber resin-based composite board and its preparation method
  • A kind of intercalation material for enhancing the interlayer performance of continuous fiber resin-based composite board and its preparation method

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Effect test

Embodiment 1

[0033] A method for preparing an intercalation material for enhancing the interlayer performance of a continuous fiber resin-based composite board, comprising the steps of:

[0034] (1) Alcohol was selected as solvent, needle-shaped magnetic FeOOH nanoparticles were used as dispersed particles, KH-550 was used as coupling agent, polyvinylpyrrolidone was used as dispersant, needle-shaped magnetic FeOOH nanoparticles, KH-550, polyvinylpyrrolidone Dissolved in alcohol to form a mixed solution; the mass fractions of needle-shaped magnetic FeOOH nanoparticles, KH-550, and polyvinylpyrrolidone in alcohol were: 20%, 5%, and 10%; the morphology of needle-shaped magnetic FeOOH nanoparticles Figure such as figure 1 As shown, the hysteresis loop diagram of the acicular magnetic FeOOH nanoparticles is shown in figure 2As shown, it can be seen from the figure that the coercive force of the nanoparticles is almost zero, and there is superparamagnetism, which provides a guarantee for the s...

Embodiment 2

[0039] A method for preparing an intercalation material for enhancing the interlayer performance of a continuous fiber resin-based composite board, comprising the steps of:

[0040] (1) Using acetone as solvent, needle-like magnetic Fe 2 o 3 Nanoparticles As dispersed nanoparticles, KH-560 was used as a coupling agent, polyvinylpyrrolidone was used as a dispersant, and acicular magnetic Fe 2 o 3 Nanoparticles, KH-560, polyvinylpyrrolidone dissolved in acetone to form a mixed solution; needle-like magnetic Fe 2 o 3 The mass fractions of nanoparticles, KH-560, and polyvinylpyrrolidone in acetone are: 1%, 1%, and 0.5% respectively;

[0041] (2) Use non-woven fabric made of polyurethane, place it in a magnetic field with a magnetic induction intensity of 1T, and fix it;

[0042] (3) Spray the mixed solution obtained in step (1) evenly on the surface of the non-woven fabric described in step (2), place it in a magnetic field for 1 hour, and orient;

[0043] (4) Place the orie...

Embodiment 3

[0045] A method for preparing an intercalation material for enhancing the interlayer performance of a continuous fiber resin-based composite board, comprising the steps of:

[0046] (1) Choose water as solvent, needle-like magnetic Fe 3 o 4 Nanoparticles are dispersed nanoparticles, KH-570 is used as coupling agent, water-soluble acrylic polymer dispersant is used as dispersant, and acicular magnetic Fe 3 o 4 Nanoparticles, KH-570, polyvinylpyrrolidone dissolved in water to form a mixed solution; needle-like magnetic Fe 3 o 4 The mass fractions of nanoparticles, KH-570, and water-soluble acrylic polymer dispersant in water are: 5%, 5%, and 5%, respectively.

[0047] (2) Use non-woven fabric made of polyurethane, and arrange a magnetic field with a magnetic induction intensity of 0.5T;

[0048] (3) Immerse the polyurethane non-woven fabric in the mixed solution of step (1), and fix it in the magnetic field of step (2) for 2 hours, such as Figure 6 The device shown dip-co...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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Abstract

The invention discloses an intercalation material for enhancing the interlayer performance of a continuous fiber resin-based composite board and a preparation method thereof. The intercalation material mainly utilizes the synergistic effect of polymer fiber non-woven fabrics and acicular iron oxide particles, which can effectively improve the interlayer toughness of continuous fiber resin-based composite sheets, and orient the acicular iron oxide particles with the aid of a magnetic field. arrangement to obtain a more efficient toughening effect. The specific method is: first, disperse and dissolve different raw materials such as magnetic acicular iron oxide particles, auxiliary dispersing agent, coupling agent, etc. in a suitable solvent according to a certain proportion, and then spray or dip them on the polymer fibers of a specific material. On the non-woven fabric, the magnetic needle-shaped nano-iron oxide particles are then aligned along the direction perpendicular to the surface of the polymer fiber non-woven fabric under the assistance of a magnetic field, and the final product is obtained after drying. The preparation method of the intercalation material has the characteristics of simple process, low cost, safety and environmental protection, and high production efficiency.

Description

technical field [0001] The invention relates to the processing technology and application field of composite materials, in particular to an intercalation material for enhancing the interlayer performance of continuous fiber resin-based composite boards and a preparation method thereof. Background technique [0002] Resin-based carbon fiber laminated composite panels with carbon fiber as reinforcement, with the advantages of high modulus and high strength, are more and more widely used in various pillar industries such as aerospace, aviation, high-speed rail, automobiles, and packaging. The production process of this material is simple, and the shape of the product has high plasticity, which greatly solves the shortcomings of ceramics, glass and other non-metallic materials such as ceramics, glass and other non-metallic materials with poor impact performance and heavy quality. Initiate and propagate at the interface, that is, type I interlaminar fracture. Such cracks will gr...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): D06M11/49D06M13/513D06M15/356D06M15/263C08L63/00C08L75/04C08L79/08C08K7/06C08K7/14D06M101/20D06M101/38D06M101/30
Inventor 马传国陈官王静黄军钧戴培邦张坚
Owner GUILIN UNIV OF ELECTRONIC TECH
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