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Rainproof and fireproof ceramifiable polyolefin material and preparation method thereof

A technology of porcelainized polyolefin and polyolefin, which is applied in the field of rainproof and fireproof porcelainized polyolefin materials and its preparation, can solve the problem of not being able to further meet the needs of fireproof cables, affecting the reliability of fireproof cables, and the strength of ceramic bodies is not high enough, etc. problems, to achieve the effect of improving rain-proof performance, realizing mass production, and improving surface hydrophobicity

Inactive Publication Date: 2019-05-17
CHANGSHU ZHONGLIAN PHOTOELECTRICITY NEW STUFF +2
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

For example: Chinese invention patent CN 105367965 introduces a halogen-free flame-retardant ceramic polyolefin cable compound, which mainly solves the problem that ceramic polyolefin needs to be extruded by special extrusion equipment, and the process is relatively complicated; the invention patent CN106009140 is mainly Solve the problem that the strength of the ceramic body after ceramic polyolefin is not high enough to further meet the rapidly growing requirements of refractory cables; the invention patent CN 107488294 is mainly made by adding porous / layered aluminosilicates synthesized by natural or natural clay and combined Cooperate with surface activation treatment agent to further reduce the material cost and lower the porcelain forming temperature of ceramicized polyolefin
However, an important disadvantage of porcelainable polyolefin materials compared with porcelainable silicone rubber materials is the water absorption problem of the ceramic body after being porcelained. The resulting rain may cause the ceramic body to lose its insulation due to water absorption, thereby affecting the reliability of the fire-resistant cable
But so far, there are no related patents or reports

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0029] The present invention provides a rain-proof and fire-proof porcelain polyolefin material, which is prepared from the following raw material components (by mass fraction):

[0030] polyolefin

EVA

50 copies

Silicone rubber compound

Methyl vinyl silicone rubber

50 copies

High temperature resistant packing

Kaolin:Mica=1:3

80 copies

Halogen-free flame retardant

Magnesium hydroxide: calcium carbonate = 2:1

10 copies

Porcelain Sintering Auxiliary

ZB:APP:AF=1:1:1

20 copies

Platinum complexes or platinum compounds

Platinum content of 10000ppm isopropanol solution of chloroplatinic acid

1 copy

Compatibilizer

EVA-g-A151

5 copies

crosslinking agent

DCP: double two five = 1:1

1 copy

[0031] The preparation method of the above-mentioned rainproof and fireproof porcelain polyolefin material comprises the following steps:

[0032] (1) Polyolefin masterbatch mix...

Embodiment 2

[0039] A rain-proof and fire-proof porcelain polyolefin material, which is prepared from the following raw material components (by mass fraction):

[0040] polyolefin

LLDPE

80 copies

Silicone rubber compound

Methyl vinyl silicone rubber

20 copies

High temperature resistant packing

Kaolin:Montmorillonite=1:1

120 copies

Halogen-free flame retardant

Aluminum hydroxide: magnesium hydroxide = 2:1

20 copies

Porcelain Sintering Auxiliary

ZB:APP:AF=4:3:2

40 copies

Platinum complexes or platinum compounds

Methyl vinyl coordination platinum catalyst

0.01 part

Compatibilizer

EMA

1 copy

crosslinking agent

DCP: double two five = 1:1.5

0.5 parts

[0041] The preparation method of the above-mentioned rainproof and fireproof porcelain polyolefin material comprises the following steps:

[0042] (1) Polyolefin masterbatch mixing: set the internal mixer to 100°C, add poly...

Embodiment 3

[0049] A rain-proof and fire-proof porcelain polyolefin material, which is prepared from the following raw material components (by mass fraction):

[0050] polyolefin

EPDM

100 copies

Silicone rubber compound

Methylphenyl vinyl silicone rubber

40 copies

High temperature resistant packing

Mica:Montmorillonite=1:1

100 copies

Halogen-free flame retardant

Aluminum hydroxide: cerium oxide = 2:1

30 copies

Porcelain Sintering Auxiliary

ZB:APP:AF=4:3:1

30 copies

Platinum complexes or platinum compounds

Methyl vinyl coordination platinum catalyst

0.05 parts

Compatibilizer

EMA

1 copy

crosslinking agent

DCP: double two five = 1:1.5

0.5 parts

[0051] The preparation method of the above-mentioned rainproof and fireproof porcelain polyolefin material comprises the following steps:

[0052] (1) Polyolefin masterbatch mixing: set the internal mixer to 100°C, add polyol...

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PUM

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Abstract

The invention discloses a rainproof ceramifiable polyolefin material. The rainproof ceramifiable polyolefin material is prepared from 50-80 parts of polyolefin, 20-50 parts of rubber mixings of silicone rubber, 80-120 parts of high-temperature-resistant packings, 10-30 parts of a halogen-free flame retardant, 20-40 parts of a ceramic formation sintering aid, 0.01-1 part of a platinum complex or aplatinum compound (in terms of platinum), 1-5 parts of a compatilizer and 0.5-1 part of a cross-linking agent. The invention further discloses a preparation method of the material. The preparation method comprises following steps: polyolefin and silica gel are blended, and the various packings are mixed, aged and vulcanized. The rainproof ceramifiable polyolefin material has excellent mechanical strength and fireproof performance, the surface of formed ceramic is hydrophobic, water can be effectively prevented from permeating into the ceramic, reduction of insulating property due to water absorption after firing ceramic formation of the material can be prevented effectively, the cost of the material is lower than that of ceramifiable silicone rubber, the fireproof performance of the material is higher than that of a common ceramifiable polyolefin material, and the rainproof ceramifiable polyolefin material has great significance when applied to the field of fireproof cables.

Description

technical field [0001] The invention relates to a rain-proof and fire-proof porcelain-able polyolefin material and a preparation method thereof, belonging to the field of fire-resistant cables. Background technique [0002] Fire-resistant power and signal cables are critical to the rescue of people and property in the event of a fire. At present, most of the refractory cables at home and abroad are magnesium oxide mineral cables and mica wrapped cables. Magnesium oxide mineral cables are very expensive, and the length of a single cable is limited, making it difficult to promote the use of civil buildings. Mica-wrapped cables require multiple layers of winding during the production process. After fire, the mica tape becomes brittle and easy to fall off, which also results in poor fire resistance, making it difficult to ensure safe and smooth communication and power in case of fire. [0003] Porcelainable polyolefin material is a new type of fireproof material, which can be ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/08C08L83/07C08L23/16C08L51/06C08K13/02C08K3/34C08K3/22C08K3/26C08K3/38C08K3/32B29B7/00B29C35/02
Inventor 王金合苏桂明管文武张尔梅朱俊席凯彬唐科达
Owner CHANGSHU ZHONGLIAN PHOTOELECTRICITY NEW STUFF
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