A manufacturing method for a 
copper-based super-hydrophobic 
surface structure mainly includes that step 1, a 
metal copper base is pre-processed; step 2, a layer of 
photoresist is coated on the surface of the processed 
copper base in a rotation mode, and the 
photoresist layer attached to the surface of the copper base forms a well-aligned porous array template through photoetching 
processing; step 3, the copper base with the well-aligned porous array template obtained in the step 2 is used as an 
anode and soaked in a CuSO4 solution to form a 
primary battery to conduct a reaction for 4-8 min; step 4, the copper base of the 
primary battery obtained in the step 3 after reaction is finished is soaked into an AgNO3 solution to conduct in-situ reduction for 30-70s; step 5, the copper base subjected to the reaction in the step 4 is subjected to 
silanization processing, and the copper-based super-hydrophobic 
surface structure is manufactured. By means of the method, two simple 
redox processes are utilized to obtain a layer of micro-nano dual-
scale structure similar to the 
lotus leaf surface on the surface of 
copper metal, 
hydrophobe is achieved, the performance of the manufactured super-hydrophobic surface is stable, a 
contact angle between the super-hydrophobic surface and a water solution with a pH value 
ranging from 1 to 14 can be larger than 155 degrees, and the minimum 
rolling angle can be smaller than 1.5 degrees.