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Non-ferrous smelting sewage treatment neutralization slag concrete brick and preparation method thereof

A technology for sewage treatment and concrete bricks, which is applied in the field of non-ferrous smelting sewage treatment and slag concrete bricks and their preparation, can solve the problems of unrecognized market, threats to land and water bodies, and high disposal costs, and saves investment costs and operation. Cost, reduce secondary pollution, low production cost effect

Pending Publication Date: 2019-07-05
CHANGSHA HAIHONG BUILDING MATERIALS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

With the development of the hydrometallurgy process, the discharge of neutralized slag is increasing year by year, and it is mainly stockpiled or landfilled. In the process of stockpiling or landfilling, it not only has the disadvantages of occupying too much land and high costs, There is also an environmental risk of neutralization slag accumulation. First, the "running, leaking, dripping, and leakage" during the transportation process will have a negative impact on the environment along the way; water body poses a potential threat
At present, in China, the neutralization slag is generally processed by washing→dryinggrindingcalcination, which consumes a lot of energy and is likely to cause secondary pollution. The products produced have narrow adaptability, poor water resistance, low strength, and no economic value. , cannot be recognized by the market
Therefore, a concrete brick based on conventional industrial solid waste such as neutralization slag in the treatment of non-ferrous smelting sewage is developed to solve many problems such as environmental pollution, waste of land resources, and high disposal costs caused by neutralization slag in the treatment of non-ferrous smelting sewage. Making it resourceful and harmless has become an urgent problem to be solved

Method used

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  • Non-ferrous smelting sewage treatment neutralization slag concrete brick and preparation method thereof
  • Non-ferrous smelting sewage treatment neutralization slag concrete brick and preparation method thereof
  • Non-ferrous smelting sewage treatment neutralization slag concrete brick and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0033] A neutralized slag concrete brick for non-ferrous smelting sewage treatment, comprising raw materials of the following weights: neutralized slag 900kg, cement 120kg, slag 180kg, slag 1320kg, fly ash 450kg, and admixture 30kg. Wherein, the non-ferrous smelting sewage treatment neutralization slag concrete brick is pressed by a semi-dry method; the neutralization slag is the non-ferrous smelting sewage treatment neutralization slag, specifically the viscous sludge produced in the non-ferrous smelting wastewater treatment process , That is, in the non-ferrous smelting wastewater treatment process, the iron salt-lime / calcium carbide mud method is used as the wastewater treatment agent. After pressure filtration, it becomes a viscous sludge with a water content of 30% and a red-yellow or white appearance. The ingredients are calcium sulfate and calcium sulfite, and also contain traces of heavy metal elements such as lead, zinc, copper, chromium, cadmium, arsenic, mercury, etc....

Embodiment 2

[0049] A neutralized slag concrete brick for non-ferrous smelting sewage treatment, comprising raw materials of the following weights: neutralized slag 1350kg, cement 200kg, slag 190kg, slag 1200kg, and admixture 60kg. Wherein, the non-ferrous smelting sewage treatment neutralization slag concrete brick is pressed by a semi-dry method; the neutralization slag is the non-ferrous smelting sewage treatment neutralization slag, specifically the viscous sludge produced in the non-ferrous smelting wastewater treatment process , That is, in the non-ferrous smelting wastewater treatment process, the iron salt-lime / calcium carbide mud method is used as the wastewater treatment agent. After pressure filtration, it becomes a viscous sludge with a water content of 30% and a red-yellow or white appearance. The ingredients are calcium sulfate and calcium sulfite, and also contain traces of heavy metal elements such as lead, zinc, copper, chromium, cadmium, arsenic, mercury, etc., open-air sto...

Embodiment 3

[0065] A neutralized slag concrete brick for non-ferrous smelting sewage treatment, comprising raw materials of the following weights: 1100 kg of neutralized slag, 240 kg of cement, 300 kg of slag, 1050 kg of slag, 270 kg of fly ash, and 40 kg of additives. Wherein, the non-ferrous smelting sewage treatment neutralization slag concrete brick is pressed by a semi-dry method; the neutralization slag is the non-ferrous smelting sewage treatment neutralization slag, specifically the viscous sludge produced in the non-ferrous smelting wastewater treatment process , That is, in the non-ferrous smelting wastewater treatment process, the iron salt-lime / calcium carbide mud method is used as the wastewater treatment agent. After pressure filtration, it becomes a viscous sludge with a water content of 30% and a red-yellow or white appearance. The ingredients are calcium sulfate and calcium sulfite, and also contain traces of heavy metal elements such as lead, zinc, copper, chromium, cadmiu...

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Abstract

The invention discloses a non-ferrous smelting sewage treatment neutralization slag concrete brick and a preparation method thereof. The concrete brick comprises the following raw materials in percentage by mass: 25 to 35% of neutralization slag, 3 to 6% of cement, 8 to 12% of mineral slag, 35 to 45% of furnace slag, 0 to 15% of fly ash, and 1 to 2% of admixture. The invention also discloses a preparation method of the non-ferrous smelting sewage treatment neutralization slag concrete brick. The prepared neutralization slag concrete brick has excellent performance, the leaching toxicity meetsthe environmental protection requirement, and many problems such as environmental pollution, waste of land resources and high disposal cost caused by the non-ferrous smelting sewage treatment neutralization slag are solved, and the non-ferrous smelting sewage treatment neutralization slag is used as a resource and is harmless, and other raw materials are conventional industrial solid waste which are cheap and easy to obtain, therefore, waste is used to treat waste, the cost of non-ferrous smelting wastewater treatment neutralization slag is greatly reduced, and a broad market prospect is provided.

Description

Technical field [0001] The invention relates to the technical field of new environmental protection building materials, in particular to a neutralized slag concrete brick for non-ferrous smelting sewage treatment and a preparation method thereof. Background technique [0002] my country is a major producer of non-ferrous metals. According to statistics, the amount of non-ferrous smelting waste in my country has reached 7438×10 4 t, covering an area of ​​865×10 4 m 2 , And the annual emissions are about 920×10 4 The speed of t increases year by year. The treatment of nonferrous smelting slag in my country is mainly open-air storage. The comprehensive utilization rate is low, with an average utilization rate of about 45%. The increase in stockpiles increases environmental sanitation pollution and safety risks. Lead and zinc contained in smelting slag , Copper, chromium, cadmium, arsenic, mercury and other heavy metal elements that flow into nearby rivers with water or infiltrate int...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B28/04
CPCC04B28/04C04B2111/00017C04B2201/50C04B18/0472C04B18/141C04B18/10C04B18/08C04B22/16C04B24/123C04B24/008C04B24/06C04B24/121C04B22/147C04B24/18C04B2103/12C04B2103/601
Inventor 黄绍龙肖文彬熊铁军熊铁强黄宇
Owner CHANGSHA HAIHONG BUILDING MATERIALS
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