High-wear-resistance super-amphiphobic nanometer coating layer, and preparation method thereof

A nano-coating, super-amphiphobic technology, used in coatings, polyurea/polyurethane coatings, devices for coating liquids on surfaces, etc., can solve problems such as limited improvement, weak bonding, and poor coating adhesion. , to achieve the effect of low requirements on substrate material and shape, avoiding incomplete processing and wide application range

Inactive Publication Date: 2019-08-09
SOUTHEAST UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the superhydrophobic surface micro-nanostructure is easily damaged by abrasion, which affects the superhydrophobicity, thus limiting the application of superhydrophobic surfaces.
Especially for coatings prepared by inorganic nanoparticle superhydrophobic coatings, the inorganic nanoparticles are bonded by molecular bonds, and the binding force is weak; and the inorganic nanoparticles are simply physically adsorbed on the surface of the substrate, and the coating adhesion is poor, resulting in the coating Micro and nanostructures are more susceptible to damage
According to research in recent years, the use of resin as the bottom layer to bond superhydrophobic nanoparticles can improve the wear resistance of superhydrophobic coatings, but the degree of improvement is limited.

Method used

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  • High-wear-resistance super-amphiphobic nanometer coating layer, and preparation method thereof
  • High-wear-resistance super-amphiphobic nanometer coating layer, and preparation method thereof
  • High-wear-resistance super-amphiphobic nanometer coating layer, and preparation method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0034] A kind of preparation method of high wear-resisting super amphiphobic nano-coating, resin is fluorocarbon resin and polyurethane resin in the present embodiment, and mass ratio is 1:1, and curing agent is hexamethylene diisocyanate isocyanate, volatilizes The neutral organic solution is butyl acetate, and the liquid pore-forming agent is Freon, and the method comprises the following steps:

[0035] (1) Add 6 parts by mass of resin and 4 parts by mass of curing agent to 13 parts by mass of volatile organic solution, and mechanically stir for 10 minutes to obtain a clear mixed solution;

[0036] (2) Add 12 parts by mass of a liquid pore-forming agent to the clarified mixed solution after the treatment in step (1), and mechanically stir for 10 minutes to obtain a uniformly dispersed adhesive resin coating;

[0037] (3) Disperse 8 parts by mass of nano-silica sol, 6 parts by mass of ammonia water, 12 parts by mass of deionized water, 0.5 parts by mass of tetraethyl orthosil...

Embodiment 2

[0041] A kind of preparation method of high wear-resisting super amphiphobic nano-coating, in the present embodiment, resin is fluorocarbon resin and acrylic resin, and mass ratio is 1:1, and curing agent is pherone dimonocyanate, volatile organic The solution is butyl acetate, and the powdery pore-forming agent is azodicarbonamide, and the method comprises the following steps:

[0042] (1) Add 3 parts by mass of resin and 2 parts by mass of curing agent to 25 parts by mass of volatile organic solution, and stir mechanically for 5 minutes to obtain a clear mixed solution;

[0043] (2) Add 1 part by mass of powdery pore-forming agent to the clarified mixed solution after the treatment in step (1), and mechanically stir for 5 minutes to obtain a uniformly dispersed adhesive resin coating;

[0044] (3) Disperse 1 mass part of nano-silica sol, 2 mass parts of ammonia water, 6 mass parts of deionized water, 0.1 mass part of tetraethyl orthosilicate, and 0.1 mass part of hydrophobic...

Embodiment 3

[0048] A kind of preparation method of high wear-resisting super amphiphobic nano-coating, in the present embodiment resin is fluorocarbon resin, polyurethane resin and acrylic resin, and mass ratio is 1:1:1, and curing agent is benzoyl peroxide, volatilizes The neutral organic solution is butyl acetate, and the liquid pore-forming agent is Freon, and the method comprises the following steps:

[0049] (1) Add 12 parts by mass of resin and 8 parts by mass of curing agent to 10 parts by mass of volatile organic solution, and mechanically stir for 10 minutes to obtain a clear mixed solution;

[0050] (2) Add 15 parts by mass of a liquid pore-forming agent to the clarified mixed solution after the treatment in step (1), and mechanically stir for 10 minutes to obtain a uniformly dispersed adhesive resin coating;

[0051] (3) Disperse 15 parts by mass of nano-silica sol, 10 parts by mass of ammonia water, 16 parts by mass of deionized water, 1 part by mass of tetraethyl orthosilicat...

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Abstract

The invention discloses a high-wear-resistance super-amphiphobic nanometer coating layer, and a preparation method thereof, and belongs to the technical field of ultra infiltration functional coatinglayer material preparation. The preparation method comprises following steps: first, a resin is dissolved in a volatile organic solution, a pore forming agent is added into the volatile organic solution, continuous mechanical stirring is carried out for uniform dispersion of the pore forming agent, then the surface of a substrate is coated with an obtained mixture, then is coated with a super-amphiphobic nanometer coating material, and is introduced into a baking oven for curing of the pore forming agent so as to obtain the high-wear-resistance super-amphiphobic nanometer coating layer. The preparation method can be used on substrates such as wood, cement, and glass, the wear resistance of the high-wear-resistance super-amphiphobic nanometer coating layer is improved obviously, a problem in the prior art that hydrophobic surface is easily destroyed is solved, and under severe environment, coating layer stain resistance, self cleaning performance, fogging resistance, ice resistance, corrosion resistance, and mildew resistance are maintained. The preparation technology and equipment are simple; operation is convenient; cost is low; and the preparation method is suitable for large scale preparation and industrialized production.

Description

technical field [0001] The invention belongs to the technical field of preparation of super-wetting functional coating materials, and in particular relates to a high wear-resistant super-amphiphobic nano-coating and a preparation method thereof. Background technique [0002] Super-amphiphobic surface refers to the solid surface on which water droplets or oil droplets can roll off under the action of micro-dynamic forces under the combined action of surface micro-nano structures and low surface energy substances. It has three defenses (waterproof, oilproof, dustproof), anti Excellent comprehensive properties such as dew, drag reduction, corrosion resistance, etc., can be widely used in industrial fields such as three-proof fabrics, anti-dew and anti-frost for air conditioners, anti-bacterial and anti-mildew for building materials, oil-water separation, anti-bioadhesion interfaces and water collection systems . [0003] At present, the technology of obtaining superhydrophob...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D127/12C09D133/04C09D175/04C09D1/00C09D7/63B05D3/02B05D5/08B05D7/24
CPCB05D3/0254B05D5/08B05D7/24C08L2205/03C09D1/00C09D7/63C09D127/12C09D133/04C09D175/04C08L75/04C08K5/02C08L33/04C08K5/23C08L27/12
Inventor 张友法顾万诚程真余新泉
Owner SOUTHEAST UNIV
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