A preparation process for improving the cycle performance and conductivity of high-nickel cathode materials
A positive electrode material and preparation technology, applied in the field of lithium ion battery positive electrode materials, can solve the problems of cycle performance degradation, lithium-nickel mixed discharge, poor conductivity, etc.
- Summary
- Abstract
- Description
- Claims
- Application Information
AI Technical Summary
Problems solved by technology
Method used
Image
Examples
Embodiment 1
[0033] A preparation process for improving the cycle performance and conductivity of high-nickel cathode materials,
[0034] Based on the high-temperature sintering furnace 5, a porcelain boat 1 is provided inside the high-temperature sintering furnace 5, and a corundum tube 7 is provided on the outer cover of the porcelain boat 1, and an ozone channel with a valve and an oxygen gas channel are provided in parallel at the air inlet of the corundum tube 7. channel, the ozone channel is also provided with an ozone generator 2, and the gas outlet of the corundum tube 7 is provided with an exhaust absorption device 6,
[0035] Described preparation process comprises the steps:
[0036] S1, the high-nickel cathode material precursor Ni 0.8 co 0.1 mn 0.1 (OH) 2 and lithium salt LiOH·H 2 O is mixed evenly according to the molar ratio of 1:1.05 according to the molar ratio, and the evenly mixed mixture is placed in the porcelain boat 1, then the porcelain boat 1 is put into the h...
Embodiment 2~5
[0046] On the basis of Example 1, in Examples 2 to 5, the number of times that the ozone gas is introduced is changed to 1 time, 2 times, 4 times, and 5 times respectively, without changing the time of each time the ozone gas is introduced, that is, a total of ozone gas is introduced. Gas 20min, 40min, 80min, 100min. The cycle performance of the button battery assembled with the high-nickel cathode material obtained under different conditions is shown in Table 1 below (the charge and discharge current density is 100mA / g), and the influence of the time of ozone introduction on the battery cycle performance is discussed.
[0047] Table 1: The influence of the time of passing ozone on the cycle performance of the battery
[0048]
[0049] It can be seen from Examples 2-5 that sintering with ozone for a period of time can improve the cycle performance of the material, and the optimum time for sintering is about 80 minutes.
Embodiment 6~9
[0051] On the basis of Example 1, only the carbon dioxide plasma treatment time was changed, and the carbon dioxide plasma treatment time in Examples 6-9 were 10 min, 20 min, 30 min, and 50 min, respectively. The cycle performance of button batteries assembled with high-nickel cathode materials obtained under different conditions is shown in Table 2 (charge and discharge current density is 100mA / g), and the influence of carbon dioxide plasma treatment time on battery cycle stability was discussed.
[0052] Table 2: Effect of carbon dioxide plasma treatment time on battery cycle stability
[0053]
[0054] It can be seen from Examples 6-9 that the carbon dioxide plasma treatment can improve the initial discharge capacity and cycle performance, but if the treatment time is too long, the material will be damaged and the cycle stability and capacity will decrease.
PUM
Property | Measurement | Unit |
---|---|---|
thickness | aaaaa | aaaaa |
Abstract
Description
Claims
Application Information
- R&D Engineer
- R&D Manager
- IP Professional
- Industry Leading Data Capabilities
- Powerful AI technology
- Patent DNA Extraction
Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic, Popular Technical Reports.
© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap|About US| Contact US: help@patsnap.com