Vanadium containing material ball making method
A material and material crushing technology, which is applied in the pelletizing field of vanadium-containing materials, can solve the problems of poor pelletizing stability, poor thermal stability of pellets, high moisture content of wet pellets, etc., and achieve the effect of solving poor stability and good economic benefits
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Embodiment 1
[0035] The bonding solution was prepared according to the mass ratio of sodium hydroxide, humic acid and water being 0.1:1.0:8.0, and the temperature was raised to 85° C., then stirred and reacted for 6 hours to obtain the bonding solution. Take 100kg of the mixed material with a mass ratio of sodium to vanadium of 1.4, mix the bonding solution and the mixed material according to the moisture content of the wet bulb at 7-8%, and control the roller pressure of the briquetting machine to 0.8-1.0MPa to briquette the ball. The particle size of the wet pellets is 5-8mm; the wet bulb drying temperature system is: drying at 150°C for 30 minutes; drying at 250°C for 20 minutes; oxidation reaction at 300°C for 20 minutes.
[0036] It has been determined that the strength of a single wet pellet ranges from 10.5 to 14.7N, with an average value of 13N per pellet. During the low-temperature dehydration-high-temperature oxidation curing process, there is no abnormal phenomenon of pellet crac...
Embodiment 2
[0038] The bonding solution was prepared according to the mass ratio of sodium hydroxide, humic acid and water being 0.1:1.0:9.0, and the temperature was raised to 85° C., then stirred and reacted for 7 hours to obtain the bonding solution. Take 100kg of the mixture with a mass ratio of sodium to vanadium of 1.6, mix the bonding solution and the mixture evenly according to the moisture content of the wet bulb at 7-8%, and control the roller pressure of the briquetting machine to 0.9-1.0MPa to briquette the ball. The particle size of wet pellets is 10-15mm. The wet bulb drying temperature system is: drying at 150°C for 40 minutes; drying at 250°C for 40 minutes; oxidation reaction at 300°C for 30 minutes.
[0039] It has been measured that the strength of a single wet pellet ranges from 11.0 to 15.1N, with an average value of 14.4N. During the low-temperature dehydration-high-temperature oxidation curing process, there is no abnormal phenomenon of pellet cracking or bursting, a...
Embodiment 3
[0041] Prepare the bonding solution according to the mass ratio of sodium hydroxide, (humic acid + starch) and water is 0.1:1.0:10.0, the mass ratio of humic acid and starch is 50:1, heat up to 95°C and then stir for reaction 8h, a binding solution was obtained. Take 100kg of the mixture with a mass ratio of sodium to vanadium of 1.8, mix the bonding solution and the mixture according to the moisture content of the wet bulb at 7-8%, and control the pressure of the ball pressing machine to 1.0-1.2MPa to press the ball. The particle size of wet pellets is 15-20mm. The wet bulb drying temperature system is: drying at 200°C for 30 minutes; drying at 300°C for 20 minutes; oxidation reaction at 370°C for 30 minutes.
[0042] It has been determined that the strength of a single wet pellet ranges from 10.0 to 15.4N, with an average value of 14.1N. During the low-temperature dehydration-high-temperature oxidation curing process, there is no abnormal phenomenon of pellet cracking or bu...
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