High-emissivity infrared energy-saving material and preparation method thereof

A high-emissivity, energy-saving material technology, applied in the field of infrared energy-saving, can solve the problems of affecting stability, losing the properties of nano-materials, crystal growth, etc., and achieving the effect of high structural stability

Active Publication Date: 2019-11-22
SINOSTEEL LUOYANG INST OF REFRACTORIES RES
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  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0002] In recent years, the rapid growth of energy consumption in my country has made the situation of energy conservation very severe. The industrial energy consumption for high-temperature processes represented by thermal furnaces accounts for about 25% to 40% of the national energy consumption. At the same time, the analysis of statistical data shows that At present, the average thermal efficiency of thermal furnace equipment in my country is less than 40%, which is 10% to 20% lower than that of industrially developed countries.
[0003] So far, in the research and development and application of infrared radiation energy-saving ceramic coatings, the American Wessex company is internationally recognized as the best performing company, but because its products are based on SiB 6 Main phase, resulting in long-term high prices
In addition, the British Encoat company's coating products have achieved an energy-saving efficiency of 5% in the trials of natural gas furnaces and oil furnaces, but due to the use of SiC powder as the radiation base material, they are not suitable for thermal furnaces wi

Method used

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  • High-emissivity infrared energy-saving material and preparation method thereof
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Experimental program
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Effect test

Embodiment 1

[0022] Embodiment 1: lanthanum oxide, calcium oxide, aluminum oxide, chromium oxide and zirconium oxide are carried out batching and ball milling according to the molar ratio La:Ca:Al:Cr:Zr=0.84:0.2:0.8:0.2:0.04, after drying at 1200 ℃ in an air atmosphere for 120 min, and then the pre-fired powder was ground and pressed and calcined in an air atmosphere at 1600 ℃ for 120 min, and finally a high-emissivity infrared energy-saving material was prepared. The emissivity of the high-emissivity infrared energy-saving material is 0.95.

[0023] From figure 1 It can be seen that in this implementation case, the main crystal phase of the high-emissivity infrared energy-saving material is lanthanum aluminate, the secondary crystal phase is calcium zirconate, and no other impurity phases are found, indicating that most of the calcium and chromium ions have been solid-dissolved into the lanthanum aluminate The crystal lattice forms a lanthanum aluminate-based ceramic material co-doped wi...

Embodiment 2

[0025] Embodiment 2: lanthanum oxide, calcium oxide, aluminum oxide, chromium oxide and zirconium oxide are carried out batching and ball milling according to the molar ratio La:Ca:Al:Cr:Zr=0.82:0.2:0.8:0.2:0.02, after drying at 1200 ℃ in the air atmosphere for 120 min, and then the pre-fired powder was ground and pressed and calcined in the air atmosphere at 1600 ℃ for 120 min, and finally a high-emissivity infrared energy-saving material was prepared. The emissivity of the high-emissivity infrared energy-saving material is 0.93.

Embodiment 3

[0026] Embodiment 3: lanthanum oxide, calcium oxide, aluminum oxide, chromium oxide and zirconium oxide are carried out batching and ball milling according to the molar ratio La:Ca:Al:Cr:Zr=0.83:0.2:0.8:0.1:0.03, after drying at 1300 ℃ in an air atmosphere for 60 minutes, and then the pre-fired powder was ground and pressed and calcined in an air atmosphere at 1500 ℃ for 360 minutes, and finally a high-emissivity infrared energy-saving material was prepared. The emissivity of the high-emissivity infrared energy-saving material is 0.91.

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Abstract

The invention belongs to the technical field of infrared energy conservation, and relates to a high-emissivity infrared energy-saving material and a preparation method thereof. The high-emissivity infrared energy-saving material takes lanthanum aluminate with a perovskite structure as a main phase, and raw materials of the high-emissivity infrared energy-saving material comprise lanthanum oxide, aluminum oxide, a doping agent I and a doping agent II, which are used for preparing the lanthanum aluminate main phase; wherein the doping agent I is calcium oxide, and the doping agent II is chromiumoxide; 0.1-0.2 mol of calcium ions are doped at the lanthanum site per unit mol, and 0.1-0.2 mol of chromium ions are doped at the aluminum site per unit mol; the raw materials of the high-emissivityinfrared energy-saving material also comprise zirconium oxide; wherein the zirconium oxide and calcium oxide are subjected to a solid-phase reaction to generate second main-phase calcium zirconate, generation of a low-melting-phase (CaLa) Al3O7 is inhibited or reduced through the solid-phase reaction, and zirconium ions subjected to the solid-phase reaction with calcium ions in calcium oxide areprovided by zirconium oxide. The material has the characteristics of high emissivity, high temperature resistance, high stability and high compatibility.

Description

technical field [0001] The invention belongs to the technical field of infrared energy saving, and more specifically relates to a high emissivity material and a preparation method thereof. Background technique [0002] In recent years, the rapid growth of energy consumption in my country has made the situation of energy conservation very severe. The industrial energy consumption for high-temperature processes represented by thermal furnaces accounts for about 25% to 40% of the national energy consumption. At the same time, the analysis of statistical data shows that At present, the average thermal efficiency of my country's thermal furnace equipment is less than 40%, which is 10% to 20% lower than that of industrially developed countries. Therefore, timely layout and research and development of energy-saving technologies for thermal equipment are extremely necessary and significant. In my country, aluminum-silicon refractories (Al 2 o 3 / SiO 2 , such as: alumina fiber bri...

Claims

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Application Information

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IPC IPC(8): C04B35/50C04B35/44
CPCC04B35/44C04B35/50C04B2235/3208C04B2235/3217C04B2235/3227C04B2235/3241C04B2235/3244
Inventor 王曲王刚张琪韩建燊张伟
Owner SINOSTEEL LUOYANG INST OF REFRACTORIES RES
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