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Negative ion polyurethane resin surface layer slurry for leather

A technology of polyurethane resin and surface layer slurry is applied in the field of automotive interior materials, which can solve the problems of material performance decline, ultrafine powder performance deterioration, and the inability of a single particle to exist stably, and achieves the effect of solving compatibility problems.

Inactive Publication Date: 2019-11-22
CHINA FIRST AUTOMOBILE
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, there are problems in this process at present: the surface energy of tourmaline powder is large, and the surface activity of ultrafine negative ion powder particles is very high. Individual particles cannot exist stably, and tend to agglomerate through mutual attraction, thereby reducing their surface energy to form stable state
Moreover, after agglomeration, it will lead to the deterioration of the performance of the ultrafine powder, which is not conducive to the performance of the negative ion powder, and is more prone to product quality problems.
In the application, the surface properties of tourmaline powder and high molecular polymer are quite different, which makes it more difficult for it to be uniformly dispersed and stable in non-polar polymers. If it is directly filled in organic matter, it will easily lead to some performance degradation of the material, thus Affect the overall comprehensive performance of composite materials

Method used

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  • Negative ion polyurethane resin surface layer slurry for leather
  • Negative ion polyurethane resin surface layer slurry for leather

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Embodiment 1

[0023] A kind of surface layer slurry of negative ion polyurethane resin for leather, is made up of following components by mass parts:

[0024] Waterborne polyurethane resin (Covestro: Bayhydrol A 2601): 100 parts

[0025] Water: 20-40 parts

[0026] Water-based ink (BASF: Joncryl 678): 10-30 parts

[0027] Negative ion additive: 3 to 5 parts.

[0028] Further, the negative ion additive is a tourmaline@13X molecular sieve with a core-shell structure, and the preparation method of the tourmaline@13X molecular sieve is as follows:

[0029] a, by mechanical shearing, the tourmaline is made into a powder A with a particle size of 6-20 microns;

[0030] b. Mix sodium metaaluminate, sodium hydroxide, sodium silicate, and water according to the following molar ratio, SiO 2 / Al 2 o 3 =3~5;Na 2 O / SiO 2 =1~1.5;H 2 O / Na 2 O=35~65; get Sol B after mixing evenly;

[0031] c. Add powder A to sol B, the mass ratio is A / B=3~5%, continue stirring evenly, and let stand at room tempe...

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Abstract

The invention discloses negative ion polyurethane resin surface layer slurry for leather, and belongs to the technical field of automobile interior materials. The surface layer slurry comprises, by mass, 100 parts of water-based polyurethane resin, 20-40 parts of water, 10-30 parts of water-based ink and 3-5 parts of a negative ion additive, wherein the negative ion additive is a tourmaline@13X molecular sieve of a core-shell structure; the negative ion additive is added into polyurethane surface coating slurry to prepare the surface layer slurry of the negative ion polyurethane resin. When the surface layer slurry serves as a surface material for automobile interior, negative ion release of the surface material can be realized, and the situation that the mechanical property of the material is reduced and accordingly the overall comprehensive performance of the composite material is influenced is avoided. The compatibility problem of tourmaline powder and a polyurethane system is solved, and the negative ion polyurethane resin surface layer slurry for the leather is prepared.

Description

technical field [0001] The invention belongs to the technical field of automotive interior materials, and in particular relates to a surface layer slurry of anion polyurethane resin for leather. Background technique [0002] Negative ion polyurethane skin materials for automotive interiors, such as microfiber and PU leather, generally add negative ion powder to polyurethane raw materials for processing, because negative ions can purify the air, eliminate peculiar smells and harmful gases in the air, relieve fatigue, and promote human health. Metabolism and other advantages, such as the development of synthetic leather that can release negative oxygen ions, are mainly used in small and confined spaces such as airplanes. Such negative ions are conducive to improving the environment in small spaces and improving the sensory experience of drivers and passengers. Therefore, the dispersion and dispersion stability of anion powder directly affect the final quality and various prope...

Claims

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Application Information

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IPC IPC(8): D06N3/00D06N3/14
CPCD06N3/0061D06N3/0063D06N3/14D06N2211/261D06N2211/28
Inventor 张明远孟玲玲丛穆任晓珊张斌滕腾王超陈书礼刘宏宇赵国华
Owner CHINA FIRST AUTOMOBILE
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