A method of hydrogen and oxygen plasma combined enhanced coal slime flotation

A technology of oxygen plasma and plasma, which is applied in the field of plasma enhanced flotation, can solve the problem of lack of surface hydrophobicity modification of coal slime, and achieve the effects of improving buoyancy, improving quality upgrading efficiency, and reducing chemical consumption

Active Publication Date: 2022-02-15
CHINA UNIV OF MINING & TECH
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AI Technical Summary

Problems solved by technology

Some scholars use dielectric barrier oxygen plasma to directly modify non-polar collectors to prepare heteropolar collectors for flotation of low-order coal slimes. However, this method is not suitable for non-polar collectors in the flotation environment (water environment). Polar collectors are modified, but the pure agents are modified, which is different from the actual flotation situation
[0003] In addition, the method of improving the surface hydrophobicity of coal slime by adsorption of chemicals only indirectly modifies the surface of coal slime, and the hydrophobicity of coal slime itself does not change. At present, there is a lack of methods to directly modify the surface hydrophobicity of coal slime.

Method used

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  • A method of hydrogen and oxygen plasma combined enhanced coal slime flotation
  • A method of hydrogen and oxygen plasma combined enhanced coal slime flotation
  • A method of hydrogen and oxygen plasma combined enhanced coal slime flotation

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Embodiment

[0026] Example: Shendong low-rank coal was used as the test coal sample, the moisture content was <10%, it was ground to -0.074mm, the floating ash content was 19.77%, and the impurity minerals were mainly quartz, kaolinite, etc.

[0027] First, the direct flotation test of test coal samples was carried out. The flotation conditions were: flotation concentration 80g / l, collector was diesel oil, dosage 7500g / t, flotation machine speed 1800rpm, gas filling volume 500ml / min, foaming The agent is 2-octanol, the dosage is 2500g / t, after one flotation, the foam and the tank bottom product are collected, the foam becomes clean coal, and the tank bottom product is tailing coal. The results are shown in Table 1.

[0028] Table 1 Low-rank coal direct flotation results

[0029]

[0030] Then use hydrogen plasma to modify the coal slime for 5 minutes, and mix it evenly with the aqueous collector solution activated by oxygen plasma for 5 minutes, add a foaming agent, inflate and scrape ...

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Abstract

The invention discloses a method of hydrogen and oxygen plasma combined enhanced coal slime flotation, which comprises the following steps: the dry coal slime is selectively treated with hydrogen plasma to improve the surface hydrophobicity of organic matter, and directly expand its floatability with inorganic minerals The conventional collectors are first fully dispersed by emulsification, and then activated by oxygen plasma in an aqueous solution environment, which improves the collection performance of the agent; the dry coal slime treated with hydrogen plasma and the dry coal sludge treated with oxygen plasma The chemical solution is mixed and slurried to make the chemical and the coal slime fully adsorbed; the above slurry is fed into the flotation device after being stirred with a foaming agent, and the air bubbles are introduced to enrich the combustibles in the foam, so that the inorganic minerals do not float up and the combustibles are realized. efficient recycling. By adopting the method of the invention, the dosage of coal slime flotation agent can be significantly reduced, the recovery rate of combustible body can be effectively improved, and the loss of clean coal can be significantly reduced.

Description

technical field [0001] The invention relates to the field of flotation, in particular to a method for combined hydrogen and oxygen plasma enhanced coal slime flotation, and is particularly suitable for the plasma enhanced flotation ash method of oxidized coal, low-rank coal and other difficult-to-float coals. Background technique [0002] Flotation is a mature and effective method for improving the quality of coal slime. The surface of coal slime is often modified by chemicals to improve the hydrophobicity of the slime surface, but the dispersion effect of non-polar chemicals such as diesel and kerosene in the water environment is not good. On this basis, some scholars emulsify non-polar chemicals , which improves its dispersion effect in aqueous solution, and the compound medicine is thus produced. Some collectors containing polar functional groups such as tetrahydrofuran, biodiesel, oxidized diesel, etc. can also collect organic matter more efficiently. Some scholars use...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B03D1/018B03D1/02
CPCB03D1/018B03D1/02B03D2203/08
Inventor 王大鹏胥萌李琛光李佳
Owner CHINA UNIV OF MINING & TECH
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