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Process for increasing nickel yield in ferronickel production

A yield and process technology, applied in the technical field of nickel yield, can solve the problems of rising stainless steel smelting costs, pushing up the production cost of electrolytic nickel, increasing mining difficulty, etc. The effect of unit cost reduction

Active Publication Date: 2019-12-03
江苏江南铁合金有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] With the rapid development of my country's stainless steel industry, the disadvantage of my country's lack of nickel resources is further exposed. my country's booming stainless steel industry must face these two problems: First, the current pricing power of the nickel market is not in my country, and the domestic spot nickel price basically follows the LME Nickel fluctuations; second, the gradual reduction of global nickel sulfide ore resources and the increase in mining difficulty will inevitably push up the production cost of electrolytic nickel, and the cost of stainless steel smelting will inevitably rise
If the production process is not further improved, the loss will be great

Method used

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  • Process for increasing nickel yield in ferronickel production

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] Put the waste nickel and steel scrap prepared in proportion into the alkaline crucible of the intermediate frequency induction furnace, and spread the bottom slag accounting for 2.1% of the furnace charge on the bottom of the crucible. The bottom slag is composed of: lime 72% and fluorite 28%; When the temperature is 1575°C, the charge forms a molten pool in the crucible, and the bottom slag is melted and covered on the alloy liquid; insert the muzzle of the oxygen blowing device 22cm below the liquid level of the alloy liquid, and the oxygen blowing device is under a pressure of 0.15Mpa Blow oxygen into the alloy liquid for 16 minutes for dephosphorization, analyze phosphorus and sulfur before the sampling furnace, and add composite flux after passing the test; the components of the composite flux are composed as follows by weight percentage: 38% coke powder, 25% quartz, 31% oxidized Calcium, 6% magnesium oxide, wherein the particle size of coke powder is 100-150 mesh, ...

Embodiment 2

[0030] Put the waste nickel and steel scrap prepared in proportion into the alkaline crucible of the intermediate frequency induction furnace, and spread the bottom slag accounting for 2.3% of the furnace charge on the bottom of the crucible. The bottom slag is composed of: 75% lime and 25% fluorite; When the temperature is 1595°C, the charge forms a molten pool in the crucible, and the bottom slag is melted and covered on the alloy liquid; insert the muzzle of the oxygen blowing device 30cm below the liquid level of the alloy liquid, and the oxygen blowing device is under a pressure of 0.2Mpa Blow oxygen into the alloy liquid for 20 minutes for dephosphorization, analyze phosphorus and sulfur before the sampling furnace, and add composite flux after passing the test; the components of the composite flux are composed as follows by weight percentage: 35% coke powder, 25% quartz, 35% oxidized Calcium, 5% magnesium oxide, wherein the particle size of coke powder is 100-150 mesh, the...

Embodiment 3

[0032] Put the waste nickel and steel scrap prepared in proportion into the alkaline crucible of the intermediate frequency induction furnace, and spread the bottom slag accounting for 2.5% of the furnace charge on the bottom of the crucible. The bottom slag is composed of: 70% lime and 30% fluorite; When the temperature is 1600°C, the charge forms a molten pool in the crucible, and the bottom slag is melted and covered on the alloy liquid; insert the muzzle of the oxygen blowing device 35cm below the liquid level of the alloy liquid, and the oxygen blowing device is under a pressure of 0.2Mpa Blow oxygen into the alloy liquid for 20 minutes for dephosphorization, analyze phosphorus and sulfur before the sampling furnace, and add composite flux after passing the test; the components of the composite flux are composed as follows by weight percentage: 35% coke powder, 20% quartz, 35% oxidized Calcium, 10% magnesium oxide, wherein the particle size of coke powder is 100-150 mesh, ...

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Abstract

The invention discloses a process for increasing the nickel yield in ferronickel production. The process comprises the following steps: preparing a furnace burden, adding bottom slag, charging and melting, blowing oxygen and dephosphorizing, adding a composite flux, discharging and casting to obtain ferronickel alloy. The added composite flux is prepared from the following components in percentageby weight: 30 to 40 percent of coke powder, 20 to 30 percent of quartz, 30 to 35 percent of calcium oxide and 5 to 10 percent of magnesium oxide; and after the composite flux is added, the furnace temperature needs to be increased to 1600-1680 DEG C for slag adjustment, and slag is taken out of the furnace after slag adjustment is completed. By adding the composite flux composed of the coke powder, the quartz, the calcium oxide and the magnesium oxide, the furnace temperature can be effectively increased, the slag viscosity can be reduced, nickel metal sedimentation can be promoted, the nickel content in ferronickel can be increased, and the adding amount of finished nickel metal can be reduced; the nickel recovery rate of the process can reach 98.5% or above, and the unit cost of ferronickel production is reduced by 20% or above.

Description

technical field [0001] The invention relates to the technical field of ferronickel production, in particular to a process for improving the nickel yield in ferronickel production. Background technique [0002] The main use of nickel is to manufacture stainless steel, high-nickel alloy steel and alloy structural steel, which are widely used in various military manufacturing industries such as aircraft, radar, missiles, tanks, ships, spacecraft, atomic reactors; in civilian industries, nickel is often Made of structural steel, acid-resistant steel, heat-resistant steel, etc., it is widely used in machinery manufacturing and petroleum industry; nickel and chromium, copper, aluminum, cobalt and other elements can form non-ferrous alloys. Nickel-based alloys and nickel-chromium-based alloys are high-temperature-resistant and oxidation-resistant materials, which are used to manufacture jet turbines, resistors, electric heating elements, high-temperature equipment structural parts,...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C21C5/54C21C7/064C21C7/00C22C35/00
CPCC21C5/54C21C7/0037C21C7/064C22C35/00
Inventor 梅泽锋宋雪建夏宏梁
Owner 江苏江南铁合金有限公司
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