Elastic pressure-sensitive adhesive layer, pressure-sensitive adhesive tape, and preparation method of pressure-sensitive adhesive tape
A pressure-sensitive adhesive layer, pressure-sensitive tape technology, applied in the direction of pressure-sensitive film/sheet, adhesive, film/sheet adhesive, etc., can solve foam deformation, increase quality cost, poor heat resistance, etc. problems, to achieve good cushioning, flexible applicability, simple and convenient production
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[0040] The preparation of the elastic pressure-sensitive adhesive layer of the present invention is formed by curing the emulsion glue, and airtight air bubbles are formed during the curing process, so that a plurality of airtight air bubbles are formed inside the elastic pressure-sensitive adhesive layer. For the curing temperature and time, as long as the glue is cured and the water-in-oil structure in the glue is broken, the outer coating layer of the water drop is broken, carbon dioxide is released through the reaction of water and isocyanate, and a polyurea structure is formed to wrap the carbon dioxide bubbles at the same time, forming an airtight seal. The structure is enough, and the curing temperature and time can be adjusted according to actual needs, as long as the aforementioned conditions are met. In the subsequent tape preparation process, the curing temperature and time will be further described in detail.
[0041] The preparation method of the elastic pressure-...
Embodiment 1
[0050] Proportion of water-in-oil emulsion: the following are composed of parts by mass, 2 parts of amphiphilic nonionic surfactant FSN100, 4 parts of deionized water, and 20 parts of ethyl acetate. Preparation process: Fully stir and disperse FSN100 and deionized water to form a uniform mixed solution. After standing for 1 hour, observe that there are no visible bubbles to the naked eye, and then form a water-in-oil emulsion with ethyl acetate through an emulsification pump, and adjust the parameters of the emulsification pump. The diameter of the emulsion particles is between 1-2 μm, and the emulsion is prepared and left to stand for use;
[0051] Emulsion glue ratio: the following are all composed of parts by mass, 10 parts of water-in-oil emulsion, 100 parts of heat-curable polyacrylate pressure-sensitive resin, 30 parts of rosin ester tackifying resin, 5 parts of epoxy curing agent, 30 parts Isocyanate, 220 parts of ethyl acetate, 30 parts of cyclohexanone, 70 parts of bl...
Embodiment 2
[0058] Proportion of water-in-oil emulsion: the following are composed of parts by mass, 1 part of amphiphilic nonionic surfactant FS10, 1 part of deionized water, and 20 parts of toluene. Preparation process: Fully stir and disperse FS10 and deionized water to form a uniform mixed solution. After standing for 1 hour, observe that there are no visible bubbles with the naked eye, and then form a water-in-oil emulsion with the solvent through the emulsification pump. Adjust the parameters of the emulsification pump to make the emulsion The diameter of the particles is between 1-2 μm, and the emulsion is prepared and left to stand for use;
[0059] Emulsion glue ratio: the following are all composed of parts by mass, 1 part of water-in-oil emulsion, 200 parts of heat-curable polyacrylate pressure-sensitive resin, 150 parts of rosin ester tackifying resin, 5 parts of epoxy curing agent, 10 parts Isocyanate, 220 parts of ethyl acetate, 30 parts of toluene, 0 parts of black color pa...
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