The invention discloses a cationic functional
fluorine-containing
polymer and a preparation method thereof. The functional
fluorine-containing
polymer is a cationic functional
fluorine-containing
polymer prepared by the steps of: taking a fluorine-containing
monomer, a graftable active
monomer and a hydrophilic
functional monomer as copolymerization monomers, firstly polymerizing, in a water phase dispersion
system, the copolymerization monomers into an active
precursor polymer of which the main chain contains an atom transfer free
radical polymerization active side group, then initiating a cationic
functional monomer by using the active side group on a
solid liquid interface to perform interface atom transfer free
radical polymerization, and performing
polymerization to form the cationic functional fluorine-containing polymer containing a cationic type
side chain. The cationic type
side chain contains
quaternary ammonium salt type and
quaternary phosphonium salt type groups, has a very strong charge positive electrical property, and enables the polymer to have very strong antibacterial performance, hydrophilic performance and anion exchange absorbing performance, and the polymer can be applied separately to preparation or together with other resin to blending preparation of a high-hydrophilicity antibacterial separation membrane product, a gel
electrolyte, an
adhesive, a battery diaphragm, an anion exchange adsorbing material and an
antibacterial coating, so that the application range of
vinyl chloride type polymers is greatly broadened; and in comparison with an existing material, the polymer is good in hydrophilicity, is antibacterial, and is good in application prospect.