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A polycrystalline cubic boron nitride composite sheet with a sandwich layer structure and its preparation method

A cubic boron nitride, polycrystalline cubic technology, applied in coating, metal processing equipment, metal material coating technology and other directions, can solve the problems of insufficient toughness, low service life and efficiency of composite sheets, and prone to cracking. Achieve the effect of reducing interfacial stress, minimizing stress concentration, and improving pressure distribution

Active Publication Date: 2021-09-03
ZHONGNAN DIAMOND CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The composite sheet has changed from the traditional upper and lower two-layer structure to a three-layer structure with a sandwich layer, which solves the problem that the traditional polycrystalline cubic boron nitride composite sheet has insufficient toughness and is prone to cracking during use; the ion implantation technology is used to make up for the ordinary cubic boron nitride composite sheet. There are structural defects and performance compatibility on the surface of boron nitride particles, which solves the problem of low service life and low efficiency of ordinary polycrystalline cubic boron nitride composite sheets

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0038] The preparation method of the polycrystalline cubic boron nitride composite sheet with a sandwich layer structure in this embodiment comprises the following steps:

[0039] 1) Substrate purification treatment: first immerse the cemented carbide substrate in an alkaline solution prepared by deionized water and sodium hydroxide at a mass ratio of 1:0.15 and boil for 1 min, then immerse the cemented carbide substrate in a mixture of 98% sulfuric acid and Deionized water was ultrasonically cleaned in a sulfuric acid solution prepared with a volume ratio of 1:4 for 1min, then placed in deionized water and absolute ethanol solution for ultrasonic cleaning for 5min and 8min, and the cemented carbide substrate was taken out and dried with nitrogen, and finally Then put it in a vacuum sintering furnace, the air pressure in the furnace is not more than 5×10 -4 Pa, under the condition of 600°C, fill the furnace with hydrogen with a pressure of 15Mbar to carry out vacuum treatment ...

Embodiment 2

[0049] The preparation method of the polycrystalline cubic boron nitride composite sheet with a sandwich layer structure in this embodiment comprises the following steps:

[0050] 1) Substrate purification treatment: first immerse the cemented carbide substrate in an alkaline solution prepared by deionized water and sodium hydroxide at a mass ratio of 1:0.25 and boil for 3 minutes, then immerse the cemented carbide substrate in a mixture of 98% sulfuric acid and Deionized water was ultrasonically cleaned in a sulfuric acid solution prepared with a volume ratio of 1:5 for 3 minutes, then placed in deionized water and absolute ethanol solution for ultrasonic cleaning for 10 minutes and 12 minutes, and the cemented carbide substrate was taken out and dried with nitrogen, and finally Then put it in a vacuum sintering furnace, the air pressure in the furnace is not more than 5×10 -4 Pa, under the condition of 700°C, fill the furnace with hydrogen gas with a pressure of 20Mbar to ca...

Embodiment 3

[0060] The preparation method of the polycrystalline cubic boron nitride composite sheet with a sandwich layer structure in this embodiment comprises the following steps:

[0061] 1) Substrate purification treatment: first immerse the cemented carbide substrate in an alkaline solution prepared by deionized water and sodium hydroxide at a mass ratio of 1:0.2 and boil for 2 minutes, then immerse the cemented carbide substrate in a mixture of 98% sulfuric acid and Deionized water was ultrasonically cleaned in a sulfuric acid solution prepared with a volume ratio of 1:4.5 for 2 minutes, then placed in deionized water and anhydrous ethanol solution for 7.5 minutes and 10 minutes, and then the cemented carbide substrate was taken out and dried with nitrogen. Finally, it is placed in a vacuum sintering furnace, and the air pressure in the furnace is not more than 5×10 -4 Pa, under the condition of 650°C, fill the furnace with hydrogen with a pressure of 17.5Mbar to carry out vacuum t...

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Abstract

The invention belongs to the technical field of composite tool materials, and in particular relates to a polycrystalline cubic boron nitride composite sheet with a sandwich layer structure and a preparation method thereof. The preparation method of the polycrystalline cubic boron nitride composite sheet with a sandwich layer structure includes the following steps: 1) depositing a transition layer, 2) ion implanting the surface of cubic boron nitride, 3) mixing, 4) assembling the composite, 5) Vacuum treatment of the complex, 6) High temperature and high pressure sintering. The present invention changes the upper and lower two-layer structure of the traditional composite sheet into a three-layer structure with a sandwich layer, which solves the problem that the traditional polycrystalline cubic boron nitride composite sheet has insufficient toughness and is prone to cracking during use; the ion implantation technology is used to make up for the common There are structural defects and performance compatibility on the surface of cubic boron nitride particles, which solves the problem of low service life and low efficiency of ordinary polycrystalline cubic boron nitride composite sheets.

Description

technical field [0001] The invention belongs to the technical field of composite tool materials, and in particular relates to a polycrystalline cubic boron nitride composite sheet with a sandwich layer structure and a preparation method thereof. Background technique [0002] Polycrystalline cubic boron nitride composite sheet is a superhard composite material sintered under high temperature and high pressure conditions with cubic boron nitride micropowder and cemented carbide substrate as the substrate. Because of its high hardness and It has the characteristics of good wear resistance, and at the same time has the characteristics of strong impact resistance and good weldability of cemented carbide, so it is widely used in the field of cutting difficult-to-machine materials such as cast iron, hardened steel, and heat-resistant steel. [0003] The traditional polycrystalline cubic boron nitride composite sheet is generally composed of a cemented carbide substrate and two laye...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C23C14/02C23C14/35C23C14/06C23C14/48B22F3/02B22F3/10B22F3/15C22C29/08B22F1/00C22C47/14C22C49/02C22C49/14B22F7/04
CPCC23C14/021C23C14/35C23C14/0641C23C14/0635C23C14/48B22F3/02B22F3/1007B22F3/15C22C29/08C22C29/067C23C14/0036C22C47/14C22C49/02C22C49/14B22F7/04B22F2003/153B22F1/105
Inventor 张涛卢灿华朱培王军颢王卫康
Owner ZHONGNAN DIAMOND CO LTD