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Polypyrrole lithium sulfur battery material

A polypyrrole lithium-sulfur battery technology, which is applied in the direction of lithium batteries, battery electrodes, non-aqueous electrolyte batteries, etc., can solve the problems of low utilization rate of active materials, low battery capacity retention rate, theoretical specific capacity limit, etc., and achieve improved conductivity Stability, improve cycle stability and capacity retention, inhibit the effect of dissolving in the electrolyte

Inactive Publication Date: 2020-02-11
安徽清泉新能源科技集团有限责任公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, lithium-ion batteries using lithium cobalt oxide, lithium manganese oxide, and lithium iron phosphate as positive electrode materials are limited by theoretical specific capacity, so it is unrealistic to further increase their capacity and energy density;
[0003] Therefore, it is particularly critical and urgent to develop high-capacity, low-cost cathode materials for lithium-ion batteries. At present, there are still some problems in lithium-sulfur batteries, such as the poor conductivity of elemental sulfur and its reduced product lithium sulfide, which leads to low utilization of active materials. Low battery capacity retention, etc.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] A polypyrrole lithium-sulfur battery material, including a positive electrode and a negative electrode, the positive electrode includes a current collector and an active material a and an active material b at a weight ratio of 1:30, wherein the active material a is composed of the following parts by weight The raw materials are composed of:

[0025] Pyrrole 40, dibenzoyl peroxide 1, acetylene carbon black 50, triethanolamine 3, stearic acid 4, catalyst 0.012.

[0026] The catalyst is p-toluenesulfonic acid.

[0027] The preparation method of described activation material, comprises the following steps:

[0028] (1) get dibenzoyl peroxide, join in the dehydrated alcohol of its weight 17 times, stir, obtain initiator solution;

[0029] (2) Mix triethanolamine and pyrrole, add it to absolute ethanol that is 4 times the weight of the mixture, stir evenly, send it into the reaction kettle, feed nitrogen, adjust the temperature of the reaction kettle to 70°C, and add the ab...

Embodiment 2

[0038] A polypyrrole lithium-sulfur battery material, including a positive electrode and a negative electrode, the positive electrode includes a current collector and an active material a and an active material b with a weight ratio of 1:20, wherein the active material a is composed of the following parts by weight The raw materials are composed of:

[0039] Pyrrole 36, dibenzoyl peroxide 0.8, acetylene carbon black 43, triethanolamine 2, stearic acid 1, catalyst 0.01-.

[0040] The catalyst is p-toluenesulfonic acid.

[0041] The preparation method of described activation material, comprises the following steps:

[0042] (1) get dibenzoyl peroxide, join in the dehydrated alcohol of its weight 10 times, stir, obtain initiator solution;

[0043] (2) Mix triethanolamine and pyrrole, add it to absolute ethanol that is 3 times the weight of the mixture, stir evenly, send it into the reaction kettle, feed nitrogen, adjust the temperature of the reaction kettle to 60°C, and add th...

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Abstract

The invention discloses a polypyrrole lithium sulfur battery material which comprises a positive electrode and a negative electrode. The material is characterized in that the positive electrode includes a current collector, an active material a and an active material b, wherein the weight ratio of a to b is 1:20 to 30. According to the invention, the composite active material a composed of polypyrrole and acetylene carbon black and the composite active material b composed of elemental sulfur and porous carbon are blended and dried to enhance the tight bonding between the composite active material a and the carbon sulfur composite material; the dissolution of sulfur and a discharge product in an electrolyte is inhibited; the 'shuttle effect' is prevented; the utilization rate of sulfur is improved; and the cycle stability and capacity retention rate of the finished material are improved.

Description

technical field [0001] The invention belongs to the technical field, and in particular relates to a polypyrrole lithium-sulfur battery material. Background technique [0002] In recent years, with the decline of oil production and the intensification of global environmental pollution, countries around the world have generally recognized that clean and pollution-free electric vehicles to replace fuel vehicles is an inevitable choice for a country's sustainable development. The power battery technology with high specific capacity has become the key to the development of pure electric vehicles. At the same time, the rapid development of communication technology, space technology, and national defense industry has also greatly promoted the demand for small-volume, high-capacity rechargeable batteries. At present, lithium-ion batteries using lithium cobalt oxide, lithium manganese oxide, and lithium iron phosphate as positive electrode materials are limited by theoretical specif...

Claims

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Application Information

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IPC IPC(8): H01M4/36H01M4/38H01M4/60H01M4/62H01M10/052
CPCH01M4/364H01M4/38H01M4/608H01M4/625H01M4/628H01M10/052Y02E60/10
Inventor 袁孝友董相盛肖梦
Owner 安徽清泉新能源科技集团有限责任公司
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