Polypyrrole lithium sulfur battery material
A polypyrrole lithium-sulfur battery technology, which is applied in the direction of lithium batteries, battery electrodes, non-aqueous electrolyte batteries, etc., can solve the problems of low utilization rate of active materials, low battery capacity retention rate, theoretical specific capacity limit, etc., and achieve improved conductivity Stability, improve cycle stability and capacity retention, inhibit the effect of dissolving in the electrolyte
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Embodiment 1
[0024] A polypyrrole lithium-sulfur battery material, including a positive electrode and a negative electrode, the positive electrode includes a current collector and an active material a and an active material b at a weight ratio of 1:30, wherein the active material a is composed of the following parts by weight The raw materials are composed of:
[0025] Pyrrole 40, dibenzoyl peroxide 1, acetylene carbon black 50, triethanolamine 3, stearic acid 4, catalyst 0.012.
[0026] The catalyst is p-toluenesulfonic acid.
[0027] The preparation method of described activation material, comprises the following steps:
[0028] (1) get dibenzoyl peroxide, join in the dehydrated alcohol of its weight 17 times, stir, obtain initiator solution;
[0029] (2) Mix triethanolamine and pyrrole, add it to absolute ethanol that is 4 times the weight of the mixture, stir evenly, send it into the reaction kettle, feed nitrogen, adjust the temperature of the reaction kettle to 70°C, and add the ab...
Embodiment 2
[0038] A polypyrrole lithium-sulfur battery material, including a positive electrode and a negative electrode, the positive electrode includes a current collector and an active material a and an active material b with a weight ratio of 1:20, wherein the active material a is composed of the following parts by weight The raw materials are composed of:
[0039] Pyrrole 36, dibenzoyl peroxide 0.8, acetylene carbon black 43, triethanolamine 2, stearic acid 1, catalyst 0.01-.
[0040] The catalyst is p-toluenesulfonic acid.
[0041] The preparation method of described activation material, comprises the following steps:
[0042] (1) get dibenzoyl peroxide, join in the dehydrated alcohol of its weight 10 times, stir, obtain initiator solution;
[0043] (2) Mix triethanolamine and pyrrole, add it to absolute ethanol that is 3 times the weight of the mixture, stir evenly, send it into the reaction kettle, feed nitrogen, adjust the temperature of the reaction kettle to 60°C, and add th...
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