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A kind of highly waterproof and corrosion-resistant concrete and its preparation method

A technology for corrosion-resistant concrete and cement, applied in the field of inorganic cementitious materials, can solve the problems of poor seawater erosion resistance and poor durability.

Inactive Publication Date: 2020-10-27
道县宏达混凝土有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The purpose of the present invention is to provide a kind of high waterproof and corrosion-resistant concrete and its preparation method, to solve the disadvantages of poor seawater erosion resistance and poor durability of concrete in the prior art

Method used

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  • A kind of highly waterproof and corrosion-resistant concrete and its preparation method
  • A kind of highly waterproof and corrosion-resistant concrete and its preparation method
  • A kind of highly waterproof and corrosion-resistant concrete and its preparation method

Examples

Experimental program
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Effect test

Embodiment 1

[0031] In parts by weight, take 10 parts of graphene oxide, 10 parts of sepiolite, 8 parts of shell powder, 3 parts of water-soluble silicate, 20 parts of 42.5# ordinary Portland cement, and 1% of the cement mass Silica fiber; the graphene oxide edge is grafted with octadecylamine, and the grafting rate is 75%; in the sepiolite molecular skeleton, some magnesium ions are replaced by hydrogen ions, and the substitution rate is 90%; The nano-silica fiber is a short fiber with an aspect ratio of 3:1; the water-soluble silicate includes sodium silicate, potassium silicate and lithium silicate;

[0032] First mix graphene oxide, sepiolite, shell powder, water-soluble silicate and cement into the ball mill tank, and add zirconia ball mill beads according to the mass ratio of ball to material at 10:1, and the rotation speed is 350r / min. Under the condition of the revolution speed of 300r / min, after ball milling and mixing for 4 hours, the ball mill was obtained, and the ball mill and...

Embodiment 2

[0034] In parts by weight, 15 parts of graphene oxide, 15 parts of sepiolite, 9 parts of shell powder, 4 parts of water-soluble silicate, 40 parts of 42.5# ordinary Portland cement, and nano Silica fiber; the graphene oxide edge is grafted with octadecylamine, and the grafting rate is 80%; in the sepiolite molecular skeleton, some magnesium ions are replaced by hydrogen ions, and the substitution rate is 92%; The nano-silica fiber is a short fiber with an aspect ratio of 5:1; the water-soluble silicate includes sodium silicate and lithium silicate;

[0035] First mix graphene oxide, sepiolite, shell powder, water-soluble silicate and cement into the ball mill tank, and add zirconia ball mill beads according to the ball-to-material mass ratio of 20:1, and the rotation speed is 400r / min. Under the condition of the revolution speed of 400r / min, after ball milling and mixing for 5 hours, the ball mill was obtained, and the ball mill and nano-silica fibers were transferred to the m...

Embodiment 3

[0037]In parts by weight, 20 parts of graphene oxide, 20 parts of sepiolite, 10 parts of shell powder, 5 parts of water-soluble silicate, 60 parts of 42.5# ordinary Portland cement, and 10% of cement quality nano Silica fiber; the edge of the graphene oxide is grafted with octadecylamine, and the grafting rate is 90%; part of the magnesium ions in the molecular skeleton of the sepiolite is replaced by hydrogen ions, and the substitution rate is 98%; The nano-silica fiber is a short fiber with an aspect ratio of 10:1; the water-soluble silicate includes sodium silicate, potassium silicate and lithium silicate;

[0038] First mix graphene oxide, sepiolite, shell powder, water-soluble silicate and cement into the ball mill tank, and add zirconia ball mill beads according to the mass ratio of ball to material at 30:1, and the rotation speed is 450r / min. Under the condition of the revolution speed of 500r / min, after ball milling and mixing for 6 hours, the ball abrasive was obtaine...

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Abstract

The invention discloses a high waterproof and corrosion-resistant concrete and a preparation method thereof, comprising graphene oxide, sepiolite, shell powder, water-soluble silicate, cement and nano-silica fiber; wherein the edge of graphene oxide is grafted with Octadecylamine, the grafting rate is not less than 75%; part of the magnesium ions in the molecular skeleton of sepiolite is replaced by hydrogen ions, and the substitution rate is not less than 90%; while the nano-silica fiber is short fiber; in the preparation of the product At the same time, first mix graphene oxide, sepiolite, shell powder, water-soluble silicate and cement into the ball mill tank, and add anhydrous sodium sulfate with 1 to 3% graphene oxide mass, and mix for 4 to 6 hours after ball milling , and then add nano-silica fibers, stir and mix for 1-3 hours, and then discharge to obtain. The product obtained by the invention has good corrosion resistance and can maintain long-term stability in seawater environment.

Description

technical field [0001] The invention relates to the technical field of inorganic gelling materials, in particular to a highly waterproof and corrosion-resistant concrete and a preparation method thereof. Background technique [0002] In the marine environment, there are many materials used for concrete repair, commonly used are polymer repair materials, epoxy resin repair materials and cement-based repair materials. Studies have shown that in the marine environment, although the bonding performance of polymer mortar is higher than that of self-compacting cement mortar, its durability is worse than that of self-compacting cement mortar; in the marine ultra-fine area, the bonding performance of epoxy resin material is poor in ordinary Portland cement. Therefore, compared with polymer repair materials and epoxy resin repair materials, cement-based repair materials are more suitable for repairing concrete structures in marine environments. Although the bonding strength of ordi...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C04B28/04C04B111/24C04B111/27
CPCC04B28/04C04B2201/50C04B2111/20C04B2111/28C04B14/024C04B14/042C04B14/28C04B12/04C04B14/4631
Inventor 张国浩
Owner 道县宏达混凝土有限公司