Multifunctional polar polyolefin material as well as metal complex material, preparation method and application thereof

A technology of metal complexes and polyolefins, applied in adhesives, etc., can solve the problems of no ternary copolymerization, no polyolefin materials and their properties, no ternary copolymerization, etc., and achieve the effect of enhanced adhesion strength

Active Publication Date: 2020-04-28
UNIV OF SCI & TECH OF CHINA
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In addition, there is no report on the terpolymerization of ethylene, eugenol and another α-olefin, nor the terpolymerization of ethylene with eugenol

Method used

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  • Multifunctional polar polyolefin material as well as metal complex material, preparation method and application thereof
  • Multifunctional polar polyolefin material as well as metal complex material, preparation method and application thereof
  • Multifunctional polar polyolefin material as well as metal complex material, preparation method and application thereof

Examples

Experimental program
Comparison scheme
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preparation example Construction

[0048] In the preparation method of the present invention, the polymerization temperature is preferably 50-100°C, such as 80°C; the ethylene pressure is preferably 1-15 atmospheres (atm), more preferably 3-9 atm; the α-olefin comonomer is a gas The pressure under the situation of can be 1~15atm, and under the situation of liquid, its concentration in reaction solvent can be 0.05~10mol / L, more preferably 0.1~4mol / L; Eugenol comonomer concentration is in The concentration in the reaction solvent is preferably 0.05-10 mol / L, more preferably 0.1-2 mol / L; polymerization time: 0.5-12 h, preferably 1-12 h, for example about 2 h.

[0049] In the present invention, the copolymerization reaction can be carried out in the presence of an additionally added organic solvent, that is, the copolymerization reaction is carried out in a solution, which can be called solution polymerization. Preferably, the organic solvent usable in the present invention is toluene, xylene, chlorobenzene, n-hexa...

Embodiment 1-12

[0069] Example 1-12: Preparation and performance testing of multifunctional polar polyolefin materials

[0070] (1) Preparation of Embodiment 1-10:

[0071] In a glove box, under a nitrogen atmosphere, comonomers (i.e., α-olefin comonomer (Hex) and eugenol mono The respective molar concentrations of the monomers (Eug, Eug-Si or Eug-OH) are indicated in brackets after the corresponding comonomers. For example, when the total reactant volume is 20mL, for the random obtained in Example 4 Copolymer E / Eug-Si(0.1) / Hex(4), the molar number of Eug-Si comonomer is 2mmol, and the molar number of Hex comonomer is 80mmol), and add and dissolve in 1mL 20 μmol of catalyst PO-Pd in ​​dichloromethane. Then, connect the ethylene gas source pipeline to feed ethylene (monomer E) gas into the reactor, and after adjusting the ethylene pressure to 8atm or 3atm, under magnetic stirring, the reactor was heated to 80°C by heating in a water bath and heated in a water bath. React under magnetic stir...

Embodiment 13-14

[0100] Examples 13-14: Preparation of multifunctional polar polyolefin metal Fe complex materials and testing of their mechanical properties and scratch repair properties

[0101] (1) Preparation:

[0102] Under a nitrogen atmosphere, in a 100 mL reaction flask with a branch tube, dissolve 3 g of the multifunctional polyolefin material prepared in Example 11 or 12 above in 60 mL of tetrahydrofuran heated to 40 ° C by a water bath, and then add 1 mL of / L of ferric nitrate nonahydrate (FeNO 3 9H 2 (2) After the aqueous solution (deionized water) was mixed uniformly by magnetic stirring, the sodium hydroxide aqueous solution of 2.25mol / L was added dropwise to a pH value of about 8. Then filter under reduced pressure to obtain a solid precipitate, wash three times with 15ml of methanol, and dry it in a vacuum oven at 50°C to obtain the desired Fe complex material (expressed as E / Eug-Si(0.1) / Hex (4)-HCL-Fe).

[0103] (2) Mechanical performance test:

[0104] The obtained mult...

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Abstract

The invention relates to a novel multifunctional polar polyolefin material as well as a metal complex material, a preparation method and an application thereof. The multifunctional polar polyolefin material is a random copolymer formed by copolymerizing an ethylene monomer represented by a formula CH2 = CH2, an alpha-olefin comonomer represented by a formula CH2 = CH-(CH2) m-CH3 and an eugenol comonomer represented by the formula, wherein m, X and Y are as defined herein, the multifunctional polar polyolefin material can be simply and effectively prepared under mild conditions, and can be usedas a compatible agent and an adhesive, and a multifunctional polar polyolefin metal complex material with significantly improved mechanical properties and a self-repairing function can be obtained after transition metal modification.

Description

technical field [0001] The invention belongs to the field of functional polymer polyolefin materials, and in particular relates to multifunctional polar polyolefin materials and metal complex materials, preparation methods and applications thereof. Background technique [0002] Since the last century, polymer materials have penetrated into every aspect of human life, partly due to their excellent thermal, mechanical, rheological and even optical properties, which can be adjusted by adjusting the composition and structure of the polymer or changing the polarity The types of functional groups are fine-tuned. Polyolefins, derived from readily available low-cost olefin feedstocks such as ethylene, propylene and other α-olefins, have become the most widely produced polymers in the world. Because of its cheap, light and durable characteristics, it has been used as a substitute for traditional materials such as wood, metal and glass, and is widely used in pipes, films, packaging, ...

Claims

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Application Information

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IPC IPC(8): C08F210/16C08F210/14C08F230/08C08F8/12C08G83/00C08L23/08C09J123/08
CPCC08F8/12C08F210/16C08G83/008C08L23/0892C09J123/0892C08F210/14C08F230/08
Inventor 陈昶乐那银娜
Owner UNIV OF SCI & TECH OF CHINA
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