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A kind of plugging and anti-collapse treatment agent for shale formation and preparation method thereof

A technology for plugging anti-slump and treatment agents, which is applied in the direction of chemical instruments and methods, drilling compositions, etc., can solve the problems of uncontrollable fixed material size, affecting pump pressure stability, poor temperature resistance, etc., and achieves production Low cost, stable product quality, and enhanced stability

Active Publication Date: 2022-05-03
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, polymeric alcohol plugging materials have poor temperature resistance and unstable cloud point, which affects the stability of pump pressure. There are also defects such as short residence time, fixed and uncontrollable material size, and prominent foaming problems.

Method used

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  • A kind of plugging and anti-collapse treatment agent for shale formation and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] Into a 500mL there-necked bottle for three times, add 50g C9 petroleum resin, 20g polyethylene glycol (molecular weight 500), 10g polyether modified trisiloxane, add 100mL 1,2-dichloroethane, stir Until each component is fully dispersed, control the temperature at 10°C, add 0.1g of palladium chloride catalyst, react for 1h, add 1g of sulfur, continue the reaction for 1h, use vacuum distillation technology to recover the organic solvent, dry and pulverize the residue to obtain 75g The yellow powder is the plugging and anti-collapse treatment agent for the shale formation.

Embodiment 2

[0028] After pumping and exchanging air three times into a 1000mL three-necked bottle, add 150g C5 petroleum resin, 10g polyethylene glycol (molecular weight 1000), 20g vinyl triperoxy tert-butylsilane, add 300mL carbon tetrachloride, and stir until each group Fully disperse, control the temperature at 30°C, add 0.05g of rhodium chloride catalyst, react for 3 hours, add 10g of thiourea, continue to react for 24 hours, use vacuum distillation technology to recover the organic solvent, dry and pulverize the residue to obtain 165g of yellow powder , which is the plugging and anti-collapse treatment agent for the shale formation.

Embodiment 3

[0030] Into a 1000mL three-necked bottle, after pumping and exchanging air three times, add 100g of C9 petroleum resin and 20g of coumarone resin, 50g of polyethylene glycol (molecular weight 2000), 10g of polyether modified dimethyl siloxane and, add 200mL Ethyl acetate and 100mL chloroform, stir until the components are fully dispersed, control the temperature at 30°C, add 0.05g of rhodium chloride catalyst, react for 3 hours, add 10g of thiourea, continue the reaction for 24 hours, and use vacuum distillation technology to recover the organic solvent , dry and pulverize the residue to obtain 165g of yellow powder, which is the plugging and anti-collapse treatment agent for the shale formation.

[0031] Plugging performance evaluation

[0032] Determination of filtration loss at high temperature and high pressure (test temperature: 150°C)

[0033] Divide the treatment agent in Examples 1 to 3 into several parts, and add to 4% drilling fluid base slurry respectively (the spe...

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PUM

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Abstract

The invention relates to a plugging and anti-collapse treatment agent for shale formations in the field of chemicals for shale formation drilling and a preparation method thereof; the plugging and anti-slump treatment agent for shale formations comprises oil-soluble resin, polyethylene Components including diol, silicone modifier, and cross-linking modifier are used as raw materials, dissolved in an organic solvent, and under the action of a catalyst, through temperature-controlled reaction, solvent recovery, and dry crushing to obtain the shale formation. Plugging and anti-slump treatment agent; the plugging and anti-slump treatment agent for shale formations has the functions of adsorption and film formation, wetting reversal, bonding and wall strengthening, etc., and at the same time uses its own size to plug and bond to bridge cracks and prevent hydration It can reduce the filtration loss of drilling fluid and improve the plugging ability of drilling fluid, which can effectively solve the problems of fluorescence and foaming of existing plugging and anti-slump materials, and effectively improve the stability of wellbore walls in shale formations. The process is simple, the production cost is low, and the product quality is stable, so it is worth popularizing and applying.

Description

technical field [0001] The invention relates to the field of chemicals for drilling wells in shale formations, and more particularly relates to a plugging and anti-collapse treatment agent for shale formations and a preparation method thereof. Background technique [0002] The commercial exploitation of shale gas resources in North America has achieved great success. The proportion of unconventional natural gas in the energy supply of North America is getting higher and higher, which basically changed the energy supply and demand structure in Canada and the United States, and also stimulated the upsurge of shale gas resource development in my country. . my country's shale gas resources are abundant and widely distributed, with broad prospects for development. However, bedding and micro-fractures are developed in shale formations, and the invasion of drilling fluid can easily cause the dispersion and peeling of shale rock mass, resulting in block loss and collapse. The size ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09K8/24C09K8/512
CPCC09K8/24C09K8/512C09K8/5086
Inventor 林永学孔勇金军斌刘贵传杨帆甄剑武高书阳陈晓飞
Owner CHINA PETROLEUM & CHEM CORP
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