Fluorine-silicon composite visible-light-catalyzed antibacterial antifouling coating material and preparation method thereof

An anti-fouling coating and visible light technology, applied in anti-fouling/underwater coatings, coatings, devices for coating liquids on surfaces, etc., can solve the problems of coating hardness not meeting the requirements, substrate detachment, and low coating surface Energy and other issues, to achieve the effect of strength improvement, surface biofouling prevention, and high light transmittance

Active Publication Date: 2020-05-22
QUZHOU RES INST OF ZHEJIANG UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] However, the low surface energy of the coating film obtained by polymerization of a single fluorine-containing acrylate makes it easy to separate from the substrate after curing, and the hardness of the coating obtained by silicon-containing acrylate does not meet the requirements.

Method used

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  • Fluorine-silicon composite visible-light-catalyzed antibacterial antifouling coating material and preparation method thereof
  • Fluorine-silicon composite visible-light-catalyzed antibacterial antifouling coating material and preparation method thereof
  • Fluorine-silicon composite visible-light-catalyzed antibacterial antifouling coating material and preparation method thereof

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Embodiment Construction

[0036] Below in conjunction with specific embodiment and comparative example the invention is described in further detail. The examples can enable those skilled in the art to understand the present invention more comprehensively, but do not limit the present invention in any way.

[0037] The preparation and application method of the fluorine-silicon composite visible light catalyzed antibacterial antifouling coating comprises the following steps:

[0038] step one:

[0039] Take 60-90 parts by weight of fluorine-containing (meth)acrylate monomers, 10-30 parts by weight of silicon-containing (meth)acrylate monomers, 10-40 parts by weight of acrylate monomers and 5-30 parts by weight Reactive silane coupling agent in parts by weight, mixed evenly; then add azobisisobutyronitrile as an initiator, the initiator accounts for 0.2% of the total weight of all monomers; then add hydrofluoric acid equal to the total weight of all monomers Ether, react at 70°C for 5-10 hours to obtain...

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Abstract

The invention relates to a coating material preparation technology, and provides a fluorine-silicon composite visible-light-catalyzed antibacterial antifouling coating material and a preparation method thereof. The coating material comprises the following components in percentage by mass: 20-60% of a fluorine-silicon-containing acrylic resin solution, 0.1-20% of propylene glycol methyl ether acetate, 0.1-20% of a nano semiconductor material with photocatalytic response, 0.1-20% of nano silicon oxide and 30-75% of an organic solvent, wherein the nano semiconductor material with photocatalytic response is nano silver vanadate or a combination of nano silver vanadate and a reinforced nano semiconductor material, and the reinforced nano semiconductor material is at least one of nano titanium dioxide and nano silver powder. According to the invention, the fluorine-silicon composite visible-light-catalyzed antibacterial antifouling coating material has the advantages of high light transmittance, good scrub resistance and good solvent resistance, and has the self-cleaning antifouling function; and by introducing the photocatalytic antibacterial nano-filler, fouling microorganisms are inactivated at the initial stage of microbial fouling formation, and a long-acting self-cleaning effect is achieved under the characteristic of low surface energy of the coating.

Description

technical field [0001] The invention relates to coating preparation technology, in particular to a fluorine-silicon composite visible light catalyzed antibacterial and antifouling coating and a preparation method thereof. The coating can be used for antibacterial and antifouling protection of glass and other transparent or opaque inorganic non-metallic or metal surfaces, as well as for anticorrosion and antifouling of plastic surfaces and metal plated parts, wear-resistant coatings, insulation and antifouling of electronic components . Background technique [0002] In many occasions in life, glass is used as a decorative or protective surface material. However, the glass surface is rich in hydroxyl groups, which is a hydrophilic surface. When it encounters rainy days or water vapor in the air encounters a supercooled glass surface, a water film will be formed on the glass surface, which is easily contaminated by dust and other sundries. For example, the glass curtain wall ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D5/14C09D5/16C09D133/16C08F220/24C08F230/08C08F220/14C08F220/18B05D7/24
CPCB05D7/24B05D2518/10C08F220/24C08K2003/0806C08K2003/2241C08K2201/011C09D5/14C09D5/1662C09D5/1687C09D143/04C08K3/22C08K3/36C08K3/08
Inventor 张庆华郭鸿宇詹晓力陈丰秋程党国
Owner QUZHOU RES INST OF ZHEJIANG UNIV
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