Anti-shearing flame-retardant glass fiber composite material

A composite material and anti-shear technology, applied in the field of composite materials, can solve problems affecting performance stability and service life, poor compatibility, complex components, etc., to improve process performance and mechanical properties, and improve wear resistance , Improve the effect of comprehensive performance

Inactive Publication Date: 2020-06-19
邓华斌
View PDF6 Cites 1 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In this invention, calcium carbonate and glass fiber are respectively subjected to cyanamide and epoxidation treatment, the surfaces of calcium carbonate and glass fiber are fully organicized, and then blended and dispersed into polycarbonate, effectively improving the calcium carbonate and glass fiber in the polycarbonate. Compatibility in organic polycarbonate, thereby improving the stability of the finished product, however, the composition of the invention is complex, the compatibility between the components is not good, and extravasation will occur during long-term use, affecting performance stability and service life

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0029] A shear-resistant flame-retardant glass fiber composite material, characterized in that it includes the following components in parts by weight: 70 parts of hyperbranched borate ester, 4 parts of epoxy fluorophenyl sulfone calixyrrole, glass fiber 20 parts, 1 part of 2,2'-dihydroxy-4,4'-dimethoxybenzophenone-5,5'-disulfonic acid, 1 part of silane coupling agent KH5501, 0.2 part of phosphorus pentoxide; The aspect ratio of the glass fiber is 50.

[0030] The preparation method of described epoxy group fluorophenyl sulfone group calixyrrole, comprises the steps:

[0031] Step S1. Add Meso-tetramethyl-meso-tetra-p-aminophenylcalix[4]pyrrole and epichlorohydrin to dimethyl sulfoxide, add sodium hydroxide to it, and stir the reaction at 80°C 6 After hours, the insolubles were removed by filtration, and the solvent was removed by rotary evaporation to obtain epoxy-modified Meso-tetramethyl-meso-tetra-p-aminophenyl calix[4]pyrrole; the Meso-tetramethyl-meso-tetramethyl The m...

Embodiment 2

[0036] A shear-resistant flame-retardant glass fiber composite material, characterized in that it includes the following components in parts by weight: 75 parts of hyperbranched borate ester, 5 parts of epoxy-based fluorophenylsulfone-based calixyrrole, glass fiber 22 parts, 1.5 parts of 2,2'-dihydroxy-4,4'-dimethoxybenzophenone-5,5'-disulfonic acid, 1.2 parts of silane coupling agent KH560, 0.3 parts of phosphorus pentoxide Parts; The aspect ratio of the glass fiber is 80.

[0037] The preparation method of described epoxy group fluorophenyl sulfone group calixyrrole, comprises the steps:

[0038] Step S1, adding Meso-tetramethyl-meso-tetra-p-aminophenyl calix[4]pyrrole and epichlorohydrin to N,N-dimethylformamide, and adding potassium hydroxide to it, at 83 Stir the reaction at ℃ for 6.5 hours, then remove the insoluble matter by filtration, and remove the solvent by rotary evaporation to obtain epoxy-modified Meso-tetramethyl-meso-tetra-p-aminophenyl calix[4]pyrrole; the M...

Embodiment 3

[0043] A shear-resistant flame-retardant glass fiber composite material, characterized in that it includes the following components in parts by weight: 80 parts of hyperbranched borate ester, 6 parts of epoxy fluorophenyl sulfone calixyrrole, glass fiber 25 parts, 2,2'-dihydroxy-4,4'-dimethoxybenzophenone-5,5'-disulfonic acid 2 parts, silane coupling agent KH5701.5 parts, phosphorus pentoxide 0.35 Parts; the aspect ratio of the glass fiber is 100.

[0044] The preparation method of described epoxy group fluorophenyl sulfone group calixyrrole, comprises the steps:

[0045] Step S1, adding Meso-tetramethyl-meso-tetra-p-aminophenylcalix[4]pyrrole and epichlorohydrin to N,N-dimethylacetamide, and adding sodium carbonate to it, at 85°C The reaction was stirred for 7 hours, and the insolubles were removed by filtration, and the solvent was removed by rotary evaporation to obtain epoxy-modified Meso-tetramethyl-meso-tetra-p-aminophenyl calix[4]pyrrole; the Meso-tetramethyl The mola...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

No PUM Login to view more

Abstract

The invention discloses an anti-shearing flame-retardant glass fiber composite material. The material is characterized by being prepared from the following components in parts by weight: 70 to 90 parts of hyperbranched borate, 4 to 8 parts of epoxy fluorophenyl sulfuryl calixpyrrole, 20 to 30 parts of glass fiber, 1 to 3 parts of 2, 2'-dihydroxy-4, 4'-dimethoxybenzophenone-5, 5'-disulfonic acid, 1to 2 parts of coupling agent and 0.2 to 0.5 part of phosphorus pentoxide. The invention also discloses a preparation method of the anti-shearing flame-retardant glass fiber composite material. The anti-shearing flame-retardant glass fiber composite material disclosed by the invention is better in comprehensive performance, better in performance stability, higher in shearing force strength, more excellent in heat resistance and flame retardance and easier to process and form.

Description

technical field [0001] The invention relates to the technical field of composite materials, in particular to a shear-resistant flame-retardant glass fiber composite material and a preparation method thereof. Background technique [0002] In recent years, with the development of the economy and the advancement of science and technology, various high value-added materials have emerged one after another, bringing more excitement to people's lives. Composite material is one of the more common ones, which is composed of two or more materials with different properties, through physical or chemical methods, to form materials with new properties on the macro (micro) level. Since various materials learn from each other in terms of performance and produce synergistic effects, the comprehensive performance of composite materials is better than that of the original constituent materials to meet various requirements. [0003] Glass fiber composite material is a new type of composite mat...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
IPC IPC(8): C08L85/04C08K13/04C08K7/14C08K5/544C08K5/47C08K5/41C08K5/5425C08K5/5435
CPCC08K5/41C08K5/47C08K5/5425C08K5/5435C08K5/544C08K7/14C08K13/04C08K2201/016C08L2201/02C08L2201/08C08L2312/00C08L85/04
Inventor 不公告发明人
Owner 邓华斌
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products