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A highly wear-resistant and modified technology, applied in the field of plastics, can solve the problems of reduced mechanical properties and flexibility of the plastic body
Inactive Publication Date: 2020-07-03
界首市宏利塑料股份有限公司
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Problems solved by technology
In traditional wear-resistant plastics, relevant wear-resistant additives are added to the polypropylene matrix to improve the wear resistance of plastic filaments. However, a large amount of wea
Method used
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Embodiment 1
[0023] The preparation method of modified polypropylene is:
[0024] S1, preparation of modifier
[0025] Add 1mol 1-octyne, 1.05mol bistrimethylsiloxymethylsilane, 3mmol catalyst chloroplatinic acid and 1L solvent isopropanol into the reaction kettle, feed nitrogen for 15min, replace the air in the reaction kettle, and Heat up to 80°C while stirring, keep warm and stir to react for 6 hours. After the reaction, remove the solvent by rotary evaporation, wash with anhydrous ether, and dry to obtain the modifier shown in formula N; the yield is 92.5%, and the reaction formula is as follows Shown:
[0026]
[0027] S2, preparation of modified polypropylene
[0028] Add 1 kg of deionized water, 1.5 g of emulsifier polyoxypropylene ether, 1.5 g of initiator sodium persulfate, and 77 g of propylene monomer into the reactor, transfer the reactor to a water bath, and perform prepolymerization at a temperature of 55 ° C React for 30 minutes, then remove the reaction kettle from th...
Embodiment 2
[0030] A high wear-resistant PP rope, including the following raw materials in parts by weight: 100g modified polypropylene, 15g filler, 8g EPDM rubber, 0.6g plasticizer, 0.4g antioxidant, 2g paraffin oil, 0.6g lubricant agent;
[0031] Described filler is calcium carbonate;
[0032] Described plasticizer is epoxy fatty acid methyl ester;
[0033] Said antioxidant is antioxidant 168;
[0034] Described lubricant is zinc stearate.
Embodiment 3
[0036] A high wear-resistant PP rope, including the following raw materials in parts by weight: 120g modified polypropylene, 17g filler, 12g EPDM rubber, 1.2g plasticizer, 0.4g antioxidant, 3g paraffin oil, 1g lubricant ;
[0037] Described filler is calcium carbonate;
[0038] Described plasticizer is diethyl terephthalate;
[0039] Said antioxidant is antioxidant 168;
[0040] Described lubricant is zinc citrate.
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Abstract
The invention discloses a high-wear-resistance PP rope. The high-wear-resistance PP rope comprises the following raw materials in parts by weight: 100 to 150 parts of modified polypropylene, 15 to 20parts of a filler, 6 to 12 parts of ethylene propylene diene monomer, 0.5 to 1.2 parts of a plasticizer, 0.3 to 0.5 part of an antioxidant, 1.5 to 3 parts of paraffin oil and 0.5 to 1 part of a lubricant. According to the invention, polypropylene is modified, and organic silicon is introduced in a bonding manner. Specifically, an emulsion polymerization mode is adopted; a propylene monomer is pre-polymerized, then a modifier is added, and double bonds on the modifier are copolymerized with propylene so as to be embedded into polypropylene, so the polypropylene containing organic silicon is obtained; and due to introduction of the organic silicon, the unit density of a polypropylene chain segment is increased, the mechanical strength and the flexibility of the polypropylene are greatly improved, and the bearing stress of the polypropylene is enhanced, so the wear resistance of the PP rope is further improved.
Description
technical field [0001] The invention belongs to the technical field of plastics, and in particular relates to a high wear-resistant PP rope. Background technique [0002] Most of the plastic ropes on the market today are based on polypropylene (PP), which has been the fastest growing major thermoplastic, especially in fiber and filament, film extrusion, injection molding processing, etc. Polypropylene's excellent flow properties and wide range of flow rates, combined with other unique polymer properties, give it excellent processability. The lower flow rate can meet the processing requirements of extruded tape, tape filament and monofilament, etc., and can also make the finished product have tensile strength and low elongation, while maintaining sufficient transverse integrity, so that the winding machine guide device The splitting and dusting conditions are kept to a minimum. Main features: non-toxic, odorless, low density, strength, stiffness, hardness and heat resistanc...
Claims
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Application Information
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