The invention discloses an environment-friendly building wall system. The environment-friendly building wall system comprises an outer wall, a ventilation and water-replenishing system, a discharge system, a rainwater collection tank, a rainwater storage chamber and an electric control system. The outer wall is composed of a wall body, a moisture-proof layer, a light concrete layer, a heat insulation layer and a plant layer sequentially from inside to outside; the rainwater collection tank is arranged at the position, close to the exterior, of the top of the heat insulation layer of the outerwall; and the rainwater storage chamber is formed in the bottom of the light concrete layer of the outer wall. According to the environment-friendly building wall system, the technology that negativeion generation by plants is promoted through electric simulation is applied to the plant outer wall of an environment-friendly building creatively, the unique system design is adopted to solve the problems of installation, construction, water replenishing and power supply of the plant outer wall, the technology that negative ion generation by the plants is promoted through electric simulation andthe plant outer wall can be utilized to build a small environment with clean air and the suitable temperature outside the building, the air purification capability of the plant wall in unit area and unit density is improved, and the environment-friendly building has the environment-friendly and energy-saving effects.