High-capacity-density lithium ion battery negative electrode

A lithium-ion battery, high-capacity technology, used in battery electrodes, secondary batteries, circuits, etc., to solve problems such as consumption, rupture, and separation of electrode materials and current collectors

Active Publication Date: 2020-07-07
BERZELIUS (NANJING) CO LTD +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Therefore, the consequence is that silicon has a serious volume effect in the process of completely inserting and removing lithium, and the volume change rate is about 400%. Most of them lose their electrochemical activity; in addition, due to the volume effect during charge and discharge, the solid electrolyte interface (SEI) protective layer formed on the surface of the silicon material

Method used

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  • High-capacity-density lithium ion battery negative electrode
  • High-capacity-density lithium ion battery negative electrode
  • High-capacity-density lithium ion battery negative electrode

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0077] The negative electrode formula is replaced by: polysilicon particles (median particle size D50=0.8 micron, maximum particle size D100=2.5 ​​micron) coated with carbon by chemical vapor deposition of the negative active material and conductive agent multi-armed carbon nanotubes, conductive graphite, The mass ratio of thickener carboxymethylcellulose sodium (CMCNa), sodium polyacrylate (PAANa), binder styrene-butadiene rubber (SBR), and polystyrene acrylic acid copolymer is 80:2:3:3:4: 5:3; electrode porosity is 35%. Among them, the powder obtained by crushing polysilicon is coated with carbon on the surface by chemical vapor deposition: the polysilicon powder is placed in the center of the tube furnace, and acetylene is introduced as the precursor of the carbon coating layer, and the surface coating is obtained by heating at 940°C for 2.5 hours. Carbon-coated polysilicon powder. The amount of carbon coated on the surface of silicon particles is 4.5%.

[0078] figure 1...

Embodiment 2

[0081] The negative electrode formula is replaced by: polysilicon particles (median particle size D50=0.8 micron, maximum particle size D100=2.5 ​​micron) coated with carbon by chemical vapor deposition of the negative active material and conductive agent multi-armed carbon nanotubes, conductive graphite, The mass ratio of thickener carboxymethylcellulose sodium (CMCNa), sodium polyacrylate (PAANa), binder styrene-butadiene rubber (SBR), and polystyrene acrylic acid copolymer is 80:2:3:3:4: 5:3; electrode porosity is 35%. Among them, the powder obtained by crushing polysilicon is coated with carbon on the surface by chemical vapor deposition: the polysilicon powder is placed in the center of the tube furnace, and acetylene is introduced as the precursor of the carbon coating layer, and the surface coating is obtained by heating at 940°C for 2.5 hours. Carbon-coated polysilicon powder. The amount of carbon coated on the surface of silicon particles is 4.5%.

[0082] The rever...

Embodiment 3

[0084] The negative electrode formula is replaced by: polysilicon particles (median particle size D50=0.8 micron, maximum particle size D100=2.5 ​​micron) coated with carbon by chemical vapor deposition of the negative active material and conductive agent multi-armed carbon nanotubes, conductive graphite, The mass ratio of thickener carboxymethylcellulose sodium (CMCNa), sodium polyacrylate (PAANa), binder styrene-butadiene rubber (SBR), and polystyrene acrylic acid copolymer is 80:2:3:3:4: 5:3; electrode porosity is 35%. Among them, the powder obtained by crushing polysilicon is coated with carbon on the surface by chemical vapor deposition: the polysilicon powder is placed in the center of the tube furnace, and acetylene is introduced as the precursor of the carbon coating layer, and the surface coating is obtained by heating at 940°C for 2.5 hours. Carbon-coated polysilicon powder. The amount of carbon coated on the surface of silicon particles is 4.5%.

[0085] The rever...

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Abstract

The invention relates to a high-capacity-density lithium ion battery negative electrode. The negative electrode comprises surface-modified silicon particles, a carbon conductive agent capable of forming a conductive network, an organic polymer binder with high tensile strength and high elastic deformation characteristics, and a current collector substrate beneficial to electron conduction. The capacity of the negative electrode is greatly improved, and the compaction density is not much lower than that of the traditional graphite negative electrode, so that the negative electrode has the characteristic of high capacity density. When the negative electrode is applied to a lithium ion battery, the lithium ion battery with high energy density can be obtained. The lithium ion negative electrode is prepared by adopting common means and processes in industrial production in the current lithium battery industry; the method is simple, efficient and low in cost, and commercial production of thehigh-capacity-density lithium ion battery negative electrode can be achieved.

Description

technical field [0001] The invention relates to the field of lithium-ion batteries, in particular to a high-capacity-density lithium-ion battery negative electrode. Background technique [0002] In recent years, with the gradual consumption of traditional fossil energy and the increasingly serious problem of global warming, people are increasingly aware of the importance of new energy in the future society. In all new energy systems, solar energy, wind energy, water energy, nuclear energy, etc. do not have convenient mobility; and lithium-ion batteries, as a portable form of energy storage, have their specific irreplaceability in practical applications So it is widely used. [0003] In 2017, before China’s National Development and Reform Commission stated that it would stop selling domestic traditional fuel vehicles in 2030, many countries had already announced a timetable for a complete ban on the sale of fuel vehicles: Britain and France set the target time for a complete...

Claims

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Application Information

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IPC IPC(8): H01M4/36H01M4/38H01M4/62H01M4/134H01M4/1395H01M10/0525B82Y30/00
CPCH01M4/366H01M4/386H01M4/625H01M4/134H01M4/1395H01M10/0525B82Y30/00Y02E60/10
Inventor 王岑张和宝李喆叶兰
Owner BERZELIUS (NANJING) CO LTD
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