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A water-based nano heavy-duty anti-corrosion coating for chemical sewage pools and its preparation

A technology for chemical sewage and heavy anti-corrosion, applied in anti-corrosion coatings, coatings, polyurea/polyurethane coatings, etc., can solve problems such as fast curing speed, reduced coating performance, poor adhesion, etc., and achieve improved anti-corrosion performance. Effects of strength and compactness

Active Publication Date: 2021-11-19
SHENYANG RES INST OF CHEM IND +2
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

If a leak occurs, the company will bear high economic losses such as stopping production and dealing with environmental pollution caused by the leak
[0003] At present, the coatings used to solve the anticorrosion of chemical sewage pools are mainly rubber coatings such as epoxy glass fiber reinforced plastics, vinyl resins, and polyvulcanized rubber, as well as traditional polyurea coatings. The performance of the medium is relatively single and the durability is poor, which is easy to cause the coating to be eroded, swelled, leaked or the whole coating is peeled off from the substrate, and the adhesion is not good; (2) The elasticity is low and cannot expand with the shrinkage of the substrate And produce corresponding elastic deformation; (3) more toxic and harmful VOC components are produced during construction, which will cause great harm to the health of construction workers and the environment; (4) the construction method is single, such as traditional polyurea anti-corrosion coatings. However, its curing speed is too fast, which reduces the performance of the coating and requires higher construction technology.

Method used

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  • A water-based nano heavy-duty anti-corrosion coating for chemical sewage pools and its preparation
  • A water-based nano heavy-duty anti-corrosion coating for chemical sewage pools and its preparation
  • A water-based nano heavy-duty anti-corrosion coating for chemical sewage pools and its preparation

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0044] In parts by weight, each component is mixed according to the ratio recorded in Table 1

[0045] Preparation process of mixed phosphate color paste: add 4 parts of color powder to the mixed phosphate ester of 4 parts of triethyl phosphate and 7 parts of tricresyl phosphate under stirring at 200r / min, and grind to 0.5 μm in a horizontal sand mill Next, a mixed phosphate ester color paste is obtained.

[0046] The preparation process of component A: Mix 60 parts of liquefied MDI and 20 parts of LTW resin at 500r / min under the condition of dry air protection to make a mixed resin, stir and add 15 parts of mixed phosphate ester color paste under the condition of dry air protection at 500r / min , 2 parts of wetting agent, 2 parts of defoamer, stir at 700r / min and add 2 parts of anti-sagging agent, stir evenly, and obtain component A after filtering.

[0047] The preparation process of component B: Add 60 parts of deionized water to 40 parts of potassium silicate powder with a...

Embodiment 2

[0060] The difference from Example 1 is:

[0061] Preparation process of mixed phosphate color paste: add 4 parts of color powder to the mixed phosphate of 4 parts of triethyl phosphate and 7 parts of tricresyl phosphate under stirring state, and grind it to below 0.5 μm in a horizontal sand mill.

[0062] The preparation process of component A: Mix 60 parts of liquefied MDI and 20 parts of LTW resin at 500r / min under the condition of dry air protection to make a mixed resin, stir and add 15 parts of mixed phosphate ester color paste under the condition of dry air protection at 500r / min , 2 parts of wetting agent, 2 parts of defoamer, stir at 700r / min and add 2 parts of anti-sagging agent, stir evenly, and obtain component A after filtering.

[0063] The preparation process of component B: Add 60 parts of deionized water to 40 parts of potassium silicate powder with a modulus of 3 under stirring, disperse at 30°C and 700r / min for 1 hour, and obtain component B after filtration...

Embodiment 3

[0068] The difference from Example 1 is:

[0069] Preparation process of mixed phosphate color paste: add 4 parts of color powder to the mixed phosphate of 4 parts of triethyl phosphate and 7 parts of tricresyl phosphate under stirring state, and grind it to below 0.5 μm in a horizontal sand mill.

[0070] The preparation process of component A: Mix 60 parts of liquefied MDI and 20 parts of LTW resin at 500r / min under the condition of dry air protection to make a mixed resin, stir and add 15 parts of mixed phosphate ester color paste under the condition of dry air protection at 500r / min , 2 parts of wetting agent, 2 parts of defoamer, stir at 700r / min and add 2 parts of anti-sagging agent, stir evenly, and obtain component A after filtering.

[0071] The preparation process of component B: Add 60 parts of deionized water to 40 parts of potassium silicate powder with a modulus of 3 under stirring, disperse at 30°C and 700r / min for 1 hour, and obtain component B after filtration...

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Abstract

The invention relates to the technical field of chemical heavy-duty anti-corrosion, in particular to a water-based nano-heavy anti-corrosion coating for chemical sewage pools and its preparation. The coating is mixed by components A, B and C according to the mass ratio of 1:1-3:1-3; among them, component A contains a modified resin mixture of modified polyisocyanate and modified polyester resin, and the mixed phosphate color Slurry, wetting agent, defoamer, anti-sagging agent, component B is silicate aqueous solution, and component C is modified montmorillonite slurry. In the preparation process of the coating of the present invention, components A and C are mixed evenly according to the proportion, and then mixed into component B. After mixing, the inorganic nanoparticles are generated in situ and evenly dispersed in the coating while polymerizing to produce a crosslinked structure. The anti-corrosion performance of the coating is greatly improved, and it can be used in the treatment of concrete with poor base surface conditions, as well as in the anti-corrosion fields of sewage pools such as chemical sewage pools for concrete substrates or metal substrates, and can make up for concrete defects and improve the strength of the substrate. and density.

Description

technical field [0001] The invention relates to the technical field of chemical heavy-duty anti-corrosion, in particular to a water-based nano-heavy anti-corrosion coating for chemical sewage pools and its preparation. Background technique [0002] During the production process of the chemical industry, a large amount of toxic and harmful waste liquid containing strong corrosive media such as strong acid, strong alkali, and organic solvent will be produced. Most of the chemical sewage pools are made of concrete, and a few sewage pools are made of steel structure. The sewage pools of these materials The ability to resist medium is weak, and long-term storage of corrosive medium will cause leakage of waste liquid, pollute groundwater and soil, and cause irreversible environmental pollution. In recent years, with the increasing requirements of the country on environmental protection and sewage discharge requirements of chemical enterprises, the anti-seepage of chemical sewage p...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09D175/02C09D5/08C09D7/62C09D7/63C09D7/61
CPCC08K2201/011C08K2201/014C09D5/08C09D175/02C09D7/61C09D7/62C09D7/63C08L83/04C08K13/06C08K9/02C08K3/346C08K3/34C08K5/521C08K5/523C08K9/04C08K9/06
Inventor 滕赟张宇吴井龙孔凡厚王佳妮王新张学龙黄月
Owner SHENYANG RES INST OF CHEM IND