Aluminum alloy powder for laser coaxial powder feeding additive manufacturing and application of aluminum alloy powder in repairing 5-series aluminum alloy

A technology of coaxial powder feeding and additive manufacturing, which is applied in the direction of additive processing, metal material coating technology, coating, etc., and can solve problems such as low fatigue resistance, easy cracking, and cracks

Active Publication Date: 2020-08-28
CENT SOUTH UNIV +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] At present, there are many problems and defects in Al-Mg-Sc-Zr alloy powder used directly for laser repair. The repair coating has obvious growth of columnar crystals, a large number of pores between dendrites, and easy cracking for repairing a wide area, resulting in low comprehensive strength of the repair layer. , low fatigue resistance
The existing research patents are all Al-Mg-Sc alloy powders used in powder bed laser additive manufacturing. They are directly used in laser coaxial powder feeding additive manufacturing, which is prone to problems such as low mechanical properties and cracks.
Because powder bed additive manufacturing and powder feeding additive manufacturing are different types of additive manufacturing methods, the former has a fast cooling rate, the grains are not easy to grow, and the mechanical properties are high; but the latter is easy to grow grains, and the precipitation is relatively coarse
In the patent with the publication number CN109175350A, a kind of Al-Mg-Mn-Sc-Zr aluminum alloy powder and its preparation method for additive manufacturing are disclosed, which strengthens the Al-Mg alloy by adding Sc and Zr elements, although The strength of aluminum alloy reaches 450MPa, but it is inevitable that defects such as cracks and holes will appear during the printing process, and it is difficult to eliminate the anisotropy between it and the base material
Furthermore, the above-mentioned aluminum alloy powder formula is difficult to be used in the repair process of coaxial powder feeding, because during the repair process, the repair coating columnar crystals grow obviously and there are holes, which are very easy to crack when used for large-scale repair
The patent with the publication number CN107881382A discloses a special rare earth modified high-strength aluminum alloy powder for additive manufacturing. Strength, but the strength is still lower than 300MPa, mainly due to the neglect of the synergistic effect of other elements on the strength of the alloy. The parts printed by this system will still have anisotropy and a large proportion of columnar crystals.

Method used

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  • Aluminum alloy powder for laser coaxial powder feeding additive manufacturing and application of aluminum alloy powder in repairing 5-series aluminum alloy
  • Aluminum alloy powder for laser coaxial powder feeding additive manufacturing and application of aluminum alloy powder in repairing 5-series aluminum alloy
  • Aluminum alloy powder for laser coaxial powder feeding additive manufacturing and application of aluminum alloy powder in repairing 5-series aluminum alloy

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0031] Using coaxial powder feeding laser cladding to repair the surface cracks of 5xxx aluminum alloy parts with a surface hardness of 89HV 0.2 , The damaged repair area is 60mm×50mm.

[0032] Step1: Preparation of aluminum alloy powder for repair, its composition calculated by mass percentage is Si: 1.0wt%, Mg: 3.4wt%, Cu: 0.4wt%, Mn: 0.3wt%, Zn: 0.35wt%, Cr: 0.5wt% %, Ti: 0.7wt%, Fe: 1.1wt%, Zr: 0.7wt%, Sc: 1.4wt%, Ni: 0.25wt%, TiB 2 : 1.6wt%, Ce: 0.45wt%, the balance being Al.

[0033] Step2: Primary alloy powder preparation: remove TiB from the components 2 The other metals are added to the vacuum melting furnace according to the proportion of Step1, and the melting temperature is 600°C, and the furnace pressure is 0.6MPa. After the melting is completed, it is carried out in an argon atmosphere and a gas pressure of 5MPa. Atomization, to obtain the primary alloy powder, SEM characterization of the primary alloy powder, the results are as follows figure 1 shown, from ...

Embodiment 2

[0039] Using coaxial powder feeding laser cladding to repair the surface cracks of 5xxx aluminum alloy parts with a surface hardness of 92HV 0.2 , The damaged repair area is 70mm×40mm.

[0040] Step1: Prepare the aluminum alloy powder for repair, its composition is calculated by mass percentage as Si: 1.0wt%, Mg: 4.0wt%, Cu: 0.5wt%, Mn: 0.4wt%, Zn: 0.45wt%, Cr: 0.6wt% %, Ti: 0.8wt%, Fe: 1.2wt%, Zr: 0.8wt%, Sc: 1.6wt%, Ni: 0.35wt%, TiB 2 : 1.8wt%, Ce: 0.55wt%, the balance being Al.

[0041] Step2: Primary alloy powder preparation: remove TiB from the components 2 The other metals are added to the vacuum melting furnace according to the proportion of Step1, and the melting temperature is 600°C, and the furnace pressure is 0.6MPa. After the melting is completed, it is carried out in an argon atmosphere and a gas pressure of 5MPa. Atomization to obtain primary alloy powder, the average particle size of primary alloy powder is 120μm

[0042] Step3: Combine the primary alloy pow...

Embodiment 3

[0047] Using coaxial powder feeding laser cladding to repair the surface cracks of 5xxx aluminum alloy parts with a surface hardness of 92HV 0.2 , The damaged repair area is 60mm×40mm.

[0048] Step1: Preparation of aluminum alloy powder for repair, its composition calculated by mass percentage is Si: 1.2wt%, Mg: 4.6wt%, Cu: 0.6wt%, Mn: 0.5wt%, Zn: 0.55wt%, Cr: 0.7wt% %, Ti: 0.9wt%, Fe: 1.4wt%, Zr: 0.9wt%, Sc: 1.8wt%, Ni: 0.45wt%, TiB2: 2.0wt%, Ce: 0.65wt%, and the balance is Al.

[0049] Step2: Primary alloy powder preparation: remove TiB from the components 2 The other metals are added to the vacuum melting furnace according to the proportion of Step1, and the melting temperature is 600°C, and the furnace pressure is 0.6MPa. After the melting is completed, it is carried out in an argon atmosphere and a gas pressure of 5MPa. atomization to obtain primary alloy powder, the average particle size of the primary alloy powder is 140 μm.

[0050] Step3: Combine the primary alloy...

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Abstract

The invention discloses aluminum alloy powder for laser coaxial powder feeding additive manufacturing and application of the aluminum alloy powder in repairing 5-series aluminum alloy. The aluminum alloy powder is composed of the following components in percentage by mass: 0.4-1.5 wt% of Si, 0.5-5.0 wt% of Mg, 0.15-0.8 wt% of Cu, 0.05-0.9 wt% of Mn, 0.15-0.7 wt% of Zn, 0.01-1.0 wt% of Cr, 0.2-1.2wt% of Ti, 0.1-2.0 wt% of Fe, 0.2-2.1 wt% of Zr, 0.2-2.1 wt% of Sc, 0.15-0.65 wt% of Ni, 0.2-2.5 wt% of TiB2, 0.1-0.9 wt% of Ce, and the balance of Al. The beneficial elements including Zn, Cr, Ti, Fe, Ni, TiB2 and Ce are added on the basis of the 5-series aluminum alloy, second phases such as a long-range ordered phase and a twin crystal phase are formed to form synergistic reinforcement of the elements, so that the anisotropy of the material is eliminated, meanwhile, the content of Si element is increased, then a eutectic structure is formed in the later period of laser cladding solidification, and the eutectic structure is used for supplementing hot crack pores caused by rapid solidification.

Description

technical field [0001] The invention belongs to laser cladding surface repair and surface modification technology, in particular to a laser coaxial powder feeding additive manufacturing aluminum alloy powder and its application in repairing 5 series aluminum alloys. Background technique [0002] 5xxx aluminum alloy has medium and high strength, good welding performance and corrosion resistance, and is widely used in transportation and structural engineering, such as bridges, aero-engine parts and fuselage panels, transport ships, and cranes. In recent years, with the development of science and technology industry at home and abroad, in order to reduce the weight of the machine itself, aluminum alloys have gradually replaced steel materials. However, aluminum alloys are often affected by external large stresses during service, including surface friction and reciprocating unloading and loading, resulting in surface fatigue, cracks, pores and other defects. Therefore, a large ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22C21/08C22C32/00B22F9/08B22F9/04C23C24/10B33Y70/10
CPCB22F9/04B22F9/082B22F2009/043B22F2009/0848B33Y70/10C22C21/08C22C32/0073C23C24/103
Inventor 李瑞迪袁铁锤王银
Owner CENT SOUTH UNIV
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