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Functional ethylene propylene diene monomer and preparation method thereof

A functional technology of EPDM rubber, which is applied in the field of functional EPDM rubber and its preparation, can solve the problems of reducing the volume resistivity and mechanical properties of rubber, increasing the amount of paraffin oil, etc., and achieving anti-aging performance Excellent, high electrical performance, high volume resistivity effect

Pending Publication Date: 2020-09-11
CHANGLAN CABLE ACCESSORIES
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, since the volume resistivity of paraffin oil is lower than that of EPDM rubber, the increase in the amount of paraffin oil will not only reduce the volume resistivity and mechanical properties of the rubber, but also cause the rubber to have the potential risk of oil injection

Method used

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  • Functional ethylene propylene diene monomer and preparation method thereof
  • Functional ethylene propylene diene monomer and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0069] In this example, a functional EPDM rubber is prepared, and the specific preparation raw materials include:

[0070] EPDM rubber with grade 4520 of Dow Chemical: 100 parts,

[0071] Zinc oxide: 5 parts,

[0072] Stearic acid: 1 part,

[0073] Antiaging agent RD: 1 part,

[0074] Naphthenic oil: 15 parts,

[0075] White carbon black: 25 parts,

[0076] Methylphenyl methoxy silicone oil: 2.5 parts,

[0077] Bis(γ-triethoxysilylpropyl)tetrasulfide: 2 parts,

[0078] Dicumyl peroxide: 3 parts,

[0079] Insoluble sulfur: 0.3 parts,

[0080] Triallyl isocyanurate: 1 part.

[0081] The preparation method of the above-mentioned low-hardness, high-strength and high-electricity EPDM insulating rubber comprises the following steps:

[0082] S1: Put the EPDM rubber in the formula amount into a pressurized internal mixer for 8 minutes to break the rubber;

[0083] S2: Add zinc oxide, stearic acid, anti-aging agent RD, and methylphenylmethoxy silicone oil in the formula amou...

Embodiment 2

[0088] In this example, a functional EPDM rubber was prepared by using the same preparation method as in Example 1, and the specific preparation raw materials included:

[0089] EPDM rubber with grade 4520 of Dow Chemical: 100 parts,

[0090] Zinc oxide: 5 parts,

[0091] Stearic acid: 1 part,

[0092] Antiaging agent RD: 1 part,

[0093] Paraffin oil: 5 parts,

[0094] Naphthenic oil: 10 parts,

[0095] White carbon black: 25 parts,

[0096] Methylphenyl methoxy silicone oil: 2.5 parts,

[0097] Bis(γ-triethoxysilylpropyl)tetrasulfide: 2 parts,

[0098] Dicumyl peroxide: 3 parts,

[0099] Insoluble sulfur: 0.3 parts,

[0100] Triallyl isocyanurate: 1 part.

Embodiment 3

[0102] In this example, a functional EPDM rubber was prepared by using the same preparation method as in Example 1, and the specific preparation raw materials included:

[0103] EPDM rubber with grade 4520 of Dow Chemical: 100 parts,

[0104] Zinc oxide: 5 parts,

[0105] Stearic acid: 1 part,

[0106] Antiaging agent RD: 1 part,

[0107] Naphthenic oil: 15 parts,

[0108] White carbon black: 25 parts,

[0109] Methylphenyl methoxy silicone oil: 4 parts,

[0110] Bis(γ-triethoxysilylpropyl)tetrasulfide: 4 parts,

[0111] Dicumyl peroxide: 3 parts,

[0112] Insoluble sulfur: 0.3 parts,

[0113] Triallyl isocyanurate: 1 part.

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Abstract

The invention provides functional ethylene-propylene-diene monomer rubber and a preparation method thereof. The functional ethylene-propylene-diene monomer rubber is prepared from the following raw materials: ethylene-propylene-diene monomer rubber, zinc oxide, stearic acid, an anti-aging agent, a plasticizer, a reinforcing agent, a structure control agent, a silane coupling agent, a vulcanizing agent and an assistant cross-linking agent. The functional ethylene propylene diene monomer rubber provided by the invention has low hardness (shore hardness is less than 60), low Mooney value (90 DEGC, 1+4 min, less than 40) and short vulcanization time T90 (175 DEG C, 15min, less than 7min). The volume resistivity is high (greater than 1.0 * 10<16> omega.cm), the breakdown strength is high (greater than 32 kV / mm), the mechanical strength is high (the tearing strength is greater than 22 MPa and the tensile strength is greater than 10 MPa), the anti-aging performance is excellent (the tensilestrength and the elongation at break change rate are both less than + / - 20%), and frosting is avoided.

Description

technical field [0001] The invention belongs to the technical field of insulating rubber preparation, and in particular relates to a functional EPDM rubber and a preparation method thereof. Background technique [0002] Power cable accessories are products that connect cables with power transmission and distribution lines and related power distribution devices. Generally, they refer to the intermediate connection and terminal connection of various cables in the cable line. Together with the cables, they form a power transmission network. Cable accessories are mainly based on the characteristics of the cable structure, which can not only restore the performance of the cable, but also ensure the extension of the cable length and the connection of the terminal. The reliability of high-voltage cable accessories can be judged from the aspects of electrical performance, sealing and moisture-proof performance, mechanical performance and process performance. Commonly used cable acc...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/16C08L91/00C08L83/04C08L91/06C08K13/04C08K3/22C08K5/09C08K7/26C08K5/14C08K5/3492C08K3/06C08K5/548
CPCC08L23/16C08L2201/08C08L2312/00C08L2205/03C08L2205/02C08L2205/035C08K2003/2296C08L91/00C08L83/04C08K13/04C08K3/22C08K5/09C08K7/26C08K5/14C08K5/34924C08K3/06C08K5/548C08L91/06
Inventor 贺志文乐新波陈进
Owner CHANGLAN CABLE ACCESSORIES