Preparation method of polyformaldehyde self-lubricating sieve plate
A polyoxymethylene and self-lubricating technology, applied in the field of preparation of polyoxymethylene self-lubricating sieve plates, can solve the problems of low lubrication effect, easy breakage of polyoxymethylene, unusable use, etc., and achieves fast crystallization speed, easy stress concentration, and improved surface hardness. Effect
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Embodiment 1
[0018]The first step is to prepare microcapsule fillers: first prepare microcapsule fillers with solid chlorinated paraffin as the capsule core and formaldehyde-aniline polymer as the capsule shell, dissolve 130 parts of distilled water and 30 parts of formaldehyde into the reaction kettle, and use carbonic acid Adjust the pH to 9.0 with the sodium solution, add aniline according to the molar ratio of formaldehyde:aniline 1:0.75, raise the temperature to 60°C at a rate of 2°C / min, keep it warm for 1h, quickly cool down to 40°C, add 60 parts of distilled water to dilute , to obtain a prepolymer, then take chlorinated paraffin and heat and melt it according to the mass ratio of core-to-wall ratio of 1.5:1, add emulsifier sodium polystyrene sulfonate and emulsify at 1000r / min for 10min, during which the mass fraction is added dropwise Continue to emulsify 0.5% polyvinylpyrrolidone aqueous solution for 4 minutes to obtain a stable chlorinated paraffin emulsion, add the prepolymer t...
Embodiment 2
[0020] The first step is to prepare microcapsule fillers: first prepare the microcapsule fillers with solid chlorinated paraffin as the capsule core and formaldehyde-aniline polymer as the capsule shell. The preparation method is: 20 parts of formaldehyde and 120 parts of distilled water are added to the reaction kettle , adjust the pH to 8.5 with sodium carbonate solution, add aniline according to the molar ratio of formaldehyde:aniline 1:0.75, raise the temperature to 50°C at a rate of 2°C / min, keep it warm for 0.5h, quickly cool down to 40°C, add 50 distilled water to obtain a prepolymer, and then take chlorinated paraffin and heat and melt it according to the mass ratio of core wall ratio of 1.5:1, add emulsifier sodium polystyrene sulfonate and emulsify at 1000r / min for 5min, gradually Add dropwise 0.5% polyvinylpyrrolidone aqueous solution and continue to emulsify for 2 minutes to obtain a stable chlorinated paraffin emulsion. Add the prepolymer to the prepared chlorinate...
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